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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Ruthenium carbonyl

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for Ruthenium Carbonyl Cas 15243-33-1 Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Orange powder Storage:N/A Package:100g,1kg/foil bag Application:Cata

High quality Ruthenium Carbonyl Cas 15243-33-1 with best price

Cas:15243-33-1

Min.Order:100 Gram

FOB Price: $10.0 / 15.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:shanghai

Ruthenium carbonyl

Cas:15243-33-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High efficiency 99% Triruthenium Dodecacarbonyl 15243-33-1 Manufacturer

Cas:15243-33-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Triruthenium dodecacarbonyl

Cas:15243-33-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM--RUTHENIUM CARBONYL

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $1300.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

RUTHENIUM CARBONYL CAS 15243-33-1

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 15243-33-1 with best quality

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 15243-33-1Carbon monooxide-ruthenium (4:1)

Cas:15243-33-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

RUTHENIUM CARBONYL/15243-33-1CAS NO.: 15243-33-1

Cas:15243-33-1

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ruthenium,dodecacarbonyltri-, triangulo 15243-33-1

Cas:15243-33-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: RUTHENIUM CARBONYL MF: C12O12Ru3 MW: 639.33 EINECS: 239-287-4 Mol File: 15243-33-1.mol RUTHENIUM CARBONYL Structure RUTHENIUM CARBONYL Chemical Properties Melting point 150 °C storage temp. Inert atmosphere,

RUTHENIUM CARBONYL

Cas:15243-33-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

RUTHENIUM CARBONYL CAS:15243-33-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

RUTHENIUM CARBONYL CAS:15243-33-1

Cas:15243-33-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ruthenium,dodecacarbonyltri-, triangulo

Cas:15243-33-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

We provide tailor-made photoinitiator solutions for different performances by custom synthesisi.blends or other technical supports low-odor uv formulations non-yellowing uv formulations benzene-free uv formulations polymeric uv formul

triruthenium dodecacarbonyl CAS NO.15243-33-1 Factory Low Price High Quality

Cas:15243-33-1

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply triruthenium dodecacarbonyl

Cas:15243-33-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ruthenium,dodecacarbonyltri-, triangulo

Cas:15243-33-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products TrirutheniuM dodecacarbonyl

Cas:15243-33-1

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ruthenium Carbonyl

Cas:15243-33-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Factory outlet Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1

Cas:15243-33-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

RUTHENIUM CARBONYL

Cas:15243-33-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Factory outlet Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

RUTHENIUM CARBONYL

Cas:15243-33-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Factory outlet Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1

Cas:15243-33-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Ruthenium carbonyl99%

Cas:15243-33-1

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Factory outlet Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12 15243-33-1

Cas:15243-33-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Triruthenium dodecacarbonyl

Cas:15243-33-1

Min.Order:1 Gram

Negotiable

Type:Other

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Triruthenium dodecacarbonyl

Cas:15243-33-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Triruthenium dodecacarbonyl

Cas:15243-33-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Dodecacarbonyltriruthenium

Cas:15243-33-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ruthenium pentacarbonyl
16406-48-7

ruthenium pentacarbonyl

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In further solvent(s) byproducts: CO; exposure to an N2-atmosphere, hydrocarbon soln.;;100%
In pentane storing of soln. for 1 day under Ar at room temp.;
In neat (no solvent) decompn. of (Ru(CO)5) at room temp.;;
Ru2[μ-η(2)-OC(CF3)O]2(CO)6

Ru2[μ-η(2)-OC(CF3)O]2(CO)6

carbon monoxide
201230-82-2

carbon monoxide

cesium trifluoroacetate
21907-50-6

cesium trifluoroacetate

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

fac-Cs[Ru(CF3COO)3(CO)3]
184584-51-8

fac-Cs[Ru(CF3COO)3(CO)3]

Conditions
ConditionsYield
In tetrahydrofuran CO-atmosphere; stirring Ru-complex soln. (30°C, 8 h); sepn. of Ru3(CO)12, evapn.;A 95%
B 99%
Ru3{μ-H,μ-O=C(NMe2)}(CO)10

Ru3{μ-H,μ-O=C(NMe2)}(CO)10

ethene
74-85-1

ethene

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru2(OCC2H5)(OCN(CH3)2)(CO)6

Ru2(OCC2H5)(OCN(CH3)2)(CO)6

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A n/a
B 98%
K(1+)*RuCl2(CO)2(CO2H)(1-) = K[RuCl2(CO)2(CO2H)]

K(1+)*RuCl2(CO)2(CO2H)(1-) = K[RuCl2(CO)2(CO2H)]

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In 2-methoxy-ethanol byproducts: CO2, KCl; heating the Ru complex and CO in 2-methoxyethanol to 85°C for 20 min; filtration, washing (EtOH);97%
diruthenium(II,III) tetraacetatechloride

diruthenium(II,III) tetraacetatechloride

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With carbon monoxide In methanol; dichloromethane; water High Pressure; dissolving Ru2(CH3COO)4Cl in CH3OH-CH2Cl2-H2O (10:10:1), charging into pressure vessel, pressurizing to 1000 psi with CO, stirring at this pressure for 4 h; venting CO atmosphere, partially removing solvent by vac. distn., pptn.filtration;96%
H(μ-H)Ru3(CO)11

H(μ-H)Ru3(CO)11

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With carbon monoxide In methanol CO atmosphere (room temp., 10 min, stirring), pptn.; redn. of vol. (vac.), filtration off, washing (MeOH): 87.7%; evapn. of filtrate to dryness, chromy. (silica, hexane): 7.9%;95.7%
[Ru(CO)4(η2-ethylene)]
52621-15-5

[Ru(CO)4(η2-ethylene)]

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In n-heptane N2-atmosphere; refluxing for 2 h; solvent removal (vac.), TLC (CH2Cl2/hexane=1:1);95%
tricarbonyldichlororuthenium (II) dimer

tricarbonyldichlororuthenium (II) dimer

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With sodium carbonate In ethylene glycol molar ratio Ru:Na2CO3=1:1; bubbling CO for 5 h at 95°C; extn. of ppt. and sublimate with CH2Cl2 (room temp.), evapn., washing (water);93%
ethene
74-85-1

ethene

Ru3(H)(OCC6H5)(CO)10

Ru3(H)(OCC6H5)(CO)10

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru2(OCC2H5)(OCC6H5)(CO)6

Ru2(OCC2H5)(OCC6H5)(CO)6

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A n/a
B 93%
ruthenium trichloride

ruthenium trichloride

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With triethylamine In propan-1-ol; water at 85℃; under 2625.26 Torr; Concentration; Reagent/catalyst; Solvent; Temperature; Pressure; Autoclave;92.5%
In methanol at 125℃; under 48754.9 Torr; for 8h; Autoclave;
With triethylamine In propan-1-ol at 85℃; under 2625.26 Torr; for 17h; Autoclave; Gas phase;
Ru3(2-)*11CO*2N(P(C6H5)3)2(1+)=(N(P(C6H5)3)2)2(Ru3(CO)11)

Ru3(2-)*11CO*2N(P(C6H5)3)2(1+)=(N(P(C6H5)3)2)2(Ru3(CO)11)

tropylium tetrafluoroborate
27081-10-3

tropylium tetrafluoroborate

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With carbon monoxide In not given dropwise addn. of CO and Ru-cluster soln. (CH2Cl2 or MeCN) to soln. of (C7H7)BF4 (N2 purge, room temp.); IR monitoring;92%
ruthenium trichloride hydrate

ruthenium trichloride hydrate

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With sodium carbonate In ethylene glycol bubbling of CO (1 atm) through a soln. of Ru salt in ethylene glycol for5 min, heating under CO at 110°C for 2 h, cooling to 25°C , addn. of Na2CO3 (Na2CO3:Ru mol. ratio 3:2), heating under CO at 80°C for 7 h; extn. of sublimate and reaction mixt. with dichloromethane at room temp., evapn. to dryness, washing the solid with water and then pentane;91%
With potassium hydroxide In 2-ethoxy-ethanol under CO (1 atm), 1 h at 80°C, 45 min at 135°C, then addedKOH (2 equiv.) at 75°C under CO bubbling;90%
With Fe or stainless steel or Fe-Cr-alloy In ethanol byproducts: RuO2, [RuCl2(CO)3]2; High Pressure; by a react. of Ru-contg. compd. in EtOH soln. at high CO pressure (50 bar) in autoclave in the presence of Fe plate or stainless steel (76% Fe, 17% Cr, 7% Ni) or Fe-Cr alloy (72.8% Fe, 22% Cr, 5% Al, 0.1% Y, 0.1 Zr);at 125°C; react. time: > 3 h; cooling in an ice bath; solid was filtered off and the resulting soln. was evapd. to dryness;80%
Ru3(H)(OCC2H5)(CO)10

Ru3(H)(OCC2H5)(CO)10

ethene
74-85-1

ethene

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

{(μ-propionyl)2(carbonyl)6diruthenium}

{(μ-propionyl)2(carbonyl)6diruthenium}

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A 27%
B 91%
HRu3(CO)10(μ-η2-C(O)CH3)
80800-53-9

HRu3(CO)10(μ-η2-C(O)CH3)

ethene
74-85-1

ethene

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru2(OCC2H5)(OCCH3)(CO)6

Ru2(OCC2H5)(OCCH3)(CO)6

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A n/a
B 91%
carbon monoxide
201230-82-2

carbon monoxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With caesium carbonate In methanol other Radiation; mixt. of RuCl3, Cs2CO3 and MeOH was sealed in microwave app.; CO (50 psi) was introduced; sealed; heated with stirring to 110°C using power of 300 W; held for 10 min; cooled to 50°C; evapd. (vac.); hexane added; heated; solvent removed;90%
With Cu or Zn In ethanol other Radiation; γ irradiation of 1E-3 mol/l RuCl3 in ethanol under CO atmosphere at room temp. in presence of Cu or Zn powder;
With zinc In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
With Zn In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
[Ru(CO)4(η2-ethylene)]
52621-15-5

[Ru(CO)4(η2-ethylene)]

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In n-heptane CO-atmosphere; refluxing for 2 h; TLC (CH2Cl2/hexane=1:1); other unidentified products;90%
Ru3H(H)(CO)11

Ru3H(H)(CO)11

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

H4(ruthenium)4(carbonyl)12

H4(ruthenium)4(carbonyl)12

C

dihydrotetraruthenium tridecacarbonyl

dihydrotetraruthenium tridecacarbonyl

Conditions
ConditionsYield
In dichloromethane-d2 thermal decompn. in soln. at room temp. within 15 min;A 90%
B n/a
C n/a
Ru3H(1+)*10CO*SC6H5(1-)=HRu3(CO)10(SC6H5)

Ru3H(1+)*10CO*SC6H5(1-)=HRu3(CO)10(SC6H5)

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)
105121-22-0

ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

Conditions
ConditionsYield
With CO In hexane refluxing (30 min, bubbling CO); crystn., solvent removal (vac.), dissoln. in CH2Cl2, thin layer chromy.(SiO2, hexane); elem. anal.;A n/a
B 89%
H3Ru3(μ3-methoxymethylidyne)(carbonyl)9
71562-47-5

H3Ru3(μ3-methoxymethylidyne)(carbonyl)9

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

ruthenium pentacarbonyl
16406-48-7

ruthenium pentacarbonyl

C

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
With carbon monoxide; hydrogen In toluene an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;A 89%
B <1
C n/a
Ru3(CO)10H(OCC6H4N(CH3)2)
140111-19-9

Ru3(CO)10H(OCC6H4N(CH3)2)

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

4-dimethylamino-benzaldehyde
100-10-7

4-dimethylamino-benzaldehyde

Conditions
ConditionsYield
With CO In benzene High Pressure; heating (3 bar CO, 90 min, 80°C); chromy. (hexane);A 88%
B 81%
ruthenium(III) chloride trihydrate

ruthenium(III) chloride trihydrate

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With KOH In methanol; 2-methoxy-ethanol byproducts: KCl; heating RuCl3*3H2O and CO in 2-methoxyethanol to 125°C for ca. 2 h, after cooling to 20°C addn. of methanolic KOH, heating to 85°C for 20 min; filtration;86%
In methanol High Pressure; a soln. of RuCl3 in methanol was charged with 2.0 MPa CO and pressurizedto 5.0 MPa, the autoclave was placed in a thermostatic oil bath with st irring for 8 h at 125°C, cooled to room temp.; filtered, recrystd. from toluene;54%
methanol
67-56-1

methanol

bis(dimethylgermyl)methane ruthenium tetracarbonyl
131145-73-8

bis(dimethylgermyl)methane ruthenium tetracarbonyl

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

bis(dimethylmethoxygermyl)methane
131245-48-2

bis(dimethylmethoxygermyl)methane

Conditions
ConditionsYield
the Ru complex reacts with an excess of methanol (6 h 80°C); fractional distn.; elem. anal.;A n/a
B 85%
{HRu3(CO)9(μ3-η2:η2:η2-C6H6)}BF4
128391-81-1

{HRu3(CO)9(μ3-η2:η2:η2-C6H6)}BF4

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru3(CO)9(μ3:η(2):η(2):η(2)-C6H6)
128363-71-3

Ru3(CO)9(μ3:η(2):η(2):η(2)-C6H6)

Conditions
ConditionsYield
With 1,8-diazabicyclo{5.4.0}undec-7-ene In dichloromethane (N2); added dropwise a soln. of N-compound to soln. of Ru-complex; filtered; evapd. (vac.); chromy.;A n/a
B 85%
tricarbonyl-cyclo{dicarbonyl(cyclopentadienyl)molybdenum}-μ3-(ethylmethylidine)-μ3-hydrido(tricarbonylcobalt)ruthenium (Co-Mo, Co-Ru, Mo-Ru)

tricarbonyl-cyclo{dicarbonyl(cyclopentadienyl)molybdenum}-μ3-(ethylmethylidine)-μ3-hydrido(tricarbonylcobalt)ruthenium (Co-Mo, Co-Ru, Mo-Ru)

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

RuCoMo(CO)8Cp(μ3-C=CHMe)

RuCoMo(CO)8Cp(μ3-C=CHMe)

Conditions
ConditionsYield
In toluene byproducts: H2; stirred at 80°C for 1 h; solvent removed under vacuum, chromd. (silica gel, hexane), solvent removed under vacuum from the 2. fraction, crystd. at -30°C;A n/a
B 83%
bis(dimethylgermyl)ethane ruthenium tetracarbonyl
131145-74-9

bis(dimethylgermyl)ethane ruthenium tetracarbonyl

Nitrosobenzene
586-96-9

Nitrosobenzene

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

(CH3)2GeCH2CH2Ge(CH3)2O
120926-63-8

(CH3)2GeCH2CH2Ge(CH3)2O

C

Azobenzene
1227476-15-4

Azobenzene

Conditions
ConditionsYield
In benzene byproducts: CO; the Ru complex reacts in benzene with C6H5NO in a closed tube at 140°C (48 h);A n/a
B 82%
C n/a
Ru4H3(CO)10C6H5PCH2P(C6H5)2
98976-61-5

Ru4H3(CO)10C6H5PCH2P(C6H5)2

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru3(μ-H)(CO)9(μ3-PPhCH2PPh2)

Ru3(μ-H)(CO)9(μ3-PPhCH2PPh2)

Conditions
ConditionsYield
With CO In toluene CO was bubbled through a toluene soln. of complex heated under reflux for 3 h, the soln. was cooled; chromy. on silica gel, eluent heptane-toluene;A 18.7%
B 80.5%
ruthenium(IV) oxide hydrate

ruthenium(IV) oxide hydrate

carbon monoxide
201230-82-2

carbon monoxide

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In toluene stainless steel autoclave; pressurizing with 20 atm CO, heating to 160°C for 2 h (stirring); cooling, collection (filtration), washing (cold PhMe);80%
In further solvent(s) stainless steel autoclave, PhNH2 solvent; pressurizing with 5 atm CO, heating to 160°C for 2 h (stirring); cooling, collection (filtration), washing (cold PhMe);70%
[Ru3(acetonitrile)2(CO)10]

[Ru3(acetonitrile)2(CO)10]

Triethylsilanol
597-52-4

Triethylsilanol

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In acetonitrile N2 atmosphere; stirring (24 h, room temp.);80%
In neat (no solvent) N2 atmosphere; 70°C;
bis(dimethylgermyl)methane ruthenium tetracarbonyl
131145-73-8

bis(dimethylgermyl)methane ruthenium tetracarbonyl

2-propynyl chloride
624-65-7

2-propynyl chloride

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

bis(chlorodimethylgermyl)methane
98187-50-9

bis(chlorodimethylgermyl)methane

Conditions
ConditionsYield
In benzene HCCCH2Cl reacts with the tetracarbonyl ruthenium complex (80°C, 4 h, inert conditions); identification by spectroscopy;A n/a
B 80%
{Ru4(Se2)(CO)8(CO)3}

{Ru4(Se2)(CO)8(CO)3}

bis(diphenylphosphino)acetylene
5112-95-8

bis(diphenylphosphino)acetylene

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru3Se2(CO)7((C6H5)2PCCP(C6H5)2)

Ru3Se2(CO)7((C6H5)2PCCP(C6H5)2)

Conditions
ConditionsYield
In dichloromethane react. under dry N2 using Schlenk and vac.-line techniques; addn. of 1.0 equiv. of the acetylene to Ru-complex in CH2Cl2 with stirring (orange soln.), react. for 1 h at room temp.; TLC (Kiesegel, eluent CH2Cl2-hexane 2:3), orange band, slow evapn. of a CH2Cl2-hexane soln.; elem. anal.;A 20%
B 80%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

carbon monoxide
201230-82-2

carbon monoxide

ruthenium pentacarbonyl
16406-48-7

ruthenium pentacarbonyl

Conditions
ConditionsYield
In hexane Irradiation (UV/VIS); photolysis (>376nm, filtered 250 W high pressure mercury arc) in n-hexane (ca. 6ml of a 1E-4M soln.) under ca. 600Torr CO for 3h;; monitoring of react. by IR;;100%
In tetrahydrofuran High Pressure; 80 bar CO, autoclave; 150°C (5 h);73%
In hexane for 3h; Inert atmosphere; Schlenk technique; UV-irradiation;
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole
118734-49-9

4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole

A

tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)ruthenium
118772-38-6

tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)ruthenium

B

carbon monoxide
201230-82-2

carbon monoxide

Conditions
ConditionsYield
In 1,3,5-trimethyl-benzene Ar atmosphere, heating (140°C, 4 h); filtn., solvent removal (0.001 Torr), sublimation (75-80°C, 0.001 Torr); elem. anal.;A 82%
B 100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

trisodium tris(3-sulfophenyl)phosphine
63995-70-0

trisodium tris(3-sulfophenyl)phosphine

3Na(1+)*Ru3(CO)11(P(C6H4SO3)3)(3-)=Ru3(CO)11(P(C6H4SO3Na)3)

3Na(1+)*Ru3(CO)11(P(C6H4SO3)3)(3-)=Ru3(CO)11(P(C6H4SO3Na)3)

Conditions
ConditionsYield
In methanol N2-atmosphere, molar ratio = 1 : 1; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

trisodium tris(3-sulfophenyl)phosphine
63995-70-0

trisodium tris(3-sulfophenyl)phosphine

6Na(1+)*Ru3(CO)10(P(C6H4SO3)3)2(6-)=Ru3(CO)10(P(C6H4SO3Na)3)2

6Na(1+)*Ru3(CO)10(P(C6H4SO3)3)2(6-)=Ru3(CO)10(P(C6H4SO3Na)3)2

Conditions
ConditionsYield
In methanol N2-atmosphere, molar ratio = 1 : 2; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

trisodium tris(3-sulfophenyl)phosphine
63995-70-0

trisodium tris(3-sulfophenyl)phosphine

9Na(1+)*Ru3(CO)9(P(C6H4SO3)3)3(9-)=Ru3(CO)9(P(C6H4SO3Na)3)3

9Na(1+)*Ru3(CO)9(P(C6H4SO3)3)3(9-)=Ru3(CO)9(P(C6H4SO3Na)3)3

Conditions
ConditionsYield
In methanol N2-atmosphere, molar ratio = 1 : 3; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

(triphenylphosphine)gold(I) chloride
14243-64-2

(triphenylphosphine)gold(I) chloride

acetonitrile
75-05-8

acetonitrile

Ru3(μ-AuPPh3)(μ-Cl)(CO)10

Ru3(μ-AuPPh3)(μ-Cl)(CO)10

Conditions
ConditionsYield
With (CH3)3NO In dichloromethane; acetonitrile (N2), soln. of Me3NO in CH3CN added dropwise to soln. of Ru complex in CH2Cl2 at -78°C over 15 min, slowly warmed to room temp., reacted for 15 min, treated with Au complex, stirred at room temp. for 1.5 h; evapd.(vac.), elem. anal.;100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin
110452-48-7

5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin

acetonitrile
75-05-8

acetonitrile

[acetonitrile][carbonyl][5,10,15,20-tetrakis(4-tertbutylphenyl)porphyrinato]ruthenium(II)

[acetonitrile][carbonyl][5,10,15,20-tetrakis(4-tertbutylphenyl)porphyrinato]ruthenium(II)

Conditions
ConditionsYield
Stage #1: dodecacarbonyl-triangulo-triruthenium; 5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin In 1,2-dichloro-benzene at 160℃; for 12h; Inert atmosphere;
Stage #2: acetonitrile In 1,2-dichloro-benzene at 80℃; for 12h; Inert atmosphere;
100%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

malonic acid
141-82-2

malonic acid

2Ru(1+)*4CO*OOCCH2COO(2-)=[Ru2(CO)4(OOCCH2COO)]

2Ru(1+)*4CO*OOCCH2COO(2-)=[Ru2(CO)4(OOCCH2COO)]

Conditions
ConditionsYield
In 1,4-dioxane; benzene byproducts: CO; Ru3(CO)12 and malonic acid were refluxed in benzene/dioxane under a slow flow of N2 for 24 h;; the solid was filtered off from the hot suspension, washed with dioxaneand diethyl ether, and dried under vac.; elem. anal.;;99.4%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

ruthenium pentacarbonyl
16406-48-7

ruthenium pentacarbonyl

Conditions
ConditionsYield
With CO In n-heptane 133 atm CO, 100°C, 24 h;99%
With carbon monoxide In diethylene glycol Irradiation (UV/VIS); 25°C, 1 atm of CO; UV monitoring; not isolated, detected by IR;
With carbon monoxide In octane Irradiation (UV/VIS); 25°C, 1 atm of CO; UV monitoring; not isolated, detected by IR;
pyridine
110-86-1

pyridine

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

trifluoroacetic acid
76-05-1

trifluoroacetic acid

RuH(CF3CO2)(CO)2(C5H5N)2
166821-97-2, 167073-80-5

RuH(CF3CO2)(CO)2(C5H5N)2

Conditions
ConditionsYield
In pyridine byproducts: CO; 95°C, 10 min; evapn. (reduced pressure), dissoln. in EtOH, Et2O addn., crystn. (0°C); isomer mixt. not sepd.;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

[1,2-bis(diphenylphosphino)ethane]tricarbonylruthenium
58201-22-2

[1,2-bis(diphenylphosphino)ethane]tricarbonylruthenium

Conditions
ConditionsYield
With carbon monoxide; 1,2-bis-(diphenylphosphino)ethane In benzene equimolar amts., 100 atm CO, 100°C, 4-5 h; crystn. (< 0°C, 4-5 h), washing (C6H6, light petroleum), drying (vac.); elem. anal.;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

acetonitrile
75-05-8

acetonitrile

Ru3(CO)10(acetonitrile)2
103257-53-0

Ru3(CO)10(acetonitrile)2

Conditions
ConditionsYield
With trimethylamine-N-oxide In dichloromethane; acetonitrile Ar-atmosphere; dropwise addn. of slight excess Me3NO to Ru-complex soln.(in CH2Cl2/MeCN=10:1) at -78°C, warming to room temp.; evapn. (reduced pressure); elem. anal.;99%
With trimethylamine-N-oxide In dichloromethane soln. of Me3NO added to a soln. of Ru-compd. and CH3CN at 0°C about 15 min, stirred for 1 h; filtered about silica gel, evapd.;
In dichloromethane filtration (degassed SiO2), the soln. kept at -10°C;
With (CH3)3NO In dichloromethane
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

sodium
7440-23-5

sodium

sodium tetracarbonylruthenate(II)

sodium tetracarbonylruthenate(II)

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;99%
In ammonia NH3 (liquid); NH3 distilled onto Na/Ru mixture (acetone/dry ice bath) under vac., slowly warmed to 235 K, vigorously stirred for ca. 60 min, warmed to 260 K; dried (vac., 260 K, 3.5 h);
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

deuterium
16873-17-9

deuterium

β-{Ru4D4(CO)12}

β-{Ru4D4(CO)12}

Conditions
ConditionsYield
In octane byproducts: CO; High Pressure; n-octane added to Ru complex, degassed (vac.), heated at 120°C (bath) under 5 atm (2)H2 for 9 h with intermediate blowings with N2; allowed to cool to room temp. overnight, filtered, dried (vac.);99%
In not given according to Knox et al., J. Am. Chem. Soc., 97 (1975) 3942; Bruce et al., Inorg. Synth., 26 (1989) 262;
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

succinic acid
110-15-6

succinic acid

[Ru2(CO)4(butan-1,4-dioato)](n)

[Ru2(CO)4(butan-1,4-dioato)](n)

Conditions
ConditionsYield
In 1,4-dioxane; toluene byproducts: CO; Ru3(CO)12 and succinic acid were refluxed in toluene/dioxane under a slow flow of N2 for 24 h;; the solid was filtered off from the hot suspension, washed with acetoneand diethyl ether, and dried under vac.; elem. anal.;;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

acetonitrile
75-05-8

acetonitrile

Ru3(CO)9(acetonitrile)

Ru3(CO)9(acetonitrile)

Conditions
ConditionsYield
With trimethylamine-N-oxide In dichloromethane; acetonitrile Ar-atmosphere; dropwise addn. of excess Me3NO to Ru-complex soln. (in CH2Cl2/MeCN=2:5) at -78°C, warming to room temp.; crystn. on slow removal of solvent (reduced pressure); elem. anal.;99%
1,4-dihydroxybut-2-yne
110-65-6

1,4-dihydroxybut-2-yne

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

bis(triphenylphosphine)iminium chloride
21050-13-5

bis(triphenylphosphine)iminium chloride

[PPN][Ru3(μ-Cl)(μ-HOCH2CCCH2OH)(CO)9]

[PPN][Ru3(μ-Cl)(μ-HOCH2CCCH2OH)(CO)9]

Conditions
ConditionsYield
In tetrahydrofuran Ru3(CO)12 and (PPN)Cl (molar ratio 1:1) dissolved in THF; stirred at room temp. for 3 h under N2 bubbling; monitored by IR spectra; ligand (1 equiv.) added; a few min; evapd.;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

1,2-bis(di(pentafluorophenyl)phosphino)ethane
76858-94-1

1,2-bis(di(pentafluorophenyl)phosphino)ethane

Ru3(CO)10(1,2-bis(bis-pentafluorophenylphosphino)ethane)
225779-93-1, 225779-94-2

Ru3(CO)10(1,2-bis(bis-pentafluorophenylphosphino)ethane)

Conditions
ConditionsYield
With catalyst:Ph2CO(1-) In tetrahydrofuran catalyst (8 drops) added to THF soln. of Ru compd. (0.078 mmol), ligand (0.086 mmol) added, stirred, catalyst (8-10 drops added), TLC conrol;99%
With sodium diphenylketyl In tetrahydrofuran under argon, Schlenk setup, 1:2 mixt., heated at 40°C, 5 drops ofsodium diphenylketyl soln. added, stirred (IR control); evapd., dissolved (CH2Cl2), chromd. (silica, C6H12/CH2Cl2), recrystd. (CH2Cl2), elem. anal.;77%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Ph2PC*C-C*CBu(t)
172987-61-0

Ph2PC*C-C*CBu(t)

[Ru3(CO)11(P(C6H5)2CCCCC(CH3)3)]
163727-43-3

[Ru3(CO)11(P(C6H5)2CCCCC(CH3)3)]

Conditions
ConditionsYield
With sodium benzophenone ketyl In tetrahydrofuran99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Ph2PC*C-C*CPh
7608-31-3

Ph2PC*C-C*CPh

[Ru3(CO)11(P(C6H5)2CCCCC6H5)]
163727-44-4

[Ru3(CO)11(P(C6H5)2CCCCC6H5)]

Conditions
ConditionsYield
With sodium benzophenone ketyl In tetrahydrofuran99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

dimethyl(ethoxy)silane
14857-34-2

dimethyl(ethoxy)silane

[Ru2(CO)8(Si(CH3)2(OC2H5))2]

[Ru2(CO)8(Si(CH3)2(OC2H5))2]

Conditions
ConditionsYield
In hexane Irradiation (UV/VIS); (N2); irradiation (180 W mercury lamp, 25°C, 2 h); prepd. as soln. (spectr. yield);99%
In hexane Irradiation (UV/VIS); (N2); reflux (1.5 h); concn., TLC (SiO2; CH2Cl2/hexane);30%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

hydrogen
1333-74-0

hydrogen

H4(ruthenium)4(carbonyl)12

H4(ruthenium)4(carbonyl)12

Conditions
ConditionsYield
In octane byproducts: CO; High Pressure; n-octane added to Ru complex, degassed (vac.), heated at 120°C (bath) under 5 atm H2 for 9 h with intermediate blowings with N2; allowed to cool to room temp. overnight, filtered, dried (vac.);99%
5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin
37083-37-7

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

[Ru(2,6-Cl2tpp)CO]
127390-19-6

[Ru(2,6-Cl2tpp)CO]

Conditions
ConditionsYield
In 1,2,4-trichorobenzene Reflux; Inert atmosphere;99%
5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin
37083-37-7

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin
127390-19-6

carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

Conditions
ConditionsYield
In 1,2,4-Trichlorobenzene at 195 - 200℃; Inert atmosphere;99%
With 1,2,4-Trichlorobenzene at 160 - 165℃; Inert atmosphere;
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

bis[bis(trimethylsilyl)amino]germanium(II)
59863-12-6

bis[bis(trimethylsilyl)amino]germanium(II)

[Ru(Ge(HMDS)2)2(CO)3]
1310738-35-2

[Ru(Ge(HMDS)2)2(CO)3]

Conditions
ConditionsYield
In toluene (N2) Ge(HMDS)2 was added to suspn. (Ru3(CO)12) in toluene and heated at 100°C for 1 h; solvent was removed in vacuo;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

2-(2-methylprop-1-en-1-yl)phenyl formate
1396690-42-8

2-(2-methylprop-1-en-1-yl)phenyl formate

2-oxo-3-isopropyl-2,3-dihydrobenzofuran
4374-68-9

2-oxo-3-isopropyl-2,3-dihydrobenzofuran

Conditions
ConditionsYield
With 1-(1-phenylethyl)-1H-imidazole In 1,3,5-trimethyl-benzene at 135℃; for 24h; Inert atmosphere; Sealed tube; regioselective reaction;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

2-(cyclopent-1-en-1-yl)phenyl formate
1396690-44-0

2-(cyclopent-1-en-1-yl)phenyl formate

A

1,3,3a,9b-tetrahydrocyclopenta[c]chromen-4(2H)-one

1,3,3a,9b-tetrahydrocyclopenta[c]chromen-4(2H)-one

B

spiro-2-one

spiro-2-one

Conditions
ConditionsYield
With 2,4,5-trimethyl-1-phenyl-1H-imidazole In 1,3,5-trimethyl-benzene at 135℃; for 24h; Inert atmosphere; Sealed tube; Overall yield = 75 %; regioselective reaction;A n/a
B 99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

C29H48P2
1620470-32-7

C29H48P2

C31H48O2P2Ru

C31H48O2P2Ru

Conditions
ConditionsYield
In tetrahydrofuran for 20h; Inert atmosphere; Reflux;99%

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