1,1,1,3,3,3-hexafluoro-2,2-di(3,4-dicarboxyphenyl)-propane
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
at 250℃; for 3h; Temperature; | 89% |
With 2,6-bis[(2,2,6,6-tetramethylpiperidin-1-yl)methyl]phenylboronic acid In propyl cyanide for 12h; Reflux; | 85% |
In o-xylene at 180℃; for 3h; | 3.5 g |
acetic anhydride
4,4'-(perfluoropropane-2,2-diyl)bis(1,2-dimethylbenzene)
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Stage #1: 4,4'-(hexafluoroisopropylidene)-bis-(o-xylene) With pyridine; potassium permanganate In water at 100℃; for 3h; Stage #2: acetic anhydride In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 0.666667h; Temperature; | 79% |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: AlCl3 / 16 h / 110 °C 2: aq. KMnO4 / pyridine / 12 h / Heating 3: 3.5 g / o-xylene / 3 h / 180 °C View Scheme | |
Multi-step reaction with 3 steps 1: 69 percent / HF / 18 h / 130 °C / 22065.2 Torr 2: aq. KMnO4 / pyridine / 12 h / Heating 3: 3.5 g / o-xylene / 3 h / 180 °C View Scheme |
4,4'-(perfluoropropane-2,2-diyl)bis(1,2-dimethylbenzene)
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aq. KMnO4 / pyridine / 12 h / Heating 2: 3.5 g / o-xylene / 3 h / 180 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: benzenesulfonic acid / dichloromethane / 60 h / 150 - 160 °C / Inert atmosphere 2: water; potassium hydroxide / methanol / 40 h / 110 °C 3: acetic anhydride / toluene / 10 h / 120 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: Reflux 1.2: 17 h / 115 °C / 7980.54 Torr / Autoclave; Inert atmosphere 2.1: pyridine; potassium permanganate / water / 3 h / 100 °C / pH 1 3.1: 3 h / 250 °C View Scheme |
N-butylphthalimide
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: iron(III) chloride; sulfuric acid / 80 h / 100 °C 2: water; potassium hydroxide / 18 h / 95 °C 3: 3 h / 250 °C View Scheme |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: water; potassium hydroxide / 18 h / 95 °C 2: 3 h / 250 °C View Scheme |
2,2-bis(3-nitro-4-hydroxyphenyl)hexafluoropropane
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: palladium on activated charcoal; hydrogen / 2-methyl-propan-1-ol; acetic acid butyl ester 2: ammonia 3: nitrosylsulfuric acid / acetic acid 4: water 5: Heating; Acidic conditions 6: Heating View Scheme | |
Multi-step reaction with 6 steps 1: hydrogen; palladium on activated charcoal / butan-1-ol; acetic acid butyl ester 2: ammonia 3: nitrosyl sulphuric acid / acetic acid 4: urea 5: Heating; Acidic conditions 6: Heating View Scheme |
2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: ammonia 2: nitrosylsulfuric acid / acetic acid 3: water 4: Heating; Acidic conditions 5: Heating View Scheme | |
Multi-step reaction with 5 steps 1: ammonia 2: nitrosyl sulphuric acid / acetic acid 3: urea 4: Heating; Acidic conditions 5: Heating View Scheme |
2,2-bis(3,4-di-o-aminophenyl)hexafluoropropane
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: nitrosylsulfuric acid / acetic acid 2: water 3: Heating; Acidic conditions 4: Heating View Scheme | |
Multi-step reaction with 4 steps 1: nitrosyl sulphuric acid / acetic acid 2: urea 3: Heating; Acidic conditions 4: Heating View Scheme |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: water 2: Heating; Acidic conditions 3: Heating View Scheme | |
Multi-step reaction with 3 steps 1: urea 2: Heating; Acidic conditions 3: Heating View Scheme |
[(m-aminophenylamino)-4-aminophenylmethylidene]propanedinitrile
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
polyimide, Mw = 51000; monomer(s): [(m-aminophenylamino)-4-aminophenylmethylidene]propanedinitrile; 4,4'-hexafluoroisopropylidene diphthalic anhydride
Conditions | Yield |
---|---|
In 1-methyl-pyrrolidin-2-one; chlorobenzene at 20 - 190℃; | 100% |
3,3'-bis(N-aminophthalimide)
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
polymer, Mn/Mw = 1.1, Mn = 30370 g/mol, Mw = 32910 g/mol, inherent viscosity = 0.35 dL/g; monomer(s): 3,3\-bis(N-aminophthalimide); 4,4\-(hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With 4-chloro-phenol; benzoic acid at 100 - 190℃; | 98% |
N-(4-aminophenyl)-N-phenyl-1-aminopyrene
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
4,4'-hexafluoroisopropylidenebis[4-(N-phenyl-N-pyren-1-ylamino)phenylphthalimide]
Conditions | Yield |
---|---|
Stage #1: N-(4-aminophenyl)-N-phenyl-1-aminopyrene; 4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride In tetrahydrofuran at 20℃; for 1h; Stage #2: for 4h; Reflux; | 98% |
2-methyl-2-propenoic acid 2-hydroxyethyl ester
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With dmap; 2,6-di-tert-butyl-4-methyl-phenol; 4-methoxy-phenol at 90℃; for 1h; Concentration; | 98% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Stage #1: 2,5-bis(m-aminobenzoyloxy)terephthalic acid bis(2-hydroxychalcone) ester; 4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Stage #2: With 3-Methylpyridine; acetic anhydride In N,N-dimethyl-formamide at 20 - 120℃; for 2h; | 97.4% |
3.5-diaminobenzoic acid
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
In various solvent(s) at 200℃; | 97.3% |
3.5-diaminobenzoic acid
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
In 3-methyl-phenol at 60 - 200℃; | 97% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
2-amino-3-(4-chlorophenyl)-1,8-naphthyridine
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.15h; Milling; Green chemistry; | 97% |
2-amino-3-(4-fluorophenyl)-1,8-naphthyridine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.141667h; Milling; Green chemistry; | 97% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
Stage #1: 2,5-bis(m-aminobenzoyloxy)terephthalic acid bis(2-cinnamoyloxyethyl) ester; 4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Stage #2: With 3-Methylpyridine; acetic anhydride In N,N-dimethyl-formamide at 20 - 120℃; for 2h; | 96.5% |
3-amino-5-ethynylbenzoic acid
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With acetic acid at 118℃; for 24h; Inert atmosphere; | 96.09% |
N-Methyldiethanolamine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
di(4-isocyanatophenyl)methane
polymer, product of diol-diisocyanate condensation followed by polycondensation with dianhydride and heating; monomer(s): 4,4\-methylenebis(phenyl isocyanate); N-methyldiethanolamine; 4,4\-(hexafluoroisopropylidene)bis(phthalic anhydride)
Conditions | Yield |
---|---|
Stage #1: N-Methyldiethanolamine; di(4-isocyanatophenyl)methane In N,N-dimethyl-formamide at 20℃; for 1h; Stage #2: 4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride In N,N-dimethyl-formamide at 60 - 80℃; Stage #3: for 15h; Heating; vacuum; | 96% |
L-phenylalanine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
C37H24F6N2O8
Conditions | Yield |
---|---|
With acetic acid at 20℃; Reflux; | 95% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide for 0.0916667h; Solvent; Time; Reagent/catalyst; Microwave irradiation; Green chemistry; | 95% |
2-hydrazino-3-(4-fluorophenyl)-1,8-naphthyridine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide for 0.1h; Solvent; Time; Reagent/catalyst; Microwave irradiation; Green chemistry; | 95% |
3-[3-(trifluoromethyl)phenyl][1,8]naphthyridin-2-amine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.133333h; Milling; Green chemistry; | 95% |
C15H10F3N3
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.15h; Milling; Green chemistry; | 95% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.141667h; Milling; Green chemistry; | 95% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
2,2'-(4,4'-hexafluoroisopropylidene)-bis(5-aminobenzimidazole)
Conditions | Yield |
---|---|
With 1-methyl-pyrrolidin-2-one In toluene at 140 - 190℃; | 94% |
L-alanin
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
C25H16F6N2O8
Conditions | Yield |
---|---|
With acetic acid at 20℃; Reflux; | 94% |
C15H11F3N4
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide for 0.0916667h; Solvent; Time; Reagent/catalyst; Microwave irradiation; Green chemistry; | 94% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
2-hydrazino-3-(2-chlorophenyl)-1,8-naphthyridine
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide for 0.0916667h; Solvent; Time; Reagent/catalyst; Microwave irradiation; Green chemistry; | 94% |
2-hydrazino-3-(2-fluorophenyl)-1,8-naphthyridine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide for 0.0833333h; Solvent; Time; Reagent/catalyst; Microwave irradiation; Green chemistry; | 94% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
2-amino-3-(o-chlorophenyl)-1,8-naphthyridine
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.133333h; Milling; Green chemistry; | 94% |
2-amino-3-(2-fluorophenyl)-1,8-naphthyridine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.141667h; Milling; Green chemistry; | 94% |
2-amino-3-(3-fluorophenyl)-1,8-naphthyridine
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.133333h; Milling; Green chemistry; | 94% |
4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic anhydride
2-amino-3-phenyl-1,8-naphthyridine
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In neat (no solvent, solid phase) at 20℃; for 0.116667h; Milling; Green chemistry; | 94% |
The Molecular Structure of 1,3-Isobenzofurandione, 5,5'-(2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis- (CAS NO.1107-00-2):
Empirical Formula: C19H6F6O6
Molecular Weight: 444.2378
IUPAC: 5-[2-(1,3-dioxo-2-benzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-benzofuran-1,3-dione
Product Categories: Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research);Bisphenol AF type Compounds (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;Anhydride Monomers;Monomers;Polymer Science
Nominal Mass: 444 Da
Average Mass: 444.2378 Da
Monoisotopic Mass: 444.006857 Da
Index of Refraction: 1.556
Molar Refractivity: 84.17 cm3
Molar Volume: 261.7 cm3
Surface Tension: 50.2 dyne/cm
Density: 1.697 g/cm3
Flash Point: 243.7 °C
Enthalpy of Vaporization: 76.19 kJ/mol
Boiling Point: 494.5 °C at 760 mmHg
Vapour Pressure: 6.4E-10 mmHg at 25°C
Sensitive: Moisture Sensitive
InChI
InChI=1/C19H6F6O6/c20-18(21,22)17(19(23,24)25,7-1-3-9-11(5-7)15(28)30-13(9)26)8-2-4-10-12(6-8)16(29)31-14(10)27/h1-6H
Smiles
C(C(F)(F)F)(C(F)(F)F)(c1cc2c(cc1)C(=O)OC2=O)c1cc2C(OC(=O)c2cc1)=O
Hazard Codes: CXi
Risk Statements: 34
R34: Causes burns
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3261 8/PG 2
WGK Germany: 1
F 21: Sensitive to humidity
Hazard Note: Irritant
TSCA: T
HazardClass: 8
PackingGroup: II
1,3-Isobenzofurandione, 5,5'-(2,2,2-trifluoro-1-(trifluoromethyl)ethylidene)bis- (CAS NO.1107-00-2) is also called as 2,2'-Bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride ; 4,4'-(Hexafluoroisopropylidene)bis(phthalic anhydride) ; EINECS 214-170-0 ; 4,4'-(2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene)diphthalic anhydride .
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