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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Dimethyl ether

Cas:115-10-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Dimethyl ether

Cas:115-10-6

Min.Order:1

Negotiable

Type:Other

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Dimethyl ether

Cas:115-10-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Dimethyl ether

Cas:115-10-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Dimethyl ether Basic information Product Name: Dimethyl ether Synonyms: (CH3)2O;demeond;Dymel A;dymela;Ether, dimethyl;Ether, methyl;ether,dimethyl;ether,dimethyl- CAS:

TIANFU-CHEM - Dimethyl etherDimethyl ether

Cas:115-10-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Methoxymethane 115-10-6 CAS NO.115-10-6

Cas:115-10-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Dimethyl ether

Cas:115-10-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Dimethyl ether gas

Cas:115-10-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediates Tr

Methane, 1,1'-oxybis-

Cas:115-10-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Dimethyl ether

Cas:115-10-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl Ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers414.Safe and fa

Methyl Ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Dimethyl Ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 115-10-6 with competitive price

Cas:115-10-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methane, 1,1'-oxybis-

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Dimethyl Ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

TIANFUCHEM--High purity 115-10-6 Dimethyl ether Application:TIANFUCHEM--High purity 115-10-6 Dimethyl ether

TIANFUCHEM--High purity 115-10-6 Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

TIANFUCHEM--High purity 115-10-6 Dimethyl etherAppearance:powder Storage:room tempurature Package:As required Application:medical Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea

TIANFUCHEM--High purity 115-10-6 Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jiutai Energy (Zhangjiagang) Co., Limited

1 product : Dimethyl Ether (DME) 2 Names: methyl ether,wood ether ,diemthyl oside 3 UN number :1033 business type : dimethyl ether supplier , dimethyl ether manufacturer , dimethyl ether exporter. applications of dimethyl ether (DME): 1 a

Dimethyl Ether ( DME)

Cas:115-10-6

Min.Order:460 Kilogram

Negotiable

Type:Manufacturers

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Dimethyl ether

Cas:115-10-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

Dimethyl ether gas

Cas:115-10-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

shanghai Longyu biotechnology Co.,Ltd

We have strong R&D center which can support and provide custom synthesis accordingly such as fine chemicals,biotechnique , pharmaceuticals etc.We can provide free sample for our clients to test anf verify the quality of our goods.LongyuChem holds str

Methane, 1,1'-oxybis-

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Dongguan Dayang Aerosol Chemical Technonlgy Co., Ltd.

Sprayidea 92 Multi-purpose frame and lightweight material spray adhesive Advantages 1.Tempopary & Permanent bonding, easy to operate; 2.Eco-friendly, non-toxic; 3.Large coverage, good elasticity and impact resistance;

Sprayidea 92 Multi-purpose frame and lightweight material spray adhesive

Cas:115-10-6

Min.Order:540 Kilogram

FOB Price: $2.85

Type:Other

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

TIANFU-CHEM - Dimethyl etherDimethyl ether

Cas:115-10-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Methane, 1,1'-oxybis-

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Methane, 1,1'-oxybis-

Cas:115-10-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Yierdechem Co. Ltd

With about ten years experiences in the field of pharmaceutical chemicals, Yierdechem has established solid business cooperation relationships with many large companys worldwide.As a leading supplier of API and pharmaceutical intermediates, holds its

Dimethyl ether

Cas:115-10-6

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

methanol
67-56-1

methanol

B

Dimethyl ether
115-10-6

Dimethyl ether

C

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

D

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
With H2O In chloroform-d1 water was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and mixt. was allowed to stand at room temp. for 33 h; detn. by NMR;A 30%
B 16%
C 100%
D 100%
methanol
67-56-1

methanol

2,6-di-tert-butyl-4-methylpyridine
38222-83-2

2,6-di-tert-butyl-4-methylpyridine

methyltriphenylbismuthonium tetrafluoroborate
278172-59-1

methyltriphenylbismuthonium tetrafluoroborate

A

Dimethyl ether
115-10-6

Dimethyl ether

B

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
160142-36-9

2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C

triphenylbismuthane
603-33-8

triphenylbismuthane

Conditions
ConditionsYield
In chloroform-d1 alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;A 69%
B 100%
C 100%
C4H10O2*C10H15(1-)*C24BF20(1-)*Si(2+)

C4H10O2*C10H15(1-)*C24BF20(1-)*Si(2+)

A

1,4-dioxane
123-91-1

1,4-dioxane

B

1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

C

Dimethyl ether
115-10-6

Dimethyl ether

D

Cp*Si(1+)* B(C6F5)4(1-)

Cp*Si(1+)* B(C6F5)4(1-)

Conditions
ConditionsYield
In dichloromethane-d2 for 120h;A n/a
B n/a
C n/a
D 100%
methanol
67-56-1

methanol

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
NaPZSM-5 In water at 250℃; under 7600.51 Torr; Product distribution / selectivity;99%
50 to 70 meshes; silica-alumina catalyst; Aldrich at 225 - 350℃; for 4h;96%
ZSM-5 zeolite on β-silicon carbide at 400℃; under 760.051 Torr; for 18h; Product distribution / selectivity; Inert atmosphere;90%
N-sulfinylmethylamine
4291-05-8, 62248-83-3

N-sulfinylmethylamine

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

A

Dimethyl ether
115-10-6

Dimethyl ether

B

N-Methyl-N-sulfinylmethanaminium tetrafluoroborate
65149-75-9

N-Methyl-N-sulfinylmethanaminium tetrafluoroborate

Conditions
ConditionsYield
at 15℃; for 3h;A n/a
B 99%
methanol
67-56-1

methanol

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

A

Dimethyl ether
115-10-6

Dimethyl ether

B

methyl valerate
624-24-8

methyl valerate

Conditions
ConditionsYield
With water at 255℃; for 23.8333h; Catalytic behavior; Concentration; Time; Reagent/catalyst; Inert atmosphere; Gas phase; chemoselective reaction;A 52.7%
B 98.6%
methanol
67-56-1

methanol

A

formaldehyd
50-00-0

formaldehyd

B

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
molybdenum(VI) oxide In gas at 290 - 350℃; under 750.06 Torr; Thermodynamic data; Product distribution; structure sensitive oxidation with orthorhomb. or microcrystalline MoO3, further temperatures, activation energy EA;A 95%
B 5%
With oxygen; aluminophosphate zeolite at 300℃; Product distribution; temperature, without oxygen, effect of catalysts;
With oxygen; vanadia at 300 - 600℃; Product distribution; further catalysts;
dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

A

methane
34557-54-5

methane

B

Trimethylphosphine oxide
676-96-0

Trimethylphosphine oxide

C

Dimethyl ether
115-10-6

Dimethyl ether

D

magnesium bis(methyl methylphosphonate)

magnesium bis(methyl methylphosphonate)

Conditions
ConditionsYield
With magnesium In neat (no solvent) at 165℃; for 1.5h; Further byproducts given;A n/a
B 4.8 g
C n/a
D 95%
dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

Dimethyl ether
115-10-6

Dimethyl ether

D

monomethyl methylphosphonate lithium salt

monomethyl methylphosphonate lithium salt

Conditions
ConditionsYield
With lithium In neat (no solvent) at 160℃; for 3h; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C n/a
D 95%
dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

A

methane
34557-54-5

methane

B

ethene
74-85-1

ethene

C

Dimethyl ether
115-10-6

Dimethyl ether

D

sodium methyl methanephosphonate
73750-69-3

sodium methyl methanephosphonate

Conditions
ConditionsYield
With sodium In neat (no solvent) at 95℃; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C n/a
D 94.5%
ethylpropylether
628-32-0

ethylpropylether

A

Dimethyl ether
115-10-6

Dimethyl ether

B

ethyl methyl ether
540-67-0

ethyl methyl ether

C

methyl propyl ether
557-17-5

methyl propyl ether

D

2-butyl ethyl ether
625-54-7

2-butyl ethyl ether

Conditions
ConditionsYield
Product distribution; Mechanism; Ambient temperature; Irradiation;A n/a
B 2.4%
C 4.4%
D 93.2%
ethylpropylether
628-32-0

ethylpropylether

diazomethane-d2
14621-84-2

diazomethane-d2

A

Dimethyl ether
115-10-6

Dimethyl ether

B

ethyl methyl ether
540-67-0

ethyl methyl ether

C

methyl propyl ether
557-17-5

methyl propyl ether

D

2-butyl ethyl ether
625-54-7

2-butyl ethyl ether

Conditions
ConditionsYield
Product distribution; Mechanism; Ambient temperature; Irradiation; deuterium distribution;A n/a
B 3.3%
C 4.2%
D 92.5%
methanol
67-56-1

methanol

1-(1-naphthyl)-3-phenyl-2,2-dichloroaziridine
31528-95-7

1-(1-naphthyl)-3-phenyl-2,2-dichloroaziridine

A

methylene chloride
74-87-3

methylene chloride

B

Dimethyl ether
115-10-6

Dimethyl ether

C

methyl 2-chloro-2-phenylethanoate
7476-66-6

methyl 2-chloro-2-phenylethanoate

D

methyl 2-methoxy-2-phenylacetate
3558-61-0

methyl 2-methoxy-2-phenylacetate

E

1-naphthylamine hydrochloride
552-46-5

1-naphthylamine hydrochloride

Conditions
ConditionsYield
Product distribution; Heating;A n/a
B n/a
C n/a
D n/a
E 91%
(9R,10S,11S,12R)-11,12-bis(methoxymethyl)-9,10-dihydro-9,10-ethanoanthracene

(9R,10S,11S,12R)-11,12-bis(methoxymethyl)-9,10-dihydro-9,10-ethanoanthracene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

(9R,10S,11R,15S)-9,10-dihydro-9,10-[3,4]furanoanthracene

(9R,10S,11R,15S)-9,10-dihydro-9,10-[3,4]furanoanthracene

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In hexane at 100℃; for 18h; Glovebox;A n/a
B 91%
methoxybenzene
100-66-3

methoxybenzene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

cyclohexane
110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In decalin at 20 - 220℃; under 37503.8 - 45004.5 Torr; Inert atmosphere; Autoclave;A 5.6%
B 90.3%
tetraethylammonium iodide
68-05-3

tetraethylammonium iodide

A

Dimethyl ether
115-10-6

Dimethyl ether

B

tetraethylammonium pyrosulfate

tetraethylammonium pyrosulfate

C

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
With dimethyl sulfate at 130℃; for 0.5h; Product distribution;A n/a
B 90%
C n/a
With dimethyl sulfate at 130℃; for 0.5h;A n/a
B 90%
C n/a
H3Ru3(μ3-methoxymethylidyne)(carbonyl)9
71562-47-5

H3Ru3(μ3-methoxymethylidyne)(carbonyl)9

A

dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

ruthenium pentacarbonyl
16406-48-7

ruthenium pentacarbonyl

C

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
With carbon monoxide; hydrogen In toluene an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;A 89%
B <1
C n/a
((2R,3S)-1,4-dimethoxybutane-2,3-diyl)dibenzene

((2R,3S)-1,4-dimethoxybutane-2,3-diyl)dibenzene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

(3R,4S)-3,4-diphenyltetrahydrofuran
1393686-95-7

(3R,4S)-3,4-diphenyltetrahydrofuran

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In hexane at 100℃; for 48h; Glovebox;A n/a
B 88%
(1R,2R,3S,4S)-2,3-bis(methoxymethyl)-1,2,3,4-tetrahydro-1,4-methanonaphthalene

(1R,2R,3S,4S)-2,3-bis(methoxymethyl)-1,2,3,4-tetrahydro-1,4-methanonaphthalene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

(3aR,4R,9S,9aS)-1,3,3a,4,9,9a-hexahydro-4,9-methanonaphtho[2,3-c]furan

(3aR,4R,9S,9aS)-1,3,3a,4,9,9a-hexahydro-4,9-methanonaphtho[2,3-c]furan

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In hexane at 100℃; for 18h; Glovebox;A n/a
B 87%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

A

methane
34557-54-5

methane

B

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
With methyl iodide; aluminum oxide; tin at 250℃; under 8360 Torr;A 0.7%
B 86.3%
methylene chloride
74-87-3

methylene chloride

potassium hydrogencarbonate
298-14-6

potassium hydrogencarbonate

A

Dimethyl ether
115-10-6

Dimethyl ether

B

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
tetrahexylammonium chloride In N,N-dimethyl acetamide at 150℃;A n/a
B 86%
Na[(η5-cyclopentadienyl)(nitrosyl)(carbonyl)(cyano)Mo]

Na[(η5-cyclopentadienyl)(nitrosyl)(carbonyl)(cyano)Mo]

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

A

sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

B

Dimethyl ether
115-10-6

Dimethyl ether

C

[(η5-cyclopentadienyl)Mo(nitrosyl)(carbonyl)(CNCH3)]

[(η5-cyclopentadienyl)Mo(nitrosyl)(carbonyl)(CNCH3)]

Conditions
ConditionsYield
In acetonitrile under N2, Mo complex dissolved in CH3CN, Me3OBF4 added, stirred at roomtemp. for 0.5 h; evapd., C6H6 added to residue, filtered, solvent removed, dried in vac., recrystd. from hexane with small quantity of CH2Cl2 at -50°C, elem. anal.;A n/a
B n/a
C 85%
C10H15N3O

C10H15N3O

buta-1,3-diene
106-99-0

buta-1,3-diene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

C12H15N3

C12H15N3

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 1,1-bis-(diphenylphosphino)ethene In 1,4-dioxane; toluene at 160℃; for 72h; Molecular sieve; Glovebox; Sealed tube; regioselective reaction;A n/a
B 85%
1-(1,5-dimethoxypentan-3-yl)-4-fluorobenzene

1-(1,5-dimethoxypentan-3-yl)-4-fluorobenzene

A

Dimethyl ether
115-10-6

Dimethyl ether

B

4-(4-fluorophenyl)tetrahydro-2H-pyran

4-(4-fluorophenyl)tetrahydro-2H-pyran

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In hexane at 100℃; for 48h; Glovebox;A n/a
B 84%
2,3-dimethylnaphtho<1,2-d>thiazolium methyl sulfate
64415-17-4

2,3-dimethylnaphtho<1,2-d>thiazolium methyl sulfate

A

ethene
74-85-1

ethene

B

Dimethyl ether
115-10-6

Dimethyl ether

C

2,3-dimethylnaphtho<1,2-d>thiazolium bisulfate

2,3-dimethylnaphtho<1,2-d>thiazolium bisulfate

D

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
With dimethyl sulfate at 130℃; for 0.666667h;A n/a
B n/a
C 82%
D n/a
Na[(η5-cyclopentadienyl)(nitrosyl)(cyano)Cr]

Na[(η5-cyclopentadienyl)(nitrosyl)(cyano)Cr]

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

A

sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

B

Dimethyl ether
115-10-6

Dimethyl ether

C

[(η5-cyclopentadienyl)Cr(nitrosyl)(carbonyl)(CNCH3)]

[(η5-cyclopentadienyl)Cr(nitrosyl)(carbonyl)(CNCH3)]

Conditions
ConditionsYield
In acetonitrile under N2, Cr complex dissolved in CH3CN, Me3OBF4 added, stirred at roomtemp. for 0.5 h; evapd., C6H6 added to residue, filtered, solvent removed, dried in vac., recrystd. from hexane with small quantity of CH2Cl2 at -50°C, elem. anal.;A n/a
B n/a
C 82%
(1,4-dimethoxybutan-2-yl)benzene
71053-00-4

(1,4-dimethoxybutan-2-yl)benzene

A

5-phenyl-3,4-dihydro-2H-pyran
16766-63-5

5-phenyl-3,4-dihydro-2H-pyran

B

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In hexane at 100℃; for 48h; Glovebox;A 82%
B n/a
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

A

Dimethyl ether
115-10-6

Dimethyl ether

B

acetic acid methyl ester
79-20-9

acetic acid methyl ester

C

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With Chloro(η4-cycloocta-1,5-dien)(2-diphenylphosphano-ethyl-phosphonsaeuredimethylester)rhodium(I); methyl iodide at 80℃; under 4125.3 Torr; for 5h; Product distribution; var. Rh-catalysts, var. temp.;A 5.2%
B 80.3%
C 1.1%
Rh on zeolites at 209.9℃; under 750.06 Torr; Product distribution; variation of catalysts;
With methyl iodide; [BMIM][Rh(CO)2I2]-[BMIM]I-SiO2 at 180℃; under 15001.5 Torr; for 1.5h; Product distribution; Further Variations:; Pressures; time;
Na[(η5-cyclopentadienyl)(nitrosyl)(carbonyl)(cyano)W]

Na[(η5-cyclopentadienyl)(nitrosyl)(carbonyl)(cyano)W]

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

A

sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

B

Dimethyl ether
115-10-6

Dimethyl ether

C

[(η5-cyclopentadienyl)W(nitrosyl)(carbonyl)(CNCH3)]

[(η5-cyclopentadienyl)W(nitrosyl)(carbonyl)(CNCH3)]

Conditions
ConditionsYield
In acetonitrile under N2, W complex dissolved in CH3CN, Me3OBF4 added, stirred at room temp. for 0.5 h; evapd., C6H6 added to residue, filtered, solvent removed, dried in vac., recrystd. from hexane with small quantity of CH2Cl2 at -50°C, elem. anal.;A n/a
B n/a
C 79%
Dimethyl ether
115-10-6

Dimethyl ether

A

formaldehyd
50-00-0

formaldehyd

B

Methyl formate
107-31-3

Methyl formate

Conditions
ConditionsYield
With nitrogen; oxygen at 239.84℃; Conversion of starting material;A 99.7%
B 0.3%
With nitrogen; oxygen at 239.84℃; Conversion of starting material;A 98.8%
B 1.2%
With nitrogen; oxygen at 239.84℃; Conversion of starting material;A 98.6%
B 1.4%
Dimethyl ether
115-10-6

Dimethyl ether

phenylacetonitrile
140-29-4

phenylacetonitrile

ethyl 2-phenylacetimidate hydrochloride
5442-34-2

ethyl 2-phenylacetimidate hydrochloride

Conditions
ConditionsYield
With hydrogenchloride 1.) 0 deg C, 3 h 2.) 4 d;99%
5-methylpyrazin-2-amine
5521-58-4

5-methylpyrazin-2-amine

Dimethyl ether
115-10-6

Dimethyl ether

dimethyaluminium chloride

dimethyaluminium chloride

ethyl 4-(5-(ethyl(methyl)carbamoyl)pyrazin-2-yloxy)-2-methylbenzofuran-6-carboxylate
1245604-04-9

ethyl 4-(5-(ethyl(methyl)carbamoyl)pyrazin-2-yloxy)-2-methylbenzofuran-6-carboxylate

N-ethyl-N-methyl-5-(2-methyl-6-((5-methylpyrazin-2-yl)carbamoyl)-benzofuran-4-yloxy)pyrazine-2-carboxamide
1245603-97-7

N-ethyl-N-methyl-5-(2-methyl-6-((5-methylpyrazin-2-yl)carbamoyl)-benzofuran-4-yloxy)pyrazine-2-carboxamide

Conditions
ConditionsYield
In hexane99%
Dimethyl ether
115-10-6

Dimethyl ether

boron trifluoride diethyl etherate
109-63-7

boron trifluoride diethyl etherate

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

Conditions
ConditionsYield
With epichlorohydrin In dichloromethane Cooling with acetone-dry ice; Inert atmosphere;98%
Dimethyl ether
115-10-6

Dimethyl ether

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

A

N,N-bis(trifluoromethyl)hydroxylamine
359-63-7

N,N-bis(trifluoromethyl)hydroxylamine

B

Bis--peroxid
10545-15-0

Bis--peroxid

C

O-Methoxymethyl-N,N-bis-trifluoromethyl-hydroxylamine
78073-45-7

O-Methoxymethyl-N,N-bis-trifluoromethyl-hydroxylamine

D

O-(N,N-Bis-trifluoromethyl-aminooxymethoxymethyl)-N,N-bis-trifluoromethyl-hydroxylamine
78073-46-8

O-(N,N-Bis-trifluoromethyl-aminooxymethoxymethyl)-N,N-bis-trifluoromethyl-hydroxylamine

Conditions
ConditionsYield
at 20℃; for 15h;A 92%
B n/a
C 95%
D 5.5%
Dimethyl ether
115-10-6

Dimethyl ether

sulfoxid
87108-79-0

sulfoxid

2,2,2-Trifluor-1-trifluormethylethansulfinsaeure-ethylester
109746-43-2

2,2,2-Trifluor-1-trifluormethylethansulfinsaeure-ethylester

Conditions
ConditionsYield
In dichloromethane at -60℃; for 2.5h; Irradiation;94%
Dimethyl ether
115-10-6

Dimethyl ether

[Ir(η5-Cp*)(η2-o-C6H4PPh2)(OTf)]
198146-95-1

[Ir(η5-Cp*)(η2-o-C6H4PPh2)(OTf)]

(C10H15)Ir(H)(C6H5)3PCHOCH3(1+)*CF3SO3(1-)=[(C10H15)Ir(C6H5)3PCH2OCH3]CF3SO3

(C10H15)Ir(H)(C6H5)3PCHOCH3(1+)*CF3SO3(1-)=[(C10H15)Ir(C6H5)3PCH2OCH3]CF3SO3

Conditions
ConditionsYield
In dichloromethane94%
Dimethyl ether
115-10-6

Dimethyl ether

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; epichlorohydrin In dichloromethane at -20℃;92%
2-Fluoro-4'-methoxy-[1,1'-biphenyl]-4-acetic acid

2-Fluoro-4'-methoxy-[1,1'-biphenyl]-4-acetic acid

Dimethyl ether
115-10-6

Dimethyl ether

2-fluoro-4'-hydroxy-[1,1'-biphenyl]-4-acetic acid

2-fluoro-4'-hydroxy-[1,1'-biphenyl]-4-acetic acid

Conditions
ConditionsYield
With hydrogen bromide In water; acetic acid92%
With hydrogen bromide In water; acetic acid92%
Dimethyl ether
115-10-6

Dimethyl ether

o-hydroxyacetophenone
118-93-4

o-hydroxyacetophenone

2-Methoxyacetophenone
579-74-8

2-Methoxyacetophenone

Conditions
ConditionsYield
With iron(III) chloride; phosphomolybdic acid at 80℃; for 4h; Reagent/catalyst; Temperature;92%
Dimethyl ether
115-10-6

Dimethyl ether

methyl cyclopropylcarboxylate
2868-37-3

methyl cyclopropylcarboxylate

trimethyl orthocyclopropanecarboxylate
54917-76-9

trimethyl orthocyclopropanecarboxylate

Conditions
ConditionsYield
With boron trifluoride In Hexadecane at 110℃; for 12h; Autoclave;91%
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