Quick Details ProName: Ruthenium trichloride CasNo: 10049-08-8 Molecular Formula: RuCl3 Appearance: Dark red crystalline powder Application: materials,chemical DeliveryTime: in stock, deliver against payment
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inquiryRuthenium trichloride Basic information Product Name: Ruthenium trichloride Synonyms: RUTHENIUM TRICHLORIDE;Ruthenium triehloride;Ruthenic chloride;RUTHENIUM CHLORIDE;RUTHENIUM CHLORIDE
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inquiryAppearance:Black Powder or Crystals Storage:Keep in dark place,Inert atmosphere,Room temperature Package:25 kg / drum Application:technical analysis in chemistry laboratories. used in the synthesis of 2,3-Pyridinedicarboxylic Acid-13C3, 15N, w
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inquiryProduct Name: Ruthenium(III) chloride CAS: 10049-08-8 MF: Cl3Ru MW: 207.43 EINECS: 233-167-5 Melting point 500 °C density 3.11 g/mL at 25 °C (lit.) form Powder or Crystals color Black Water Solubility INSO
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inquiryConditions | Yield |
---|---|
With water In water byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;; | A n/a B n/a C 30% |
ruthenium(IV) chloride
A
nitrogen
B
ruthenium(III)chloride
C
sodium chloride
Conditions | Yield |
---|---|
In hydrogenchloride | |
In hydrogenchloride |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In neat (no solvent) 140°C, 48 h; | |
In neat (no solvent) drying under vacuum at 125°C for 15 h; | |
With thionyl chloride In neat (no solvent) refluxed for 2 h; |
H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}
ruthenium(III)chloride
Conditions | Yield |
---|---|
In not given heating;; pure RuCl3 obtained;; |
H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}
ruthenium(III)chloride
Conditions | Yield |
---|---|
In not given heating;; pure RuCl3 obtained;; |
Conditions | Yield |
---|---|
In not given fuming off with HCl;; impure RuCl3 obtained;; | |
In neat (no solvent) dried air-free HCl; at 105 °C;; |
ruthenium
ruthenium(III)chloride
Conditions | Yield |
---|---|
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;; | |
With chlorine | |
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;; | |
With chlorine |
Conditions | Yield |
---|---|
In neat (no solvent) at 400 °C;; RuCl3 free from carbon;; | |
In neat (no solvent) at 400 °C;; carbon-free RuCl3 obtained;; |
Conditions | Yield |
---|---|
In neat (no solvent) finely dispersed Ru;; | |
With carbon monoxide In neat (no solvent) at 600-800 °C;; may contain RuCl2*2CO;; | |
With carbon monoxide In neat (no solvent) passing a stream of carefully dried Cl2 and CO over powdered Ru in a glass tube at 700-800 °C; air excluded;; crystn. after cooling down in a Cl2 stream;; |
chlorine
ruthenium
A
ruthenium(IV) chloride
B
ruthenium(III)chloride
Conditions | Yield |
---|---|
In neat (no solvent) react. of Ru in a stream of Cl2; react. of formed RuCl3 with Cl2 forming volatile RuCl4; decompn. of RuCl4 on cooling;; |
Conditions | Yield |
---|---|
In neat (no solvent) chlorination of Ru at 600-700 °C in SiO2 vessels;; formation of Ru2OCl6 as by-product;; |
Conditions | Yield |
---|---|
In not given soln. evapd. at 180 °C under a well dried HCl stream;; product contains 0.04% H;; | |
In neat (no solvent) byproducts: H2O; dry educts; at 105-115 °C;; | |
In not given concd. HCl;; |
ruthenium(III)chloride
Conditions | Yield |
---|---|
heating in Cl2 atmosphere at 600°C; elem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.; |
Conditions | Yield |
---|---|
With carbon monoxide In neat (no solvent) passing the gas stream over RuO2 at red heat;; |
ruthenium(III)chloride
Conditions | Yield |
---|---|
With carbon monoxide; chlorine In neat (no solvent) | |
With CO; Cl2 In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) heating to 440 °C in a CO2 atmosphere or in vac.;; |
ruthenium(III)chloride
Conditions | Yield |
---|---|
With alc. In not given heating;; | |
With tin(ll) chloride In not given |
ruthenium tetroxide
ruthenium(III)chloride
Conditions | Yield |
---|---|
With hydrogenchloride In not given in concd. HCl;; | |
With HCl In not given in concd. HCl;; |
ruthenium(IV) chloride
ruthenium(III)chloride
Conditions | Yield |
---|---|
In not given in presence of KI;; | >99 |
With hydrogenchloride In not given byproducts: Cl2; in 15% HCl;; |
Conditions | Yield |
---|---|
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;; | |
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;; | |
In neat (no solvent) equilibrum of gasous RuCl4 with solid RuCl3 and gasous Cl2;; |
hydrogen tetrachlorodiaquoruthenate(III)
ruthenium(III)chloride
Conditions | Yield |
---|---|
In neat (no solvent) heating in a HCl stream to 200 °C;; | |
In neat (no solvent) heating in a HCl stream to 200 °C;; |
ruthenium(V) fluoride
ruthenium(III)chloride
Conditions | Yield |
---|---|
With dichloromethane In dichloromethane byproducts: CHCl2F, HF, CH2ClF; inert atmosphere; excess of CH2Cl2, warming to room temp.; further byproducts; |
Conditions | Yield |
---|---|
In neat (no solvent) loss of 2 mol H2O on heating at 100 °C or at 25 °C in vac. forming a pink product; further loss of 2 mol H2O at 120-150 °C forming a brick-red product that becomes brown at 360 °C; at 440 °C in vac complete decompn.;; formation of RuCl3, RuO2 and CO2;; |
ruthenium(III)chloride
dicarbonyldichlororuthenium(II)
Conditions | Yield |
---|---|
With CO In 2-methoxy-ethanol RuCl3 dissolved in 2-methoxyethanol, soln. heated at reflux as stream of CO passed into it for 170-210 min; solvent removed at reduced pressure; | 100% |
potassium hexafluorophosphate
5,5'-bis(3-octylthienyl)-2,2'-pyridine
ruthenium(III)chloride
Conditions | Yield |
---|---|
In ethylene glycol under Ar atm. ethyleneglycol soln. RuCl3 and tpbpy was refluxed at 180°C for 2 h, solvent was removed in vacuo, residue was purified by chromy. on silica using acetone/water/sat.aq.KNO3 94.3/5.6/0.1 as eluent, KPF6 was added; | 100% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
With sodium hypophosphite In water mixt. (P-salt as reducing agent) refluxing for 40 min, soln. vac. concn., pptn. into acetone; ppt. repptn. from MeOH into acetone twice or three times; elem. anal.; | 99% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem. 46, 346 (2001); | 97% |
ruthenium(III)chloride
cyclopenta-1,3-diene
bis(η5-cyclopentadienyl)ruthenium
Conditions | Yield |
---|---|
With zinc In ethanol a mixt. of RuCl3 and ethanol was stirred for 2-3 h at 20°C; cyclopentadiene (frehly distd.) was added; Zn powder was added gradually (temp. < 30-35°C); the mixt. was stirred at 20°C for 3-4 d; ppt. filtered off, washed (hot C6H6 on filter); filtrates concd. (vac.), chromd. (SiO2, C6H6); | 95% |
ruthenium(III)chloride
isoprene
Conditions | Yield |
---|---|
In 2-methoxy-ethanol soln. of RuCl3 in a mixt. of isoprene and 2-methoxyethanol was refluxed for 10 d under N2; crystals were filtered, washed with Et2O and dried in vac, elem. anal.; | 95% |
dmap
ruthenium(III)chloride
2,9-di(pyridin-2-yl)-1,10-phenanthroline
Conditions | Yield |
---|---|
In ethanol phenathroline-compound was treated with RuCl3 in refluxing ethanol followed by the introduction of 4-dimethylaminopyridine; | A 5% B 95% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In water; acetone Ru-Co complex was dissolved in acetone-water and treated with anhydrous RuCl3, after 2 h stirring the solvent was removed; residue was extd. with CH2Cl2, ext. was filtered through silica, filtrate gave on evapn. black-green solid; | 93% |
ruthenium(III)chloride
[(Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)2]
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 93% |
ruthenium(III)chloride
4′-(4-phenylphenyl)-2,2′:6′,2″-terpyridine
Ru(4′-biphenyl-2,2′:6′,2″-terpyridine)Cl3
Conditions | Yield |
---|---|
In ethanol ligand and RuCl3 in EtOH were heated at reflux for 1 h; cooled, ppt. filtered off, washed with ice-cold EtOH; | 92% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 92% |
ruthenium(III)chloride
2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine
Conditions | Yield |
---|---|
In ethanol equimolar amts.; refluxing under Ar in dark for 1 h; cooling to 25°C, collection (filtration), washing (EtOH), drying (vac.); elem. anal.; | 92% |
ruthenium(III)chloride
[(Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)2]
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 91% |
Conditions | Yield |
---|---|
With KHCO3 In further solvent(s) (inert atm.); reaction of ruthenium compd. with methanol-(13)C in presecnce of phosphine deriv. and KHCO3; Marchenko A.V., Huffman J.C., ValergaP., Jimenez Tenorio M., Puerta M.C., Caulton K.G., Inorg. Chem., 2001, 40, 6444; | 91% |
potassium nitrite
ruthenium(III)chloride
Conditions | Yield |
---|---|
With Na(1+); Cl2 In hydrogenchloride heating on a water bath for 30 min; filtn. and dissolving in a minimum of water; elem. anal.; | 90% |
carbon monoxide
ruthenium(III)chloride
dodecacarbonyl-triangulo-triruthenium
Conditions | Yield |
---|---|
With caesium carbonate In methanol other Radiation; mixt. of RuCl3, Cs2CO3 and MeOH was sealed in microwave app.; CO (50 psi) was introduced; sealed; heated with stirring to 110°C using power of 300 W; held for 10 min; cooled to 50°C; evapd. (vac.); hexane added; heated; solvent removed; | 90% |
With Cu or Zn In ethanol other Radiation; γ irradiation of 1E-3 mol/l RuCl3 in ethanol under CO atmosphere at room temp. in presence of Cu or Zn powder; | |
With zinc In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;; | |
With Zn In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;; |
ruthenium(III)chloride
ethylenediamine
[Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)(ethylenediamine)(Cl)]
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 90% |
ruthenium(III)chloride
[bis(bis(1,3-dimethylpyrazol-1-yl)dithio-κ3-N,N,S-acetate)ruthenium(II)]
Conditions | Yield |
---|---|
In methanol Kinetics; byproducts: LiCl; inert atm., stoich., a soln. of Ru compd. added to a soln. of Li compd. (4 portions), stirred for 4 h; solvent removed, dissolved (CH2Cl2), filtered, solvent removed (vac.); elem. anal.; | 90% |
5-chlorosalicylaldehyde thiosemicarbazone
water
ruthenium(III)chloride
Conditions | Yield |
---|---|
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; elem. anal.; | 90% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 90% |
4'-(p-decyloxyphenyl)terpyridine
ruthenium(III)chloride
[(4'-(p-decyloxyphenylyl)terpyridine)RuCl3]
Conditions | Yield |
---|---|
In ethanol 1:1 mixt. refluxed; | 90% |
ruthenium(III)chloride
Conditions | Yield |
---|---|
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem., 46, 346 (2001); M. A. Il'in et al., Russ. J. Inorg. Chem. 53, 1070 (2008); | 90% |
2,2':6,2''-terpyridine
ammonium tetrafluroborate
2-(phenylazo)pyridine
ruthenium(III)chloride
sodium nitrite
(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate
Conditions | Yield |
---|---|
With AgNO3 In water; acetone byproducts: AgCl; RuCl3, 2,2':6',2''-terpyridine gave trichloro(terpyridine)Ru(III); 2-(phenylazo)pyridine added; soln. intermediate Cl(2-(phenyldiazenyl)pyridine)(terpyridine)Ru(II) chloride, AgNO3 in Me2CO/H2O reflux 15 min; NaNO2 added; 1 h heated; NH4BF4 added; 5 d; filtered off; washed (cool H2O, Et2O); crystn. (MeOH:M2CO = 1:1 v/v); | 88% |
ruthenium(III)chloride
ethylenediamine
[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]
Conditions | Yield |
---|---|
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.; | 88% |
2-hydroxy-1-naphthaldehydethiosemicarbazone
water
ruthenium(III)chloride
Conditions | Yield |
---|---|
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; detd. by elem. anal., ESR; | 87% |
Conditions | Yield |
---|---|
With HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 85°C for 1 wk; addn. of methanol, keeping at room temp. for 2 d, filtration, washing with ethanol and diethyl ether, drying at room temp., elem. anal.; | 87% |
With HOOCC5H3NC5H3N(COOH); HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 65°C for 1 wk; isolation of crystals, elem. anal.; | 8.9% |
ruthenium(III)chloride
ethylenediamine
[RuCl2((CH2NH2)2)(O3SCH(N2C3H(CH3)2)2)]
Conditions | Yield |
---|---|
In acetonitrile N2, equimol., stirred for 6 h; evapd., extd. (acetone), evapd. to dryness (vac.); elem. anal.; | 87% |
ruthenium(III)chloride
1,10-phenanthroline hydrate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide stoich. amt of N-compd. was added to Ru-compd., reflux for 6 h; solvent was evapd., recrystn. hot water; | 85% |
ruthenium(III)chloride
ethyl (diphenylphosphino)acetate
mer-RuCl3(Ph2PPCH2COOEt)2
Conditions | Yield |
---|---|
In hydrogenchloride; ethanol a soln. of phosphinoacetate in ethanol added slowly to a mixture of RuCl3 in ethanol and aq. HCl; stirred for 15 min; filtered; cooled to -15°C; recrystd. from ethanol/hexane; elem. anal.; | 85% |
2-(2'-pyridyl)benzimidazole
ruthenium(III)chloride
[Ru(C5H4NC7H5N2)2Cl2](1+)*Cl(1-)=[Ru(C5H4NC7H5N2)2Cl2]Cl
Conditions | Yield |
---|---|
In ethanol mixed, degassed, refluxed for 72 h; solvent evapd. (vac), washed with boiling petrolium ether, recrystd. from hot benzene-ethanol; elem. anal.; | 85% |
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