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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Iridium Trichloride supplier in China

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Iridium Trichloride

Cas:10025-83-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 10025-83-9 Iridium trichloride

Cas:10025-83-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Iridium trichloride Manufacturer/High quality/Best price/In stock

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity 鈮 9% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package can

99% Purity Catalyst CAS 10025-83-9 Iridium Trichloride with Iridium (+3) Chloride

Cas:10025-83-9

Min.Order:1 Metric Ton

FOB Price: $5.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 10025-83-9 with best quality

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Iridium trichloride

Cas:10025-83-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Iridium trichlorideCAS10025-83-9

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name Iridium trichloride CAS Number 10025-83-9 Synonyms iridiumchloride(ircl3);IRIDIUM(+3)CHLORIDE;IRIDIUM CHLORIDE;IRIDIUM(III) CHLORIDE;IRIDIUM TRICHLORIDE;IRIDIUM(III) CHLORIDE, CRYSTALS;Iridium(III)

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Iridium trichloride 10025-83-9

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $89.0 / 100.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Iridium trichloride CAS:10025-83-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

Iridium trichloride CAS:10025-83-9

Cas:10025-83-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Iridium(III) chloride

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:10025-83-9

Cas:10025-83-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

We provide tailor-made photoinitiator solutions for different performances by custom synthesisi.blends or other technical supports low-odor uv formulations non-yellowing uv formulations benzene-free uv formulations polymeric uv formul

Iridium trichloride CAS:10025-83-9

Cas:10025-83-9

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

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Lonwin Chemical Group Limited

Iridium trichloride CAS: 10025-83-9 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure C.The IR spectr

Factory supply Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and quality c

Iridium trichloride

Cas:10025-83-9

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei Lidu New Material Technology Co., Ltd

Hubei Lidu New Materials Technology Co. , Ltd. is located in No. 12,3C Industrial Park, Zhongxiang Economic Development Zone, Hubei Province. The company is committed to fine chemical raw materials, pharmaceutical intermediates and other production,

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Iridium trichloride

Cas:10025-83-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Iridium trichloride

Cas:10025-83-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Iridium Trichloride

Cas:10025-83-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Iridium trichloride CAS NO.10025-83-9

Cas:10025-83-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery Appearance:brown powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:Used as Pharmaceutical Intermediates

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Chemical Iridium(III) chloride Powder CAS 10025-83-9

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.5

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Antimony trichloride Melting point 763 °C (lit.) Density 5,3 g/cm3 Solubility H2O: insoluble(lit.) Form Powder Color Green to brown Water solubility Sensitivity Hygroscopic Merck 14,5088 Stable. Protect from moisture. CAS Da

TIANFU CHEM---highpurityof99%Iridiumtrichlorideforsale

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity Iridium trichloride

Cas:10025-83-9

Min.Order:0

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Iridium trichloride CAS NO.10025-83-9

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

High purity Iridium trichloride

Cas:10025-83-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Iridium trichloride

Cas:10025-83-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Synthetic route

iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C;100%
With chlorine
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light;
iridium

iridium

A

iridium(III) chloride

iridium(III) chloride

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

C

iridium(I)-chloride

iridium(I)-chloride

Conditions
ConditionsYield
With chlorine above 600°C, by decompn.;
With Cl2 above 600°C, by decompn.;
oxygen
80937-33-3

oxygen

iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
at red heat; product is a mixt. of Ir and IrCl3;
at red heat; product is a mixt. of Ir and IrCl3;
BaO*CO2=BaCO3

BaO*CO2=BaCO3

3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

A

iridium (III) chloride
10025-83-9

iridium (III) chloride

B

barium oxalate
516-02-9

barium oxalate

Conditions
ConditionsYield
In water filtering;evapn.;
iridium(III) trichloride hydrate

iridium(III) trichloride hydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;;
at 310°C;
3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;
3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;
iridium(IV) oxide dihydrate

iridium(IV) oxide dihydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine by heating;
With Cl2 by heating;
potassium hexachloroiridate(III)

potassium hexachloroiridate(III)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;
silver iridium(III) chloride

silver iridium(III) chloride

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride byproducts: AgCl contg. Ir;
With HCl byproducts: AgCl contg. Ir;
ammonium hexachloroiridium(IV)

ammonium hexachloroiridium(IV)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 600°C;
With Cl2 in a flow of dry Cl2 at 550°C, quenching of the product;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;;
ammonium hexachloroiridate(III)

ammonium hexachloroiridate(III)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry chlorine at 600°C;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 550°C, quenching the product;;
chlorine
7782-50-5

chlorine

iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
chlorination of iridium powder at about 600°C;
trinitro triammine iridium(III)

trinitro triammine iridium(III)

A

trichloro triammine iridium(III)
63976-47-6, 60183-09-7, 25456-36-4

trichloro triammine iridium(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

C

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
With HCl In not given glowing in sealed tube over 100°C;
potassium hexachloroiridate(IV)

potassium hexachloroiridate(IV)

A

potassium hexachloroiridate(III)

potassium hexachloroiridate(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;
hexachloroiridate(IV)

hexachloroiridate(IV)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With sulfuric acid concd. H2SO4;
With H2SO4 concd. H2SO4;
iridium hexafluoride
7783-75-7

iridium hexafluoride

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With dichloromethane In dichloromethane byproducts: CH2ClF, CH2F2, CHClF2; inert atmosphere; excess of CH2Cl2, cooling, warming to room temp.; further byproducts;
sodium hexachloroiridate

sodium hexachloroiridate

A

sodium hexachloroiridate(III)

sodium hexachloroiridate(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
in dry HCl gas flow at 440-500°C;
byproducts: Cl2;
in dry HCl gas flow at 440-500°C;
byproducts: Cl2;
iridium tetrachloride
10025-97-5

iridium tetrachloride

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
In solid in air; TG and DTA monitoring, X-ray diffraction anal.;
dihydrogen hexachloroiridium(IV) hexahydrate

dihydrogen hexachloroiridium(IV) hexahydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
In solid Ar atmosphere; TG and DTA monitoring, X-ray diffraction anal.;
iridium (III) chloride
10025-83-9

iridium (III) chloride

triphenylphosphine
603-35-0

triphenylphosphine

tris(triphenylphosphine)chloroiridium
16070-58-9

tris(triphenylphosphine)chloroiridium

Conditions
ConditionsYield
In tert-butyl alcohol PPh3 dissolved in hot t-butyl alc., purged with N2, IrCl3 added, refluxed for 72 h under N2; filtered, washed (ether), dried (air);94%
chloropentaammineiridium(III) chloride

chloropentaammineiridium(III) chloride

iridium (III) chloride
10025-83-9

iridium (III) chloride

3{Ir(NH3)5Cl}(2+)*2{IrCl6}(3-)={Ir(NH3)5Cl}3{IrCl6}2

3{Ir(NH3)5Cl}(2+)*2{IrCl6}(3-)={Ir(NH3)5Cl}3{IrCl6}2

Conditions
ConditionsYield
In water room temp. excess of IrCl3; evapn; dissolving in H2SO4; washing with H2O; heating over 100°C;90%
In water room temp. excess of IrCl3; evapn; dissolving in H2SO4; washing with H2O; heating over 100°C;90%
4-methyl-2-(phenanthren-10-yl)quinoline
863487-49-4

4-methyl-2-(phenanthren-10-yl)quinoline

iridium (III) chloride
10025-83-9

iridium (III) chloride

acetylacetone
123-54-6

acetylacetone

Ir(4-methyl-2-(phenanthren-10-yl)quinoline(1-))2(acetylacetonate)
863487-43-8

Ir(4-methyl-2-(phenanthren-10-yl)quinoline(1-))2(acetylacetonate)

Conditions
ConditionsYield
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;84%
2-(4-fluorophenyl)-5-(trifluoromethyl)pyridine

2-(4-fluorophenyl)-5-(trifluoromethyl)pyridine

iridium (III) chloride
10025-83-9

iridium (III) chloride

fac-tris((F)(C6H4)(CF3)pyridine)iridium

fac-tris((F)(C6H4)(CF3)pyridine)iridium

Conditions
ConditionsYield
With silver trifluoroacetate In neat (no solvent) 170-195°C, 2-9 h;82%
2-(4-(tert-butyl)phenyl)-4-methylquinoline
863487-45-0

2-(4-(tert-butyl)phenyl)-4-methylquinoline

iridium (III) chloride
10025-83-9

iridium (III) chloride

acetylacetone
123-54-6

acetylacetone

(2-(4-(tert-butyl)phenyl)-4-methylquinoline)2Ir(acetylacetone)
863487-39-2

(2-(4-(tert-butyl)phenyl)-4-methylquinoline)2Ir(acetylacetone)

Conditions
ConditionsYield
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;82%
iridium (III) chloride
10025-83-9

iridium (III) chloride

(2-mercaptophenyl)diphenylphosphine
119327-17-2

(2-mercaptophenyl)diphenylphosphine

[Ir(2-diphenylphosphinobenzenethiolate)3] * 0.75 CH2Cl2

[Ir(2-diphenylphosphinobenzenethiolate)3] * 0.75 CH2Cl2

Conditions
ConditionsYield
With NEt3 In methanol N2-atmosphere; refluxing of IrCl3 with 4 equiv. of ligand and NEt3 (4 h, pptn.); elem. anal.;80%
iridium (III) chloride
10025-83-9

iridium (III) chloride

dibenzyl methylphosphine
61236-06-4

dibenzyl methylphosphine

mer-[IrCl3[PMe(CH2Ph)2]3]
79177-89-2

mer-[IrCl3[PMe(CH2Ph)2]3]

Conditions
ConditionsYield
In 2-methoxy-ethanol mixt. was refluxed for 3 h; crystals were filtered off, washed with ethanol, dried; elem. anal.;77%
4-methyl-2-(4-(trifluoromethyl)phenyl)-4-methylquinoline
863487-46-1

4-methyl-2-(4-(trifluoromethyl)phenyl)-4-methylquinoline

iridium (III) chloride
10025-83-9

iridium (III) chloride

acetylacetone
123-54-6

acetylacetone

Ir(2-(4-trifluoromethylphenyl)-4-methylquinoline(1-))2(acetylacetonate)

Ir(2-(4-trifluoromethylphenyl)-4-methylquinoline(1-))2(acetylacetonate)

Conditions
ConditionsYield
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;77%
2-phenylpyridine
1008-89-5

2-phenylpyridine

ammonium hexafluorophosphate

ammonium hexafluorophosphate

iridium (III) chloride
10025-83-9

iridium (III) chloride

4,4'-di-tert-butyl-2,2'-bipyridine
72914-19-3

4,4'-di-tert-butyl-2,2'-bipyridine

iridium(III) bis[2-phenylpyridine-N,C2']-4,4'-di-tert-butyl-2,2'-bipyridine hexafluorophosphate

iridium(III) bis[2-phenylpyridine-N,C2']-4,4'-di-tert-butyl-2,2'-bipyridine hexafluorophosphate

Conditions
ConditionsYield
In 2-ethoxy-ethanol; water (N2, Schlenk technique); heating iridium compd. and 2 equiv. of triazolederiv. in 2-ethoxyethanol/water (6/1) at 110°C for 19 h, addn. o f bipyridine deriv., stirring at 110°C for 19 h; cooling to room temp., addn. of H2O, washing by Et2O, concg. at 70°C for 10 min, cooling to room temp., addn. of aq. NH4PF6, chromy. (silica gel, CH2Cl2/Me2CO (0-10%)), ppn. with aq. NH4PF6 from CH3OH soln., filtration, washing with H2O, drying;76%
2-heptanone thiosemicarbazone
2030-66-2

2-heptanone thiosemicarbazone

iridium (III) chloride
10025-83-9

iridium (III) chloride

Ir(CH3(CH2)4C(CH3)NNHCSNH2)3(3+)*3Cl(1-)=Ir(C8H17N3S)3Cl3

Ir(CH3(CH2)4C(CH3)NNHCSNH2)3(3+)*3Cl(1-)=Ir(C8H17N3S)3Cl3

Conditions
ConditionsYield
In ethanol; water a hot aq. soln. of IrCl3 was mixed with a hot ethanolic soln. of the thiosemicarbazone; refluxing on a water bath for about 2-3 h;; pptn. on cooling; the ppt. was filtered off, washed with 1:1 aq. ethanol, and dried over P4O10; elem. anal.;;75%
2-(diisopropylphosphanyl)benzenethiol
444069-41-4

2-(diisopropylphosphanyl)benzenethiol

iridium (III) chloride
10025-83-9

iridium (III) chloride

[Ir(pr(i)PS)3]

[Ir(pr(i)PS)3]

Conditions
ConditionsYield
With NEt3 In methanol under N2 atm. MeOH soln. IrCl3 and phosphino-thiol in the presence of NEt3 were heated under reflux for 2 h; ppt. was filtered and washed with cold Et2O; elem. anal.;75%
1,1'-thiobis[3-(methylthio)]propane
39095-55-1

1,1'-thiobis[3-(methylthio)]propane

iridium (III) chloride
10025-83-9

iridium (III) chloride

{bis(3-methylthiopropyl) sulphide}trichloroiridium(III)
102858-72-0

{bis(3-methylthiopropyl) sulphide}trichloroiridium(III)

Conditions
ConditionsYield
In 2-methoxy-ethanol IrCl3 and ligand were dissolved in 2-methoxyethanol, refluxed with stirring for 1 h; cooled, filtered, solvent was removed in vac., residue was dissolved in CH2Cl2, treated with Et2O; elem. anal.;72%
2-(4-(CF3O)-(C6H4))(5-CF3)pyridine
370878-66-3

2-(4-(CF3O)-(C6H4))(5-CF3)pyridine

iridium (III) chloride
10025-83-9

iridium (III) chloride

fac-tris((CF3O)(C6H4)(CF3)pyridine)iridium

fac-tris((CF3O)(C6H4)(CF3)pyridine)iridium

Conditions
ConditionsYield
With silver trifluoroacetate In neat (no solvent) 170-195°C, 2-9 h;72%
iridium (III) chloride
10025-83-9

iridium (III) chloride

2,3,8,9‐tetraphenyl‐1,4,7,10‐tetraazacyclododeca‐1,3,7,9‐tetraene
79403-78-4

2,3,8,9‐tetraphenyl‐1,4,7,10‐tetraazacyclododeca‐1,3,7,9‐tetraene

[Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
191590-22-4

[Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl

Conditions
ConditionsYield
In ethanol addn. of hot soln. of metal salt to hot soln. of macrocycle, refluxing (4 h), cooling to room temp., pptn. on volume reduction; filtration, washing (hot EtOH), air drying; elem. anal.;72%
sodium N,N-cyclo-hexamethylenedithiocarbamate dihydrate

sodium N,N-cyclo-hexamethylenedithiocarbamate dihydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

tris(hexamethyleneiminecarbodithioate)iridium(III)
121380-75-4

tris(hexamethyleneiminecarbodithioate)iridium(III)

Conditions
ConditionsYield
In methanol; water amixing of solution of IrCl3 in 1:2 H2O/CH3OH with the ligand in H2O under constant stirring; refluxing for 3 h; filtration of ppt.; cwashing with H2O/CH3OH; drying over P2O5 in vacuo; TGA-anal.; x-ray diffraction; elem. anal.; AAS;70%
octan-2-one semicarbazone
3622-69-3

octan-2-one semicarbazone

iridium (III) chloride
10025-83-9

iridium (III) chloride

methyl-n-hexylketone semicarbazone iridium(III) chloride

methyl-n-hexylketone semicarbazone iridium(III) chloride

Conditions
ConditionsYield
In ethanol; water mixing a hot aq. soln. of IrCl3 with a hot ethanolic soln. of the ligand, refluxing on a water bath for about 2 - 3 h, cooling, pptn.; filtration, washing with aq. ethanol (1:1), drying over P4O10 in vac., elem. anal.;70%
4,6-dimethyl-2-(naphthalen-2-yl)pyrimidine

4,6-dimethyl-2-(naphthalen-2-yl)pyrimidine

iridium (III) chloride
10025-83-9

iridium (III) chloride

triphenylphosphine
603-35-0

triphenylphosphine

[Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh3)2Cl2]
1359762-09-6

[Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh3)2Cl2]

Conditions
ConditionsYield
In 2-ethoxy-ethanol; water IrCl3 (0.5 mmol), pyrimidine ligand (1.5 mmol), PPh3 (1.5 mmol), 2-ethoxyethanol (15 mml) and H2O (5 ml) refluxed under N2 (12 h); cooled to room temp.; ppt. filtered; washed with H2O and EtOH; chromd. (silica gel column, eluent: CH2Cl2/ethyl acetate (5:1); elem. anal.;70%
4-methyl-2-(naphthalen-1-yl)quinoline
854139-31-4

4-methyl-2-(naphthalen-1-yl)quinoline

iridium (III) chloride
10025-83-9

iridium (III) chloride

acetylacetone
123-54-6

acetylacetone

Ir(4-methyl-2-(naphthalen-1-yl)quinoline(1-))2(acetylacetonate)

Ir(4-methyl-2-(naphthalen-1-yl)quinoline(1-))2(acetylacetonate)

Conditions
ConditionsYield
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;68%
iridium (III) chloride
10025-83-9

iridium (III) chloride

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

benzil
134-81-6

benzil

[Ir(dibenzo[e,k]-2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
191590-24-6

[Ir(dibenzo[e,k]-2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl

Conditions
ConditionsYield
In ethanol mixing hot soln. of metal salt, hot soln. of benzil, addn. of hot soln. of phenylenediamine, refluxing (12 h), volume reduction, cooling to roomtemp. (pptn., 1 d); filtration, washing (hot EtOH), air drying; elem. anal.;66%
2-furyl (m-aminophenylenimine)methyl ketone
200565-63-5

2-furyl (m-aminophenylenimine)methyl ketone

iridium (III) chloride
10025-83-9

iridium (III) chloride

[Ir(2-furyl (m-aminophenylenimine)methyl ketone)Cl3]
200565-62-4

[Ir(2-furyl (m-aminophenylenimine)methyl ketone)Cl3]

Conditions
ConditionsYield
In acetone water bath (15 min, pptn.); cooling, filtration, washing (alcohol), drying (owen, 160°C); elem. anal.;65%
N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine
863487-48-3

N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine

iridium (III) chloride
10025-83-9

iridium (III) chloride

acetylacetone
123-54-6

acetylacetone

Ir(N-(4-(4-methylquinolin-2-yl)-N-phenylbenzenamine(1-))2(acetylacetonate)
863487-42-7

Ir(N-(4-(4-methylquinolin-2-yl)-N-phenylbenzenamine(1-))2(acetylacetonate)

Conditions
ConditionsYield
With sodium carbonate In 2-methoxy-ethanol; water under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;65%
iridium (III) chloride
10025-83-9

iridium (III) chloride

bis(3-methylselenopropyl) selenide
90454-83-4

bis(3-methylselenopropyl) selenide

{bis(3-methylselenopropyl) selenide}trichloroiridium(III)
102858-73-1

{bis(3-methylselenopropyl) selenide}trichloroiridium(III)

Conditions
ConditionsYield
In 2-methoxy-ethanol IrCl3 and ligand were dissolved in 2-methoxyethanol, refluxed with stirring for 1 h; cooled, filtered, solvent was removed in vac., residue was dissolved in CH2Cl2, treated with Et2O; elem. anal.;64%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

ammonium hexafluorophosphate

ammonium hexafluorophosphate

4-(1-(2,4-difluorophenyl))-1-benzyl-1,2,3-triazole
1311386-87-4

4-(1-(2,4-difluorophenyl))-1-benzyl-1,2,3-triazole

iridium (III) chloride
10025-83-9

iridium (III) chloride

iridium(III) bis[1-benzyl-4-(2',4'-difluorophenyl)-1,2,3-triazolato-N,C6']-2,2'-bipyridine hexafluorophosphate

iridium(III) bis[1-benzyl-4-(2',4'-difluorophenyl)-1,2,3-triazolato-N,C6']-2,2'-bipyridine hexafluorophosphate

Conditions
ConditionsYield
In 2-ethoxy-ethanol; water (N2, Schlenk technique); heating iridium compd. and 2 equiv. of triazolederiv. in 2-ethoxyethanol/water (6/1) at 110°C for 19 h, addn. o f bipyridine, stirring at 110°C for 19 h; cooling to room temp., addn. of H2O, washing by Et2O, concg. at 70°C for 10 min, cooling to room temp., addn. of aq. NH4PF6, chromy. (silica gel, CH2Cl2/Me2CO (0-10%)), ppn. with aq. NH4PF6 from CH3OH soln., filtration, washing with H2O, drying;64%
iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C;100%
With chlorine
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light;
iridium

iridium

A

iridium(III) chloride

iridium(III) chloride

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

C

iridium(I)-chloride

iridium(I)-chloride

Conditions
ConditionsYield
With chlorine above 600°C, by decompn.;
With Cl2 above 600°C, by decompn.;
oxygen
80937-33-3

oxygen

iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
at red heat; product is a mixt. of Ir and IrCl3;
at red heat; product is a mixt. of Ir and IrCl3;
BaO*CO2=BaCO3

BaO*CO2=BaCO3

3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

A

iridium (III) chloride
10025-83-9

iridium (III) chloride

B

barium oxalate
516-02-9

barium oxalate

Conditions
ConditionsYield
In water filtering;evapn.;
iridium(III) trichloride hydrate

iridium(III) trichloride hydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;;
at 310°C;
3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;
3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;
iridium(IV) oxide dihydrate

iridium(IV) oxide dihydrate

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine by heating;
With Cl2 by heating;
potassium hexachloroiridate(III)

potassium hexachloroiridate(III)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;
silver iridium(III) chloride

silver iridium(III) chloride

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride byproducts: AgCl contg. Ir;
With HCl byproducts: AgCl contg. Ir;
ammonium hexachloroiridium(IV)

ammonium hexachloroiridium(IV)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 600°C;
With Cl2 in a flow of dry Cl2 at 550°C, quenching of the product;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;;
ammonium hexachloroiridate(III)

ammonium hexachloroiridate(III)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry chlorine at 600°C;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 440°C;;
With Cl2 In neat (no solvent) in a flow of dry Cl2 at 550°C, quenching the product;;
chlorine
7782-50-5

chlorine

iridium

iridium

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
chlorination of iridium powder at about 600°C;
trinitro triammine iridium(III)

trinitro triammine iridium(III)

A

trichloro triammine iridium(III)
63976-47-6, 60183-09-7, 25456-36-4

trichloro triammine iridium(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

C

iridium tetrachloride
10025-97-5

iridium tetrachloride

Conditions
ConditionsYield
With HCl In not given glowing in sealed tube over 100°C;
potassium hexachloroiridate(IV)

potassium hexachloroiridate(IV)

A

potassium hexachloroiridate(III)

potassium hexachloroiridate(III)

B

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;
hexachloroiridate(IV)

hexachloroiridate(IV)

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With sulfuric acid concd. H2SO4;
With H2SO4 concd. H2SO4;
iridium hexafluoride
7783-75-7

iridium hexafluoride

iridium (III) chloride
10025-83-9

iridium (III) chloride

Conditions
ConditionsYield
With dichloromethane In dichloromethane byproducts: CH2ClF, CH2F2, CHClF2; inert atmosphere; excess of CH2Cl2, cooling, warming to room temp.; further byproducts;

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