Conditions | Yield |
---|---|
With xylene anschliessende Behandlung mit wss. NaOH und Erhitzen des Reaktionsprodukts mit ZnCl2 und NaCl auf 290grad; |
Conditions | Yield |
---|---|
With aluminium trichloride; benzene at 60℃; | |
With aluminium trichloride; benzene at 60℃; |
Dibenzo[a,e]pyrene
Conditions | Yield |
---|---|
at 400 - 410℃; |
Dibenzo[a,e]pyrene
Conditions | Yield |
---|---|
With air Formation of xenobiotics; Heating; |
Dibenzo[a,e]pyrene
Conditions | Yield |
---|---|
With air Formation of xenobiotics; Heating; |
Dibenzo[a,e]pyrene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane; acetonitrile at 20℃; for 24h; | 70.4% |
Dibenzo[a,e]pyrene
8-Nitronaphtho<1,2,3,4-def>chrysene
Conditions | Yield |
---|---|
With nitric acid In acetic anhydride Ambient temperature; | 40% |
Dibenzo[a,e]pyrene
A
8,14-diacetoxy-naphtho[1,2,3,4-def]chrysene
B
Acetic acid naphtho[1,2,3,4-def]chrysen-8-yl ester
Conditions | Yield |
---|---|
In acetic acid; benzene at 40℃; for 7h; | A 8% B 27% |
In acetic acid; benzene at 40℃; Rate constant; |
Dibenzo[a,e]pyrene
8,8'-Bi-naphtho<1,2,3,4-def>chrysenyl
Conditions | Yield |
---|---|
In chlorobenzene for 94h; Irradiation; | 4.4% |
maleic anhydride
Dibenzo[a,e]pyrene
benzo[a]coronene-3,4,7,8-tetracarboxylic acid-3,4;7,8-dianhydride
Conditions | Yield |
---|---|
With chloranil |
Dibenzo[a,e]pyrene
A
naphtho[1,2,3,4-def]chrysene-8,14-dione
B
9,14-dioxo-9,14-dihydro-benzo[b]triphenylene-1-carboxylic acid
Conditions | Yield |
---|---|
With sodium dichromate; acetic acid; nitrobenzene | |
With sodium dichromate; acetic acid |
succinic acid anhydride
Dibenzo[a,e]pyrene
β-<1,2;4,5-Dibenzo-pyren-8-oyl>-propionsaeure
Conditions | Yield |
---|---|
With aluminium trichloride In 1,2-dichloro-benzene |
Conditions | Yield |
---|---|
With bromine; 1,2,3-trichlorobenzene |
Dibenzo[a,e]pyrene
ortho-toluoyl chloride
8-(o-Toluyl)-1,2;4,5-dibenzo-pyren
Conditions | Yield |
---|---|
With aluminium trichloride In benzene |
Conditions | Yield |
---|---|
With aluminium trichloride In dichloromethane |
maleic anhydride
Dibenzo[a,e]pyrene
A
Naphtho<1,2,3,4-ghi>perylen-5,6-dicarbonsaeureanhydrid
B
benzo[a]coronene-3,4,7,8-tetracarboxylic acid-3,4;7,8-dianhydride
Conditions | Yield |
---|---|
With chloranil for 4h; Heating; | A 3 mg B n/a |
maleic anhydride
Dibenzo[a,e]pyrene
A
Naphtho<1,2,3,4-ghi>perylen-5,6-dicarbonsaeureanhydrid
C
benzo[a]coronene-3,4,7,8-tetracarboxylic acid-3,4;7,8-dianhydride
Conditions | Yield |
---|---|
In chlorobenzene for 70h; Ambient temperature; Irradiation; |
4-Phenyl-1,2,4-triazolidine-3,5-dione
Dibenzo[a,e]pyrene
A
1-naphtho[1,2,3,4-def]chrysen-8-yl-4-phenyl-[1,2,4]triazolidine-3,5-dione
B
N-Phenylbenzochryseno<4,5,6-ghij>phthalazine-5,6-dicarboximide
Conditions | Yield |
---|---|
In dichloromethane for 44h; Ambient temperature; | A 21 % Turnov. B 19 mg C 57 mg |
4-Phenyl-1,2,4-triazolidine-3,5-dione
Dibenzo[a,e]pyrene
N,N'-(7,8-naphtho<1,2,3,4-def>chrysendiyl)urea
Conditions | Yield |
---|---|
In dichloromethane for 0.166667h; Irradiation; | 19 % Turnov. |
Dibenzo[a,e]pyrene
1-naphtho[1,2,3,4-def]chrysen-8-yl-4-phenyl-[1,2,4]triazolidine-3,5-dione
A
N-Phenylbenzochryseno<4,5,6-ghij>phthalazine-5,6-dicarboximide
Conditions | Yield |
---|---|
With pyridine; bromine In dichloromethane at 8℃; for 144h; | A 0.4 mg B 7.6 mg |
Conditions | Yield |
---|---|
examination of high-temperature stabiliti; determination of equilibrium concentration; from 1500 to 3000 K; |
Dibenzo[a,e]pyrene
A
9,14-dioxo-9,14-dihydro-benzo[b]triphenylene-1-carboxylic acid
Conditions | Yield |
---|---|
With sodium dichromate; acetic acid |
Dibenzo[a,e]pyrene
N,N'-(7,8-naphtho<1,2,3,4-def>chrysendiyl)urea
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 21 percent Turnov. / CH2Cl2 / 44 h / Ambient temperature 2: 2.8 mg / Br2, pyridine / CH2Cl2 / 96 h / 8 °C 3: 1 mg / toluene / 3.5 h / Irradiation View Scheme | |
Multi-step reaction with 2 steps 1: 19 mg / CH2Cl2 / 44 h / Ambient temperature 2: 1 mg / toluene / 3.5 h / Irradiation View Scheme |
Dibenzo[a,e]pyrene
N-Phenylbenzochryseno<4,5,6-ghij>phthalazine-5,6-dicarboximide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 21 percent Turnov. / CH2Cl2 / 44 h / Ambient temperature 2: 2.8 mg / Br2, pyridine / CH2Cl2 / 96 h / 8 °C View Scheme |
Dibenzo[a,e]pyrene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 21 percent Turnov. / CH2Cl2 / 44 h / Ambient temperature 2: 7.6 mg / Br2, pyridine / CH2Cl2 / 144 h / 8 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: AlCl3 / 1,2-dichloro-benzene 2: N2H4*H2O, NaOH / bis-(2-hydroxy-ethyl) ether / Heating 3: ZnCl2, NaCl / 300 °C View Scheme |
Chemistry informtion about Dibenzo(A,E)Pyrene (192-65-4) is:
Synonyms: Dibenz(A,E)Pyrene ; Dibenzo(A,E)Pyrene ; 1,2,4,5-Dibenzopyrene ; 1,2:4,5-Dibenzpyrene ; Db(A,E)P ; Dibenzo[A,E]Pyrene(Purity) ; Naphtho(1,2,3,4-Def)Chrysene ; Naphtho[1,2,3,4-De]Chrysene .
MF: C24H14
MW: 302.37
EINECS: 205-891-1
Boiling Point: 552.3 °C at 760 mmHg
Flash Point: 282 °C
Density: 1.313 g/cm3
Enthalpy of Vaporization: 80.17 kJ/mol
Vapour Pressure: 1.12E-11 mmHg at 25°C
Following is the molecular structure of Dibenzo(A,E)Pyrene (192-65-4) is:
There is sufficient evidence that Dibenzo(A,E)Pyrene (192-65-4) is carcinogenic to experimental animals.
NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 ,1983,p. 327.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 3 ,1973,p. 201.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .
RIDADR: 2811
HazardClass: 6.1(b)
PackingGroup: III
General description about Dibenzo(A,E)Pyrene (192-65-4). It is a yellow crystals.
Air & Water Reactions: Dust/air mixtures may ignite and explode. Insoluble in water.
Reactivity Profile: Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as Dibenzo(A,E)Pyrene(192-65-4) , and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
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