Product Name

  • Name

    Phenyl vinyl sulfone

  • EINECS 226-890-2
  • CAS No. 5535-48-8
  • Article Data97
  • CAS DataBase
  • Density 1.177 g/cm3
  • Solubility
  • Melting Point 67-69 °C(lit.)
  • Formula C8H8O2S
  • Boiling Point 314.4 °C at 760 mmHg
  • Molecular Weight 168.216
  • Flash Point 178.6 °C
  • Transport Information
  • Appearance off-white or tan powder
  • Safety 26-36/37/39-37/39
  • Risk Codes 36/37/38-43
  • Molecular Structure Molecular Structure of 5535-48-8 (Phenyl vinyl sulfone)
  • Hazard Symbols IrritantXi
  • Synonyms (Vinylsulfonyl)benzene;Sulfone, phenyl vinyl;URI 744;PHENYL VINYL SULPHONE;PHENYLVINYLSULTONE;PHENYL VINYL SULFONE;VINYL PHENYL SULFONE;Eletriptan intermediate 1
  • PSA 42.52000
  • LogP 2.68460

Synthetic route

2-chloroethyl phenyl sulfone
938-09-0

2-chloroethyl phenyl sulfone

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20 - 24℃; for 20h;100%
With benzylamine In acetonitrile at 25℃; for 0.525h; Rate constant; different amines, amine concentrations and reaction times;
With sodium hydroxide
phenylthioethylene
1822-73-7

phenylthioethylene

Conditions
ConditionsYield
With C4H9N2O9W In methanol; water at 20℃; for 4h; chemoselective reaction;99%
With selenium(IV) oxide; dihydrogen peroxide In water; ethyl acetate chemoselective reaction;99%
With dihydrogen peroxide In water at 80℃; for 7.33333h; Catalytic behavior; Reagent/catalyst; Green chemistry;98%
Phenyl vinyl sulfoxide
20451-53-0

Phenyl vinyl sulfoxide

Conditions
ConditionsYield
With dihydrogen peroxide; [(η5-C5Me5)Mo(CO)3Cl] In acetonitrile at -20 - 20℃; for 4h;98%
With dihydrogen peroxide In water; acetic acid at 20℃; for 12h;97%
With n-C4F9; perfluoro-cis-2,3-dialkyloxaziridine; n-C3F7 In chloroform; trichlorofluoromethane at -20℃; for 0.25h;90%
With dihydrogen peroxide In acetic acid Ambient temperature; Yield given;
2-(phenylsulfonyl)ethanol
20611-21-6

2-(phenylsulfonyl)ethanol

Conditions
ConditionsYield
With methanesulfonyl chloride; triethylamine In dichloromethane at 20℃; for 6h; Dehydration;95%
Multi-step reaction with 2 steps
1: 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride; DMAP / CH2Cl2 / 12 h / 20 °C
2: aq. NaHCO3 / acetone / 12 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride; DMAP / CH2Cl2 / 12 h / 20 °C
2: aq. NaHCO3 / acetone / 12 h / 20 °C
View Scheme
With sulfuric acid Behandeln des Reaktionsgemisches mit Wasser und mit wss. Natronlauge;
(1,2-dibromo-ethyl)-phenyl sulfone
65211-25-8

(1,2-dibromo-ethyl)-phenyl sulfone

Conditions
ConditionsYield
With triphenylphosphine In methanol at 25℃;92%
With triphenylphosphine In methanol at 25℃; Rate constant;92%
(Z)-1,2-bis(phenylsulfonyl)ethene
963-15-5

(Z)-1,2-bis(phenylsulfonyl)ethene

Conditions
ConditionsYield
With tri-n-butyl-tin hydride In dichloromethane for 0.0833333h; Ambient temperature;90%
With PtCl2Styr2; diphenylsilane In chloroform for 4h; Heating;15%
formaldehyd
50-00-0

formaldehyd

(phenylsulfonylmethyl)trimethylsilane
17872-92-3

(phenylsulfonylmethyl)trimethylsilane

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran87%
With n-butyllithium 1.) hexane, THF, 0 deg C, 0.5 h, 2.) hexane, THF, room temperature; Yield given. Multistep reaction;
ethane-1,2-disulfonyl chloride
31469-08-6

ethane-1,2-disulfonyl chloride

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran for 0.25h; Cooling with ice; stereospecific reaction;85%
(1-Bromo-2-methoxy-ethanesulfonyl)-benzene

(1-Bromo-2-methoxy-ethanesulfonyl)-benzene

A

PVS
5535-48-8

PVS

B

phenyl 2-methoxyethyl sulfone
25062-93-5

phenyl 2-methoxyethyl sulfone

Conditions
ConditionsYield
With methanol; triphenylphosphine at 25℃;A n/a
B 82%
With methanol; triphenylphosphine at 25℃; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.);A n/a
B 82%
C14H13BrO4S2

C14H13BrO4S2

A

1,2-bis(phenylsulfonyl)ethane
599-94-0

1,2-bis(phenylsulfonyl)ethane

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With methanol; triphenylphosphine at 25℃;A 80%
B n/a
With methanol; triphenylphosphine at 25℃; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.);A 80%
B n/a
α-bromoethyl phenyl sulfone
38009-93-7

α-bromoethyl phenyl sulfone

A

PVS
5535-48-8

PVS

B

ethyl phenyl sulfone
599-70-2

ethyl phenyl sulfone

Conditions
ConditionsYield
With methanol; triphenylphosphine at 25℃;A n/a
B 78%
With methanol; triphenylphosphine at 25℃; Rate constant; Thermodynamic data; other β-substituted α-bromosulfones; ΔH(excit.), ΔS(excit.);A n/a
B 78%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃; for 24h;78%
In N,N-dimethyl-formamide at 80℃; Inert atmosphere;50%
In N,N-dimethyl-formamide at 80℃; Inert atmosphere;50%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃;76%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With palladium dichloride In dimethyl sulfoxide at 50℃; for 8h; chemoselective reaction;71%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

2-bromoethanol
540-51-2

2-bromoethanol

Conditions
ConditionsYield
Stage #1: sodium benzenesulfonate; 2-bromoethanol In N,N-dimethyl-formamide at 80℃; Inert atmosphere;
Stage #2: With methanesulfonyl chloride; triethylamine In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;
70%
ethene
74-85-1

ethene

benzenesufonyl hydrazide
80-17-1

benzenesufonyl hydrazide

Conditions
ConditionsYield
With oxygen; copper(l) chloride; lithium bromide In dimethyl sulfoxide at 100℃; under 760.051 Torr; for 12h; Schlenk technique; stereoselective reaction;67%
phenylthioethylene
1822-73-7

phenylthioethylene

A

PVS
5535-48-8

PVS

B

Phenyl vinyl sulfoxide
20451-53-0

Phenyl vinyl sulfoxide

Conditions
ConditionsYield
With C36H27CuN8O2; dihydrogen peroxide In methanol; dichloromethane at 0℃; for 10h;A 52%
B 25%
With dihydrogen peroxide; titanium(IV) isopropylate; L-Tartaric acid; silica gel In methanol; water at 25℃; for 24h; Title compound not separated from byproducts;A 3%
B 94 % Spectr.
With dihydrogen peroxide; Mg-Al-LDH-WO4 at 20℃; for 3h;
2-(phenylsulfonyl)ethanol
20611-21-6

2-(phenylsulfonyl)ethanol

A

2-chloroethyl phenyl sulfone
938-09-0

2-chloroethyl phenyl sulfone

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With pyridine; thionyl chloride; sodium hydrogencarbonate In tolueneA n/a
B 0.7%
2-chloroethyl phenyl sulfone
938-09-0

2-chloroethyl phenyl sulfone

triethylamine
121-44-8

triethylamine

Conditions
ConditionsYield
With benzene
ethene
74-85-1

ethene

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

Conditions
ConditionsYield
Yield given. Multistep reaction;
thiophenolate
13133-62-5

thiophenolate

sodium ethanolate
141-52-6

sodium ethanolate

(2-Isocyano-ethanesulfonyl)-benzene

(2-Isocyano-ethanesulfonyl)-benzene

A

cyanide(1-)
57-12-5

cyanide(1-)

B

PVS
5535-48-8

PVS

C

2-ethoxyethyl phenyl sulphone
28525-26-0

2-ethoxyethyl phenyl sulphone

D

(2-Isocyano-ethylsulfanyl)-benzene
3126-28-1

(2-Isocyano-ethylsulfanyl)-benzene

Conditions
ConditionsYield
Rate constant; Product distribution; multistep reaction, 1.) ethanol, 25 deg C; 2.) ethanol;
S-<2-(Phenylsulfonyl)ethyl>cystein-methylester

S-<2-(Phenylsulfonyl)ethyl>cystein-methylester

A

L-Cysteine methyl ester
2485-62-3

L-Cysteine methyl ester

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With sodium hydroxide for 10h; Ambient temperature; other concentration of NaOH, reaction velocity;
S-<2-(4-Ethoxycarbonylphenylsulfonyl)ethyl>cystein-methylester
95588-67-3

S-<2-(4-Ethoxycarbonylphenylsulfonyl)ethyl>cystein-methylester

A

L-Cysteine methyl ester
2485-62-3

L-Cysteine methyl ester

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With sodium hydroxide Ambient temperature; reaction times, various conc. of NaOH;
N-Acetyl-S-<2-(4-ethoxycarbonylphenylsulfonyl)ethyl>cystein
86124-83-6

N-Acetyl-S-<2-(4-ethoxycarbonylphenylsulfonyl)ethyl>cystein

A

N-acetylcystein
616-91-1

N-acetylcystein

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With sodium hydroxide Ambient temperature; reaction times, various conc. of NaOH, add. of N-Acetyl-S-<2-(phenylsulfonyl)ethyl>-cystein;
S-<2-(Phenylsulfonyl)ethyl>glutathion

S-<2-(Phenylsulfonyl)ethyl>glutathion

A

GLUTATHIONE
70-18-8

GLUTATHIONE

B

PVS
5535-48-8

PVS

Conditions
ConditionsYield
With sodium hydroxide for 0.5h; Ambient temperature; other concentration of NaOH, reaction velocity;
N-(Benzyloxycarbonyl)glycyl-S-<2-(phenylsulfonyl)ethyl>cystein-methylester
86124-78-9

N-(Benzyloxycarbonyl)glycyl-S-<2-(phenylsulfonyl)ethyl>cystein-methylester

A

PVS
5535-48-8

PVS

B

N-(Benzyloxycarbonyl)glycyl-cystein-methylester
95920-19-7

N-(Benzyloxycarbonyl)glycyl-cystein-methylester

Conditions
ConditionsYield
With sodium hydroxide for 1.75h; Ambient temperature; reaction velocity;
1-Bromo-2-chloroethane
107-04-0

1-Bromo-2-chloroethane

Benzenesulfinic acid
618-41-7

Benzenesulfinic acid

Conditions
ConditionsYield
With triethylamine 1.) ethanol, reflux, 3 d; 2.) dichloromethane, ethanol, reflux; Yield given. Multistep reaction;
N-(Cbo-Gylicyl)-S-(phenylsulfonylethyl)-cysteinmethylester

N-(Cbo-Gylicyl)-S-(phenylsulfonylethyl)-cysteinmethylester

A

PVS
5535-48-8

PVS

B

N-Cbo-Glycyl-cysteinmethylester

N-Cbo-Glycyl-cysteinmethylester

Conditions
ConditionsYield
With sodium hydroxide In methanol for 1.75h; Product distribution; Ambient temperature;
S-(Phenylsulfonylethyl)-cysteinmethylesterhydrochlorid

S-(Phenylsulfonylethyl)-cysteinmethylesterhydrochlorid

A

PVS
5535-48-8

PVS

B

cysteine methyl ester hydrochloride
5714-80-7, 18598-63-5, 70361-61-4

cysteine methyl ester hydrochloride

Conditions
ConditionsYield
With sodium hydroxide; triethylamine In methanol for 10h; Product distribution; Ambient temperature;
1H-imidazole
288-32-4

1H-imidazole

1-(2-(phenylsulfonyl)ethyl)-1H-imidazole

1-(2-(phenylsulfonyl)ethyl)-1H-imidazole

Conditions
ConditionsYield
In acetonitrile for 2h; Ambient temperature;100%
Stage #1: 1H-imidazole With o-phenylenebis(diphenylphosphine); potassium tert-butylate; copper(l) chloride In toluene for 0.166667h; Michael Addition; Inert atmosphere;
Stage #2: PVS In toluene at 22℃; for 3h; Michael Addition; Inert atmosphere;
99%
N-methylmaleimide
930-88-1

N-methylmaleimide

Cyclohexanone oxime
100-64-1

Cyclohexanone oxime

2,2-spiropentamethylene-3-(2'-phenylsulphonylethyl)-7-methyl-3,7-diaza-4-oxabicyclo<3.3.0>octane-6,8-dione
135583-71-0

2,2-spiropentamethylene-3-(2'-phenylsulphonylethyl)-7-methyl-3,7-diaza-4-oxabicyclo<3.3.0>octane-6,8-dione

Conditions
ConditionsYield
In [D3]acetonitrile for 720h; Ambient temperature;100%
1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione
91233-19-1

1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione

2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane
103698-35-7

2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane

Conditions
ConditionsYield
In dichloromethane; benzene for 0.166667h; Mechanism; Ambient temperature; Irradiation; easy formation of a carbon-carbon bond by simply incorporating activated olefin into the system (further activated olefins gave similar products);100%
In dichloromethane; benzene for 0.166667h; Ambient temperature; Irradiation; during work up excess monomer was destroyed by hydrazine;100%
diacetone acrylamide oxime
79077-49-9

diacetone acrylamide oxime

2-(2-phenylsulphonylethyl)-1,8,8-trimethyl-6-oxo-2,7-diaza-3-oxabicyclo<4.3.0>nonane
135386-59-3

2-(2-phenylsulphonylethyl)-1,8,8-trimethyl-6-oxo-2,7-diaza-3-oxabicyclo<4.3.0>nonane

Conditions
ConditionsYield
In xylene for 16h; Heating;100%
In xylene at 140℃; Yield given;
2-Thioxo-2H-pyridine-1-carboxylic acid adamantan-1-yl ester

2-Thioxo-2H-pyridine-1-carboxylic acid adamantan-1-yl ester

2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane
103698-35-7

2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane

Conditions
ConditionsYield
In dichloromethane; benzene at 20 - 25℃; for 0.166667h; Irradiation;100%
tert-butylamine
75-64-9

tert-butylamine

2-methyl-N-[2-(phenylsulfonyl)ethyl]propan-2-amine
16191-98-3

2-methyl-N-[2-(phenylsulfonyl)ethyl]propan-2-amine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
In ethanol at 20℃; Cooling with ice;81%
1-iodocyclohexane
626-62-0

1-iodocyclohexane

((2-cyclohexylethyl)sulfonyl)benzene
126002-58-2

((2-cyclohexylethyl)sulfonyl)benzene

Conditions
ConditionsYield
With water; sodium chloride In acetonitrile pH=2; Electrochemical reaction; Green chemistry;100%
With N-ethylpiperidine hypophosphite; triethyl borane; oxygen In 1,4-dioxane at 20℃; for 1h;98%
With cetyltrimethylammonim bromide; 4,4'-dicyano-4,4'-azo-di-valeric acid; N-ethylpiperidinium hypophosphite In 1,4-dioxane; water at 100℃; for 0.5h;94%
With (CH3)3N(+)(CH2)15CH3*H2PO2(-); 4,4'-dicyano-4,4'-azo-di-valeric acid In water at 100℃; for 1h;89%
With tert-butylisonitrile; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; triethylamine; lithium chloride; palladium dichloride In benzene for 16h; Giese Free Radical Synthesis; Irradiation; Inert atmosphere;88%
2-iodo-propane
75-30-9

2-iodo-propane

1-phenylsulphonyl-3-methyl butane
52075-20-4

1-phenylsulphonyl-3-methyl butane

Conditions
ConditionsYield
With hydrogenchloride; water; sodium chloride In acetonitrile for 20h; pH=2; Solvent; pH-value; Electrochemical reaction; Green chemistry;100%
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 14h; Giese-type addition; Heating;89%
With indium In methanol; water at 20℃; for 0.5h;86%
tert-butyl 2,3-dihydro-1-oxo-1H-indene-2-carboxylate
375349-06-7

tert-butyl 2,3-dihydro-1-oxo-1H-indene-2-carboxylate

C22H24O5S

C22H24O5S

Conditions
ConditionsYield
With quinidine 9-O-(9'-phenanthryl)ether In toluene at 20℃; for 36h; Michael addition; optical yield given as %ee; enantioselective reaction;100%
3-methoxybenzenethiol
15570-12-4

3-methoxybenzenethiol

2-[(3-methoxyphenyl)sulfanyl]ethyl phenyl sulfone
1308834-07-2

2-[(3-methoxyphenyl)sulfanyl]ethyl phenyl sulfone

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 20℃; for 20h; Inert atmosphere;100%
pyrrolidine

pyrrolidine

1-[2-(phenylsulfonyl)ethyl]pyrrolidine
649760-40-7

1-[2-(phenylsulfonyl)ethyl]pyrrolidine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
N,N',N'-trimethylenediamine
142-25-6

N,N',N'-trimethylenediamine

N1,N1,N2-trimethyl-N2-[2-(phenylsulfonyl)ethyl]-1,2-ethanediamine
1496553-60-6

N1,N1,N2-trimethyl-N2-[2-(phenylsulfonyl)ethyl]-1,2-ethanediamine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
morpholine
110-91-8

morpholine

4-[2-(phenylsulfonyl)ethyl]morpholine
41821-25-4

4-[2-(phenylsulfonyl)ethyl]morpholine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
(S)-2-aminobutane
513-49-5

(S)-2-aminobutane

(S)-N-[2-(phenylsulfonyl)ethyl]butan-2-amine
1496553-62-8

(S)-N-[2-(phenylsulfonyl)ethyl]butan-2-amine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
(R)-sec-butylamine
13250-12-9

(R)-sec-butylamine

(R)-N-[2-(phenylsulfonyl)ethyl]butan-2-amine
1496553-61-7

(R)-N-[2-(phenylsulfonyl)ethyl]butan-2-amine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
propylamine
107-10-8

propylamine

N-[2-(phenylsulfonyl)ethyl]propan-1-amine
1247689-43-5

N-[2-(phenylsulfonyl)ethyl]propan-1-amine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
Thiomorpholin
123-90-0

Thiomorpholin

4-[2-(phenylsulfonyl)ethyl]thiomorpholine
882270-51-1

4-[2-(phenylsulfonyl)ethyl]thiomorpholine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
isopropylamine
75-31-0

isopropylamine

N-[2-(phenylsulfonyl)ethyl]propan-2-amine
85052-84-2

N-[2-(phenylsulfonyl)ethyl]propan-2-amine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
In ethanol at 0 - 20℃;99%
propan-1-ol-3-amine
156-87-6

propan-1-ol-3-amine

3-[(2-(phenylsulfonyl)ethyl)amino]propan-1-ol
1496553-63-9

3-[(2-(phenylsulfonyl)ethyl)amino]propan-1-ol

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
1-methyl-piperazine
109-01-3

1-methyl-piperazine

1-methyl-4-[2-(phenylsulfonyl)ethyl]piperazine
1281167-83-6

1-methyl-4-[2-(phenylsulfonyl)ethyl]piperazine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
N,N-dimethylethylenediamine
108-00-9

N,N-dimethylethylenediamine

N1,N1-dimethyl-N2-[2-(phenylsulfonyl)ethyl]ethane-1,2-diamine
121101-77-7

N1,N1-dimethyl-N2-[2-(phenylsulfonyl)ethyl]ethane-1,2-diamine

Conditions
ConditionsYield
In dichloromethane at 20℃;100%
thiophenol
108-98-5

thiophenol

2-(phenylsulfanyl)ethyl phenyl sulfone
29290-71-9

2-(phenylsulfanyl)ethyl phenyl sulfone

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In ethanol; water at 20℃; for 2h; Michael Addition; Green chemistry;99%
triethylamine In tetrahydrofuran for 4.5h; Ambient temperature;96%
With potassium carbonate In dichloromethane at 20℃; for 20h; Inert atmosphere;92%
With 1,3-dicyclohexylimidazolium-2-carboxylate In tetrahydrofuran at 21℃; for 2h; Michael Addition;90%
aniline
62-53-3

aniline

N-(2-benzenesulfonylethyl)phenyl amine

N-(2-benzenesulfonylethyl)phenyl amine

Conditions
ConditionsYield
Stage #1: aniline With potassium tert-butylate; bis[2-(diphenylphosphino)phenyl] ether; copper(l) chloride In toluene for 0.166667h; Michael Addition; Inert atmosphere;
Stage #2: PVS In toluene at 22℃; for 3h; Reagent/catalyst; Michael Addition; Inert atmosphere;
99%
acetic acid at 200℃; for 0.333333h; Michael addition; microwave irradiation;96%
With acetic acid at 200℃; for 0.333333h; Microwave irradiation; Sealed vessel tube;76%
N-tert-Butylhydroxylamine
16649-50-6

N-tert-Butylhydroxylamine

N-tert-Butyl-N-<2-(phenylsulfonyl)ethyl>hydroxylamin

N-tert-Butyl-N-<2-(phenylsulfonyl)ethyl>hydroxylamin

Conditions
ConditionsYield
In dichloromethane for 2h; Ambient temperature;99%
1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene
86531-05-7, 86531-33-1

1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene

Conditions
ConditionsYield
With hydroquinone In toluene at 110℃; for 48h;99%
1-benzene
80859-83-2

1-benzene

(3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane
126002-57-1

(3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane

Conditions
ConditionsYield
With cyclohexa-1,4-diene In dichloromethane at 30℃; for 0.25h; Irradiation;99%
With cyclohexa-1,4-diene In dichloromethane at 30℃; for 3h; Irradiation;93%
3-Adamantan-1-yl-4-tert-butyl-thiophene 1,1-dioxide
211372-59-7

3-Adamantan-1-yl-4-tert-butyl-thiophene 1,1-dioxide

1-(2-tert-Butyl-phenyl)-adamantane

1-(2-tert-Butyl-phenyl)-adamantane

Conditions
ConditionsYield
In 1,2-dichloro-benzene for 27.5h; Heating;99%

Phenyl vinyl sulfone Specification

Phenyl vinyl sulfone(CAS NO.5535-48-8) is also named as (Vinylsulfonyl)benzene; (Vinylsulfonyl)benzol; Benzene, (ethenylsulfonyl)-; Ethenyl phenyl sulfone; Phenyl-vinylsulfon; Sulfone, phenyl vinyl; (Ethenylsulfonyl)benzene. Phenyl vinyl sulfone is off-white or tan powder. It has the  Molecular Formula of C8H8O2S and Molecular Weight of 168.21292. It belongs to the Product Categories of Pharmaceutical material and intermeidates; Sulfur Compounds (for Synthesis); Synthetic Organic Chemistry; Naphthyridine,Quinoline; Organic Building Blocks; Sulfones.

Physical properties about Phenyl vinyl sulfone are: (1)ACD/LogP: 1.126; (2)ACD/LogD (pH 5.5): 1.13; (3)ACD/LogD (pH 7.4): 1.13; (4)ACD/BCF (pH 5.5):4.22; (5)ACD/BCF (pH 7.4): 4.22; (6)ACD/KOC (pH 5.5): 97.58; (7)ACD/KOC (pH 7.4): 97.58; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 2; (10)Index of Refraction: 1.537 ; (11)Molar Refractivity: 44.597 cm3; (12)Molar Volume: 142.811 cm3 ; (13)Polarizability: 17.68 10-24cm3; (14)Surface Tension: 37.1389999389648 dyne/cm; (15)Density: 1.178 g/cm3; (16)Flash Point: 178.621 °C; (17)Enthalpy of Vaporization: 53.339 kJ/mol; (18)Boiling Point: 314.371 °C at 760 mmHg; (19)Vapour Pressure: 0.00100000004749745 mmHg at 25°C

When you are using this chemical, please be cautious about it as the following:
1. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
2. Wear suitable protective clothing, gloves and eye/face protection;
3. Wear suitable protective clothing and gloves;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C8H8O2S/c1-2-11(9,10)8-6-4-3-5-7-8/h2-7H,1H2;
(2)InChIKey=UJTPZISIAWDGFF-UHFFFAOYSA-N;
(3)SmilesS(C=C)(=O)(=O)c1ccccc1

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