D-glucose
Conditions | Yield |
---|---|
With lithium chloride In N,N-dimethyl-formamide at 120℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; | 99% |
With hydrogenchloride; water for 3h; Reactivity; Ionic liquid; | 94% |
Tonsil Supreme 110F, impregnated gallium sulphate In water at 20 - 110℃; for 0.35h; Product distribution / selectivity; | 75% |
1,2-O-benzylidene-α-D-glucofuranose
D-glucose
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 0.666667h; Product distribution; Heating; at various types of sugars; | 97% |
Cellobiose
D-glucose
Conditions | Yield |
---|---|
With water at 120℃; for 1h; Autoclave; | 96% |
With sulfuric acid In water at 130℃; for 6h; pH=4; Kinetics; Catalytic behavior; pH-value; Temperature; Inert atmosphere; Sealed tube; | 91.1% |
With phosphotungstic acid hydrate; water at 160℃; for 0.5h; Reagent/catalyst; Temperature; | 37.6% |
Conditions | Yield |
---|---|
With sodium carbonate In water at 25℃; for 0.333333h; pH:8-11; | A n/a B 95% |
With glycosidase Inert atmosphere; Enzymatic reaction; |
Conditions | Yield |
---|---|
With water at 150℃; for 3h; Autoclave; | 95% |
Conditions | Yield |
---|---|
With hydrogenchloride; water for 4h; Reactivity; Ionic liquid; | A 6% B 93% |
With carbon based mesoporous Sibunit-4-ox In water for 5h; | A n/a B 45% |
With water; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 160℃; for 2.66667h; Product distribution / selectivity; | A 7% B 32% |
A
D-glucose
B
(2S,3R)-3,7-dimethyl-6-octene-1,2,3-triol
Conditions | Yield |
---|---|
With β-glucosidase In water at 37℃; for 96h; Enzymatic reaction; | A n/a B 93% |
Conditions | Yield |
---|---|
With cellulase from Aspergillus niger at 40℃; for 144h; pH=4.6; | A n/a B 92% |
Cellobiose
A
ethanol
B
D-glucose
Conditions | Yield |
---|---|
With β-glucosidase from Pseudomonas lutea BG8 In aq. buffer at 30℃; for 16h; pH=5; Enzymatic reaction; | A 91.42% B n/a |
Cellobiose
D-glucose
Conditions | Yield |
---|---|
With H3N*2H(1+)*TeW6O21(2-); water at 130℃; for 4h; Reagent/catalyst; Autoclave; | 90.5% |
With sodium acetate buffer; recombinant yeast exo-β-1,3-glucanase at 30℃; for 0.0833333h; pH=5.5; Kinetics; | |
With mesoporous Ta3W7 oxide In water at 99.84℃; for 3h; |
Conditions | Yield |
---|---|
In water at 249℃; for 0.0166667h; Product distribution; Kinetics; Thermodynamic data; activation energy; various pH (3-5.7), temperatures (180-249 deg C), and times (0.3-15 min); | 90% |
With recombinant C,N-terminal 6xHis-tagged rabbit cecum umbgl3B β-glucosidase; water at 28℃; for 0.25h; pH=6; aq. phosphate buffer; | |
With Bgl1T β-D-glucoside glucohydrolase; calcium chloride at 37℃; for 0.25h; pH=7; aq. phosphate buffer; Enzymatic reaction; |
Conditions | Yield |
---|---|
With dodecatungstophosphoric acid hydrate; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In water at 139.84℃; for 5h; Reagent/catalyst; | A 89% B n/a |
With water at 150℃; for 12h; Autoclave; | A 12% B 42% |
With 1-(3-sulfopropyl)pyridinium phosphotungstate; water at 150℃; under 15001.5 Torr; for 5h; Autoclave; Inert atmosphere; | A 32.9% B 18.1% |
A
D-glucose
Conditions | Yield |
---|---|
With cellulase In aq. acetate buffer at 37℃; for 168h; pH=5; Enzymatic reaction; | A 88% B 4 mg |
A
D-glucose
Conditions | Yield |
---|---|
With hesperidinase; emulsin; water at 37℃; for 24h; | A 86% B 72% |
megastigman-7-en-3,6-epoxy-5,9-diol 9-O-β-D-glucopyranoside
A
D-glucose
Conditions | Yield |
---|---|
With hesperidinase; emulsin; water at 37℃; for 24h; | A 67% B 86% |
Conditions | Yield |
---|---|
With water at 79.84℃; for 2h; | 85.9% |
With water; acetone in Gegenwart eines sauren Kationenaustauschers; | |
With potassium phosphate buffer; rat intestinal α-glucosidase; 5,6,7-trihydroxy-2-phenyl-4H-1-benzopyran-4-one In dimethyl sulfoxide at 37℃; for 0.25h; pH=6.3; Enzyme kinetics; |
(3R,4R,5S,6S,7E,9R)-megastigman-7-ene-3,4,9-triol 9-O-β-D-glucopyranoside
A
D-glucose
Conditions | Yield |
---|---|
With hesperidinase; emulsin; water at 37℃; for 18h; Enzymatic reaction; | A 85% B 76% |
A
5-hydroxymethyl-2-furfuraldehyde
B
Cellobiose
C
D-glucose
Conditions | Yield |
---|---|
With sulfuric acid; water; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 99.84℃; for 2h; Ionic liquid; | A 4% B 8% C 85% |
With water; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 120℃; for 1h; Product distribution / selectivity; | A 8.45% B 12.6% C 43.6% |
Conditions | Yield |
---|---|
With K 10 clay In methanol; water at 75℃; for 72h; | 83% |
2,3,4,5,6-penta-O-benzyl aldehydo D-glucose
D-glucose
Conditions | Yield |
---|---|
With hydrogen; palladium dihydroxide In methanol for 120h; Ambient temperature; | 83% |
Conditions | Yield |
---|---|
In ethanol at 53℃; for 1h; Temperature; Time; Inert atmosphere; | A n/a B 81.4% |
D-glucose
Conditions | Yield |
---|---|
With H3N*2H(1+)*TeW6O21(2-); water at 130℃; for 4h; Autoclave; | 78.4% |
With Arthrobacter sp. DL001 α-D-glucoside glucohydrolase; water at 30℃; for 0.5h; pH=5.5; citrate-phosphate buffer; Enzymatic reaction; |
A
D-glucose
Conditions | Yield |
---|---|
With hesperidinase; emulsin; water at 37℃; for 24h; | A 50% B 74% |
(2S)-naringenin 5-O-β-D-glucopyranosyl(1->6)-β-D-glucopyranoside
A
D-glucose
B
(+)-Naringenin
Conditions | Yield |
---|---|
With hydrogenchloride; water at 80℃; for 1h; | A n/a B 73% |
A
D-glucose
B
(+)-Naringenin
Conditions | Yield |
---|---|
With hydrogenchloride; water at 80℃; for 1h; | A n/a B 73% |
A
5-hydroxymethyl-2-furfuraldehyde
B
formic acid
C
D-glucose
D
levulinic acid
Conditions | Yield |
---|---|
With graphene oxide (GO) In water at 199.84℃; for 1h; Temperature; Microwave irradiation; Green chemistry; | A n/a B n/a C 73% D n/a |
A
D-glucose
B
2',4',6',4-tetrahydroxydihydrochalcone
Conditions | Yield |
---|---|
With hydrogenchloride; water at 80℃; for 1h; | A n/a B 72% |
Conditions | Yield |
---|---|
With hydrogen In water at 120℃; under 15001.5 Torr; for 1h; | 100% |
With hydrogen; ruthenium embedded in mesoporous carbon In water at 120℃; under 15001.5 Torr; for 2h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Autoclave; | 99.3% |
With hydrogen at 120℃; under 22502.3 Torr; for 2h; high pressure reactor; | 94.43% |
D-glucose
Conditions | Yield |
---|---|
With lead(IV) acetate In acetic acid at 16 - 28℃; for 0.75h; oxidative cleavage; | 100% |
D-glucose
(2S,3R,4R,5R)-2,3,4,5,6-Pentahydroxy-hexanal O-(4-methoxy-benzyl)-oxime
Conditions | Yield |
---|---|
In acetate buffer at 20℃; for 2.16667h; pH=4; | 100% |
Conditions | Yield |
---|---|
In phosphate buffer at 20℃; pH=6.5; | 100% |
Conditions | Yield |
---|---|
In phosphate buffer at 20℃; pH=6.5; | 100% |
D-glucose
Conditions | Yield |
---|---|
In acetate buffer at 20℃; for 2.16667h; pH=4; | 100% |
Conditions | Yield |
---|---|
With iodine; potassium carbonate In methanol at 20℃; for 6h; | 100% |
Conditions | Yield |
---|---|
With manganese(II) sulfate; rubidium sulfate; sulfuric acid; magnesium sulfate In water at 40℃; for 0.166667h; Temperature; Reagent/catalyst; | 100% |
With cesium sulfate; sulfuric acid; water; magnesium sulfate; 2Co(2+)*2O4S(2-) at 145℃; | |
With sulfuric acid In water at 33℃; for 72h; pH=3.9; Kinetics; Reagent/catalyst; Temperature; Microbiological reaction; |
2-[2-(vinyloxy)ethoxymethyl]oxirane
D-glucose
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100 - 110℃; for 1h; Temperature; | 100% |
Conditions | Yield |
---|---|
In methanol; water at 65℃; for 0.166667h; Schiff Reaction; Inert atmosphere; | 100% |
In neat (no solvent) at 25℃; for 24h; Kinetics; Solvent; |
Conditions | Yield |
---|---|
With H8[PMo7V5O40]; oxygen at 90℃; under 15001.5 Torr; for 24h; Autoclave; | 100% |
With H8[PMo7V5O40]; oxygen at 90℃; under 15001.5 Torr; for 24h; Autoclave; |
Conditions | Yield |
---|---|
With sodium carbonate In water at 30℃; for 40h; Wavelength; Irradiation; | 99% |
With oxygen; sodium carbonate In water at 24.84℃; under 750.075 Torr; for 2h; pH=< 9; Catalytic behavior; Reagent/catalyst; | 99% |
With 5% Pd/C; water; oxygen; sodium carbonate at 20℃; under 760.051 Torr; for 2h; Reagent/catalyst; | 98% |
Conditions | Yield |
---|---|
With sucrose phosphorylase mutant L3411/Q345S at 55℃; for 24h; pH=7; Reagent/catalyst; Enzymatic reaction; | 99% |
D-glucose
acetic anhydride
2,3,4,5-tetra-O-acetyl-D-glucopyranose
Conditions | Yield |
---|---|
With sodium acetate at 100℃; for 0.333333h; | 99% |
D-glucose
butyryl chloride
[(2R,3R,4S,5R)-3,4,5,6-tetra(butanoyloxy)tetrahydropyran-2-yl]methyl butanoate
Conditions | Yield |
---|---|
Stage #1: D-glucose; butyryl chloride In dichloromethane at 15℃; for 0.5h; Stage #2: With pyridine In dichloromethane at 15℃; for 15.5h; | 98% |
Stage #1: D-glucose; butyryl chloride In dichloromethane at 15℃; for 0.5h; Stage #2: With pyridine In dichloromethane at 15℃; for 16h; | 98.46% |
Stage #1: D-glucose; butyryl chloride In dichloromethane at 15℃; for 0.5h; Stage #2: With pyridine In dichloromethane at 15℃; for 16h; | 98.46% |
Conditions | Yield |
---|---|
Stage #1: acetic anhydride With sodium acetate for 0.333333h; Reflux; Stage #2: D-glucose for 0.25h; Reflux; | 98% |
With sodium acetate at 90℃; for 4h; Inert atmosphere; | 85% |
With sodium thiocyanide |
4,5-Dichloro-1,2-phenylenediamine
D-glucose
(1'S,2'R,3'R,4'R)-1H-2-[(1,2,3,4,5-pentahydroxy)pentyl]-5,6-dichlorobenzimidazole
Conditions | Yield |
---|---|
With air; iodine; acetic acid at 20℃; for 3h; | 98% |
D-glucose
2,3-Diaminonaphthalene
(1'S,2'R,3'R,4'R)-2-[1',2',3',4',5'-pentahydroxypentyl]-1H-naphthimidazole
Conditions | Yield |
---|---|
With air; iodine; acetic acid at 20℃; for 6h; | 98% |
With iodine; acetic acid at 20℃; for 6h; |
D-glucose
1,2-diamino-benzene
(1'S,2'R,3'R,4'R)-2-[1',2',3',4',5'-pentahydroxypentyl]-1H-benzimidazole
Conditions | Yield |
---|---|
With air; iodine; acetic acid at 20℃; for 8h; | 98% |
D-glucose
1-deoxy-1-fluoro-α-D-glucose
Cellobiose
Conditions | Yield |
---|---|
With recombinant cellobiose phosphorylase from Clostridium thermocellum ATCC27405 of glycoside hydrolase family 94 at 40℃; pH=7; aq. Tris-HCl buffer; Enzymatic reaction; | 98% |
D-glucose
Conditions | Yield |
---|---|
With sodium acetate In water at 20℃; | 98% |
Conditions | Yield |
---|---|
With E. coli whole cells harboring coumarin C-glucosyltransferase from Morus alba (MaCGT) at 30℃; for 24h; Enzymatic reaction; | 98% |
chloro-trimethyl-silane
D-glucose
2,3,4,5,6-pentakis-O-(trimethylsilyl)-D-glucose
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 0 - 20℃; | 97% |
D-glucose
5-amino-1-(6-phenyl-pyridazin-3-yl)-1H-pyrazole-4-carboxylic acid hydrazide
Conditions | Yield |
---|---|
With acetic acid In N,N-dimethyl-formamide at 80℃; for 1h; | 96.93% |
Conditions | Yield |
---|---|
With triethylamine In chloroform at 0 - 10℃; for 2h; Concentration; | 96.8% |
With pyridine; chloroform |
Conditions | Yield |
---|---|
With sodium chloride In water at 180℃; for 8h; Catalytic behavior; Reagent/catalyst; Solvent; | 96% |
With chromium chloride; 1-butyl-3-methylimidazolium chloride In toluene at 100℃; for 4h; | 91% |
With aluminium(III) triflate; methanesulfonic acid In dimethyl sulfoxide at 120℃; for 6h; Reagent/catalyst; | 90% |
USP26, USP28 / BP2000, BP2003
Glucose, its cas register number is 50-99-7. It also can be called Anhydrous dextrose; Blood sugar; Cartose; Cerelose; D-(+)-Glucose. Glucose is a simple monosaccharide found in plants. Glucose exists in several different molecular structures, but all of these structures can be divided into two families of mirror-images.
Physical properties about Glucose are: (1)ACD/LogP: -3.29; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -3.29; (4)ACD/LogD (pH 7.4): -3.29; (5)ACD/BCF (pH 5.5): 1.00 ; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00 ; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 6; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 10; (12)Index of Refraction: 1.573; (13)Molar Refractivity: 37.542 cm3; (14)Molar Volume: 113.931 cm3; (15)Polarizability: 14.883 10-24cm3; (16)Surface Tension: 92.0839996337891 dyne/cm; (17)Density: 1.581 g/cm3; (18)Flash Point: 286.664 °C; (19)Enthalpy of Vaporization: 92.224 kJ/mol; (20)Boiling Point: 527.112 °C at 760 mmHg
Preparation of Glucose: In plants and some prokaryotes, glucose is a product of photosynthesis. In animals and fungi, glucose results from the breakdown of glycogen, a process known as glycogenolysis. Glucose is produced commercially via the enzymatic hydrolysis of starch.
Uses of Glucose: Glucose is critical in the production of proteins and in lipid metabolism. In plants and most animals, it is also a precursor for vitamin C (ascorbic acid) production. It is modified for use in these processes by the glycolysis pathway. It is also used as a precursor for the synthesis of several important substances. In industry, Glucose is used as a precursor to make vitamin C in the Reichstein process, to make citric acid, gluconic acid, bio-ethanol, polylactic acid, sorbitol.
When you are using this chemical, please be cautious about it as the following:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
1. Wear suitable protective clothing and gloves;
2. Avoid contact with skin and eyes;
3. Avoid exposure - obtain special instruction before use;
4. Avoid contact with eyes;
You can still convert the following datas into molecular structure:
(1)InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4+,5+,6+/m0/s1;
(2)InChIKey=GZCGUPFRVQAUEE-SLPGGIOYSA-N;
(3)SmilesOC[C@H]([C@H]([C@@H]([C@H](C=O)O)O)O)O;
The toxiciy data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
dog | LDLo | oral | 8gm/kg (8000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
mouse | LD50 | intraperitoneal | 18gm/kg (18000mg/kg) | Proceedings of the Society for Experimental Biology and Medicine. Vol. 35, Pg. 98, 1936. | |
mouse | LD50 | intravenous | 9gm/kg (9000mg/kg) | Arzneimittel-Forschung. Drug Research. Vol. 18, Pg. 666, 1968. | |
rabbit | LDLo | intravenous | 12gm/kg (12000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
rabbit | LDLo | oral | 20gm/kg (20000mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 150, 1955. | |
rat | LD50 | oral | 25800mg/kg (25800mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: CYANOSIS | "Toxicity of Pure Foods," Boyd, E.M., Cleveland, OH, CRC Press, 1973Vol. -, Pg. 39, 1973. |
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