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Quick Details ProName: Ruthenium trichloride CasNo: 10049-08-8 Molecular Formula: RuCl3 Appearance: Dark red crystalline powder Application: materials,chemical DeliveryTime: in stock, deliver against payment

RutheniuM(III) chloride, anhydrous RuCl3

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Ruthenium trichloride Manufacturer/High quality/Best price/In stock

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Henan Allgreen Chemical Co.,Ltd

high quality Located in Zhengdong New District, Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is comprehensive high-tech modern enterprises integrating professional R&D, production and sales. Strong technical force, with a long

Ruthenium trichloride

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ruthenium Trichloride

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% Ruthenium trichloride 10049-08-8 ISO Manufacturer

Cas:10049-08-8

Min.Order:1 Gram

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Henan Tianfu Chemical Co., Ltd.

Ruthenium trichloride Basic information Product Name: Ruthenium trichloride Synonyms: RUTHENIUM TRICHLORIDE;Ruthenium triehloride;Ruthenic chloride;RUTHENIUM CHLORIDE;RUTHENIUM CHLORIDE

best offer Ruthenium trichloride

Cas:10049-08-8

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Ruthenium trichloride CAS 10049-08-8

Cas:10049-08-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 10049-08-8 with best quality

Cas:10049-08-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 10049-08-8 Ruthenium trichloride with best price

Cas:10049-08-8

Min.Order:10 Gram

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Black Powder or Crystals Storage:Keep in dark place,Inert atmosphere,Room temperature Package:25 kg / drum Application:technical analysis in chemistry laboratories. used in the synthesis of 2,3-Pyridinedicarboxylic Acid-13C3, 15N, w

hot saleRuthenium(III) chloride;anhydrous, premion;Ruthenium sesquichloride

Cas:10049-08-8

Min.Order:1 Gram

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ruthenium trichloride 10049-08-8

Cas:10049-08-8

Min.Order:1 Kilogram

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Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Shanghai Minstar Chemical Co., Ltd

Product Name: Ruthenium(III) chloride CAS: 10049-08-8 MF: Cl3Ru MW: 207.43 EINECS: 233-167-5 Melting point 500 °C density 3.11 g/mL at 25 °C (lit.) form Powder or Crystals color Black Water Solubility INSO

Ruthenium(III) chloride

Cas:10049-08-8

Min.Order:1 Gram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Homogeneous catalysis, Ruthenium trichloride CAS:10049-08-8

Cas:10049-08-8

Min.Order:1 Kilogram

FOB Price: $25.0 / 29.0

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Qingdao Beluga Import and Export Co., LTD

Ruthenium(III) chloride CAS:10049-08-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

Ruthenium(III) chloride CAS:10049-08-8

Cas:10049-08-8

Min.Order:1 Gram

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

RutheniuM(III) chloride, anhydrous CAS NO.10049-08-8

Cas:10049-08-8

Min.Order:10 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ruthenium trichloride

Cas:10049-08-8

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ruthenium trichloride

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

Ruthenium(III) chloride CAS 10049-08-8

Cas:10049-08-8

Min.Order:1 Kilogram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ruthenium(III) chloride

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ruthenium trichloride

Cas:10049-08-8

Min.Order:10 Gram

FOB Price: $100.0

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:dark red crystals or powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:10g/bag,or as your request Application:Used as Pharmaceutical Intermedi

Ruthenium trichloride

Cas:10049-08-8

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Ruthenium(III) chloride

Cas:10049-08-8

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity Ruthenium trichloride

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Ruthenium(III)chloride

Cas:10049-08-8

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Ruthenium trichloride CAS NO.10049-08-8

Cas:10049-08-8

Min.Order:1 Kilogram

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

High purity Ruthenium(III) chloride

Cas:10049-08-8

Min.Order:1 Metric Ton

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Ruthenium trichloride

Cas:10049-08-8

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Ruthenium trichloride CAS NO.10049-08-8

Cas:10049-08-8

Min.Order:1 Gram

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Ruthenium trichloride CAS NO.10049-08-8

Cas:10049-08-8

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Synthetic route

ruthenium(IV) chloride
13465-52-6

ruthenium(IV) chloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

C

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With water In water byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;;A n/a
B n/a
C 30%
sodium azide

sodium azide

ruthenium(IV) chloride
13465-52-6

ruthenium(IV) chloride

A

nitrogen
7727-37-9

nitrogen

B

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

C

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In hydrogenchloride
In hydrogenchloride
ruthenium(III) chloride trihydrate

ruthenium(III) chloride trihydrate

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) 140°C, 48 h;
In neat (no solvent) drying under vacuum at 125°C for 15 h;
With thionyl chloride In neat (no solvent) refluxed for 2 h;
H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
hydrogenchloride
7647-01-0

hydrogenchloride

ruthenium(III) hydroxide

ruthenium(III) hydroxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given fuming off with HCl;; impure RuCl3 obtained;;
In neat (no solvent) dried air-free HCl; at 105 °C;;
ruthenium
7440-18-8

ruthenium

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
phosgene
75-44-5

phosgene

ruthenium
7440-18-8

ruthenium

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) at 400 °C;; RuCl3 free from carbon;;
In neat (no solvent) at 400 °C;; carbon-free RuCl3 obtained;;
chlorine
7782-50-5

chlorine

ruthenium
7440-18-8

ruthenium

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) finely dispersed Ru;;
With carbon monoxide In neat (no solvent) at 600-800 °C;; may contain RuCl2*2CO;;
With carbon monoxide In neat (no solvent) passing a stream of carefully dried Cl2 and CO over powdered Ru in a glass tube at 700-800 °C; air excluded;; crystn. after cooling down in a Cl2 stream;;
chlorine
7782-50-5

chlorine

ruthenium
7440-18-8

ruthenium

A

ruthenium(IV) chloride
13465-52-6

ruthenium(IV) chloride

B

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) react. of Ru in a stream of Cl2; react. of formed RuCl3 with Cl2 forming volatile RuCl4; decompn. of RuCl4 on cooling;;
chlorine
7782-50-5

chlorine

ruthenium
7440-18-8

ruthenium

A

Ru2OCl6

Ru2OCl6

B

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) chlorination of Ru at 600-700 °C in SiO2 vessels;; formation of Ru2OCl6 as by-product;;
hydrogenchloride
7647-01-0

hydrogenchloride

ruthenium tetroxide
20427-56-9

ruthenium tetroxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given soln. evapd. at 180 °C under a well dried HCl stream;; product contains 0.04% H;;
In neat (no solvent) byproducts: H2O; dry educts; at 105-115 °C;;
In not given concd. HCl;;
ammonium hexachlororuthenate

ammonium hexachlororuthenate

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
heating in Cl2 atmosphere at 600°C; elem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;
ruthenium(IV) oxide

ruthenium(IV) oxide

chlorine
7782-50-5

chlorine

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With carbon monoxide In neat (no solvent) passing the gas stream over RuO2 at red heat;;
ruthenium(IV) oxide

ruthenium(IV) oxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With carbon monoxide; chlorine In neat (no solvent)
With CO; Cl2 In neat (no solvent)
ruthenium(IV) oxide

ruthenium(IV) oxide

Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent)
ruthenium nitrosylchloride

ruthenium nitrosylchloride

A

ruthenium(IV) oxide

ruthenium(IV) oxide

B

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating to 440 °C in a CO2 atmosphere or in vac.;;
Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With alc. In not given heating;;
With tin(ll) chloride In not given
ruthenium tetroxide
20427-56-9

ruthenium tetroxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride In not given in concd. HCl;;
With HCl In not given in concd. HCl;;
ruthenium(IV) chloride
13465-52-6

ruthenium(IV) chloride

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given in presence of KI;;>99
With hydrogenchloride In not given byproducts: Cl2; in 15% HCl;;
ruthenium(IV) chloride
13465-52-6

ruthenium(IV) chloride

A

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

B

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;;
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;;
In neat (no solvent) equilibrum of gasous RuCl4 with solid RuCl3 and gasous Cl2;;
hydrogen tetrachlorodiaquoruthenate(III)
1039726-55-0, 882561-97-9

hydrogen tetrachlorodiaquoruthenate(III)

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating in a HCl stream to 200 °C;;
In neat (no solvent) heating in a HCl stream to 200 °C;;
ruthenium(V) fluoride
14521-18-7

ruthenium(V) fluoride

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With dichloromethane In dichloromethane byproducts: CHCl2F, HF, CH2ClF; inert atmosphere; excess of CH2Cl2, warming to room temp.; further byproducts;
{Ru(NO)Cl3(water)2} * 3 H2O

{Ru(NO)Cl3(water)2} * 3 H2O

A

ruthenium(IV) oxide

ruthenium(IV) oxide

B

carbon dioxide
124-38-9

carbon dioxide

C

water
7732-18-5

water

D

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) loss of 2 mol H2O on heating at 100 °C or at 25 °C in vac. forming a pink product; further loss of 2 mol H2O at 120-150 °C forming a brick-red product that becomes brown at 360 °C; at 440 °C in vac complete decompn.;; formation of RuCl3, RuO2 and CO2;;
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

dicarbonyldichlororuthenium(II)
16369-40-7

dicarbonyldichlororuthenium(II)

Conditions
ConditionsYield
With CO In 2-methoxy-ethanol RuCl3 dissolved in 2-methoxyethanol, soln. heated at reflux as stream of CO passed into it for 170-210 min; solvent removed at reduced pressure;100%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

5,5'-bis(3-octylthienyl)-2,2'-pyridine
282118-31-4

5,5'-bis(3-octylthienyl)-2,2'-pyridine

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

tris(5,5'-bis(3-octylthienyl)-2,2'-pyridine)ruthenium(II) hexafluorophosphate

tris(5,5'-bis(3-octylthienyl)-2,2'-pyridine)ruthenium(II) hexafluorophosphate

Conditions
ConditionsYield
In ethylene glycol under Ar atm. ethyleneglycol soln. RuCl3 and tpbpy was refluxed at 180°C for 2 h, solvent was removed in vacuo, residue was purified by chromy. on silica using acetone/water/sat.aq.KNO3 94.3/5.6/0.1 as eluent, KPF6 was added;100%
disodium salt of 4,7-diphenyl-1,10-phenanthrolinedisulfonic acid

disodium salt of 4,7-diphenyl-1,10-phenanthrolinedisulfonic acid

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

Ru(C12H6N2(SO3Na)2)3(2+)*2Cl(1-)=[Ru(C12H6N2(SO3Na)2)3]Cl2

Ru(C12H6N2(SO3Na)2)3(2+)*2Cl(1-)=[Ru(C12H6N2(SO3Na)2)3]Cl2

Conditions
ConditionsYield
With sodium hypophosphite In water mixt. (P-salt as reducing agent) refluxing for 40 min, soln. vac. concn., pptn. into acetone; ppt. repptn. from MeOH into acetone twice or three times; elem. anal.;99%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

diammonium pentachloronitrosylruthenate

diammonium pentachloronitrosylruthenate

Conditions
ConditionsYield
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem. 46, 346 (2001);97%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

bis(η5-cyclopentadienyl)ruthenium
1287-13-4

bis(η5-cyclopentadienyl)ruthenium

Conditions
ConditionsYield
With zinc In ethanol a mixt. of RuCl3 and ethanol was stirred for 2-3 h at 20°C; cyclopentadiene (frehly distd.) was added; Zn powder was added gradually (temp. < 30-35°C); the mixt. was stirred at 20°C for 3-4 d; ppt. filtered off, washed (hot C6H6 on filter); filtrates concd. (vac.), chromd. (SiO2, C6H6);95%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

isoprene
78-79-5

isoprene

dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II)

dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II)

Conditions
ConditionsYield
In 2-methoxy-ethanol soln. of RuCl3 in a mixt. of isoprene and 2-methoxyethanol was refluxed for 10 d under N2; crystals were filtered, washed with Et2O and dried in vac, elem. anal.;95%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

2,9-di(pyridin-2-yl)-1,10-phenanthroline
773883-32-2

2,9-di(pyridin-2-yl)-1,10-phenanthroline

A

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)2]Cl2

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)2]Cl2

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)(4-dimethylaminopyridine)2]Cl2

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)(4-dimethylaminopyridine)2]Cl2

Conditions
ConditionsYield
In ethanol phenathroline-compound was treated with RuCl3 in refluxing ethanol followed by the introduction of 4-dimethylaminopyridine;A 5%
B 95%
(p-isopropyltoluene)Ru(Et2C2B3H3)CoC5H5

(p-isopropyltoluene)Ru(Et2C2B3H3)CoC5H5

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

(p-isopropyltoluene)Ru(Et2C2B3H2-4-Cl)CoC5H5

(p-isopropyltoluene)Ru(Et2C2B3H2-4-Cl)CoC5H5

Conditions
ConditionsYield
In water; acetone Ru-Co complex was dissolved in acetone-water and treated with anhydrous RuCl3, after 2 h stirring the solvent was removed; residue was extd. with CH2Cl2, ext. was filtered through silica, filtrate gave on evapn. black-green solid;93%
[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)2]
667938-04-7

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;93%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

4′-(4-phenylphenyl)-2,2′:6′,2″-terpyridine
279674-33-8

4′-(4-phenylphenyl)-2,2′:6′,2″-terpyridine

Ru(4′-biphenyl-2,2′:6′,2″-terpyridine)Cl3
279674-19-0

Ru(4′-biphenyl-2,2′:6′,2″-terpyridine)Cl3

Conditions
ConditionsYield
In ethanol ligand and RuCl3 in EtOH were heated at reflux for 1 h; cooled, ppt. filtered off, washed with ice-cold EtOH;92%
[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[(Ru((bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(H2O))2]

[(Ru((bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(H2O))2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;92%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine
112362-30-8

2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine

Ru(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)Cl3 * 2.5 H2O

Ru(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)Cl3 * 2.5 H2O

Conditions
ConditionsYield
In ethanol equimolar amts.; refluxing under Ar in dark for 1 h; cooling to 25°C, collection (filtration), washing (EtOH), drying (vac.); elem. anal.;92%
[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)2]
667938-03-6

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;91%
[13C]methanol
14742-26-8

[13C]methanol

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

tris(1-methylethyl)phosphine
6476-36-4

tris(1-methylethyl)phosphine

RuHCl((13)CO)(PiPr3)2

RuHCl((13)CO)(PiPr3)2

Conditions
ConditionsYield
With KHCO3 In further solvent(s) (inert atm.); reaction of ruthenium compd. with methanol-(13)C in presecnce of phosphine deriv. and KHCO3; Marchenko A.V., Huffman J.C., ValergaP., Jimenez Tenorio M., Puerta M.C., Caulton K.G., Inorg. Chem., 2001, 40, 6444;91%
potassium nitrite
7758-09-0

potassium nitrite

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

potassium sodium hexanitroruthenate(II)*H2O

potassium sodium hexanitroruthenate(II)*H2O

Conditions
ConditionsYield
With Na(1+); Cl2 In hydrogenchloride heating on a water bath for 30 min; filtn. and dissolving in a minimum of water; elem. anal.;90%
carbon monoxide
201230-82-2

carbon monoxide

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With caesium carbonate In methanol other Radiation; mixt. of RuCl3, Cs2CO3 and MeOH was sealed in microwave app.; CO (50 psi) was introduced; sealed; heated with stirring to 110°C using power of 300 W; held for 10 min; cooled to 50°C; evapd. (vac.); hexane added; heated; solvent removed;90%
With Cu or Zn In ethanol other Radiation; γ irradiation of 1E-3 mol/l RuCl3 in ethanol under CO atmosphere at room temp. in presence of Cu or Zn powder;
With zinc In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
With Zn In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

ethylenediamine
107-15-3

ethylenediamine

[Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)(ethylenediamine)(Cl)]
667938-06-9

[Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)(ethylenediamine)(Cl)]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;90%
tetra[(bis(1,3-dimethylpyrazol-1-yl)dithioacetate)aqualithium]

tetra[(bis(1,3-dimethylpyrazol-1-yl)dithioacetate)aqualithium]

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[bis(bis(1,3-dimethylpyrazol-1-yl)dithio-κ3-N,N,S-acetate)ruthenium(II)]
872977-80-5

[bis(bis(1,3-dimethylpyrazol-1-yl)dithio-κ3-N,N,S-acetate)ruthenium(II)]

Conditions
ConditionsYield
In methanol Kinetics; byproducts: LiCl; inert atm., stoich., a soln. of Ru compd. added to a soln. of Li compd. (4 portions), stirred for 4 h; solvent removed, dissolved (CH2Cl2), filtered, solvent removed (vac.); elem. anal.;90%
5-chlorosalicylaldehyde thiosemicarbazone
68696-06-0

5-chlorosalicylaldehyde thiosemicarbazone

water
7732-18-5

water

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

RuCl(H2O)(H2NC(S)NNC(H)C6H3Cl(OH))2*H2O

RuCl(H2O)(H2NC(S)NNC(H)C6H3Cl(OH))2*H2O

Conditions
ConditionsYield
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; elem. anal.;90%
[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[(Ru((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)Cl(H2O))2]

[(Ru((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)Cl(H2O))2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;90%
4'-(p-decyloxyphenyl)terpyridine
1015459-97-8

4'-(p-decyloxyphenyl)terpyridine

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[(4'-(p-decyloxyphenylyl)terpyridine)RuCl3]
1000374-09-3

[(4'-(p-decyloxyphenylyl)terpyridine)RuCl3]

Conditions
ConditionsYield
In ethanol 1:1 mixt. refluxed;90%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

trans-hydroxotetraamminenitrosoruthenium(II)

trans-hydroxotetraamminenitrosoruthenium(II)

Conditions
ConditionsYield
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem., 46, 346 (2001); M. A. Il'in et al., Russ. J. Inorg. Chem. 53, 1070 (2008);90%
2,2':6,2''-terpyridine
1148-79-4

2,2':6,2''-terpyridine

ammonium tetrafluroborate
13826-83-0

ammonium tetrafluroborate

2-(phenylazo)pyridine
2569-57-5

2-(phenylazo)pyridine

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

sodium nitrite
7632-00-0

sodium nitrite

(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate
359864-76-9

(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Conditions
ConditionsYield
With AgNO3 In water; acetone byproducts: AgCl; RuCl3, 2,2':6',2''-terpyridine gave trichloro(terpyridine)Ru(III); 2-(phenylazo)pyridine added; soln. intermediate Cl(2-(phenyldiazenyl)pyridine)(terpyridine)Ru(II) chloride, AgNO3 in Me2CO/H2O reflux 15 min; NaNO2 added; 1 h heated; NH4BF4 added; 5 d; filtered off; washed (cool H2O, Et2O); crystn. (MeOH:M2CO = 1:1 v/v);88%
[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

ethylenediamine
107-15-3

ethylenediamine

[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]
667938-05-8

[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;88%
2-hydroxy-1-naphthaldehydethiosemicarbazone
85949-64-0

2-hydroxy-1-naphthaldehydethiosemicarbazone

water
7732-18-5

water

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

RuCl(H2O)(H2NC(S)NNC(H)C10H6(OH))2*H2O

RuCl(H2O)(H2NC(S)NNC(H)C10H6(OH))2*H2O

Conditions
ConditionsYield
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; detd. by elem. anal., ESR;87%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

Ru6(methylthiolate)12
1193751-12-0

Ru6(methylthiolate)12

Conditions
ConditionsYield
With HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 85°C for 1 wk; addn. of methanol, keeping at room temp. for 2 d, filtration, washing with ethanol and diethyl ether, drying at room temp., elem. anal.;87%
With HOOCC5H3NC5H3N(COOH); HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 65°C for 1 wk; isolation of crystals, elem. anal.;8.9%
O3SCH(N2C3H(CH3)2)2(1-)

O3SCH(N2C3H(CH3)2)2(1-)

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

ethylenediamine
107-15-3

ethylenediamine

[RuCl2((CH2NH2)2)(O3SCH(N2C3H(CH3)2)2)]
1192123-91-3

[RuCl2((CH2NH2)2)(O3SCH(N2C3H(CH3)2)2)]

Conditions
ConditionsYield
In acetonitrile N2, equimol., stirred for 6 h; evapd., extd. (acetone), evapd. to dryness (vac.); elem. anal.;87%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

1,10-phenanthroline hydrate
5144-89-8

1,10-phenanthroline hydrate

tris(1,10-phenanthroline)ruthenium(II) dichloride

tris(1,10-phenanthroline)ruthenium(II) dichloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide stoich. amt of N-compd. was added to Ru-compd., reflux for 6 h; solvent was evapd., recrystn. hot water;85%
ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

ethyl (diphenylphosphino)acetate
55552-24-4

ethyl (diphenylphosphino)acetate

mer-RuCl3(Ph2PPCH2COOEt)2
103961-34-8

mer-RuCl3(Ph2PPCH2COOEt)2

Conditions
ConditionsYield
In hydrogenchloride; ethanol a soln. of phosphinoacetate in ethanol added slowly to a mixture of RuCl3 in ethanol and aq. HCl; stirred for 15 min; filtered; cooled to -15°C; recrystd. from ethanol/hexane; elem. anal.;85%
2-(2'-pyridyl)benzimidazole
1137-68-4

2-(2'-pyridyl)benzimidazole

ruthenium(III)chloride
10049-08-8

ruthenium(III)chloride

[Ru(C5H4NC7H5N2)2Cl2](1+)*Cl(1-)=[Ru(C5H4NC7H5N2)2Cl2]Cl
348079-89-0

[Ru(C5H4NC7H5N2)2Cl2](1+)*Cl(1-)=[Ru(C5H4NC7H5N2)2Cl2]Cl

Conditions
ConditionsYield
In ethanol mixed, degassed, refluxed for 72 h; solvent evapd. (vac), washed with boiling petrolium ether, recrystd. from hot benzene-ethanol; elem. anal.;85%
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