benzeneacetic acid methyl ester
potassium phenylacetate
Conditions | Yield |
---|---|
With potassium tert-butylate; water In ethanol at 60℃; | 95% |
Conditions | Yield |
---|---|
With potassium hydroxide; triphenylphosphine In methanol | 94% |
Conditions | Yield |
---|---|
In water at 70℃; |
phenylacetic acid
potassium phenylacetate
Conditions | Yield |
---|---|
With potassium hydroxide In water at 20℃; for 0.5h; |
Ethyl 2-phenylethanoate
potassium phenylacetate
Conditions | Yield |
---|---|
With potassium tert-butylate In benzene at 20℃; |
Conditions | Yield |
---|---|
Stage #1: phenylacetic acid With trichloroisocyanuric acid; triphenylphosphine In dichloromethane at 0 - 20℃; Stage #2: potassium phenylacetate In dichloromethane at 20℃; for 1.33333h; | 96% |
potassium phenylacetate
α-bromoacetophenone
2-oxo-2-phenylethyl 2-phenylacetate
Conditions | Yield |
---|---|
With β‐cyclodextrin In water; acetone at 50℃; | 95% |
1,4-dibromo-butane
potassium phenylacetate
1,4-bis-phenylacetoxy-butane
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; potassium carbonate In water at 100℃; for 0.5h; Microwave irradiation; Green chemistry; | 95% |
2-(3-bromopropyl)isoindole-1,3-dione
potassium phenylacetate
Conditions | Yield |
---|---|
In acetone for 0.333333h; pH=7; Solvent; Flow reactor; Irradiation; | 95% |
phthalimide
potassium phenylacetate
2,3-dihydro-3-hydroxy-3-(phenylmethyl)-1H-isoindol-1-one
Conditions | Yield |
---|---|
In acetone Flow reactor; Green chemistry; | 93% |
In acetone at 15 - 20℃; for 3h; pH=7; aq. buffer; UV-irradiation; Inert atmosphere; | 92% |
potassium phenylacetate
benzyl chloride
benzeneacetic acid methyl ester
Conditions | Yield |
---|---|
With potassium hydroxide; triphenylphosphine In methanol; isopropyl alcohol | 92% |
potassium phenylacetate
4-(bromoacetyl)toluene
Conditions | Yield |
---|---|
With β‐cyclodextrin In water; acetone at 50℃; | 90% |
potassium phenylacetate
4-chlorobenzoylmethyl bromide
2-(4-chlorophenyl)-2-oxoethyl 2-phenylacetate
Conditions | Yield |
---|---|
With β‐cyclodextrin In water; acetone at 50℃; | 90% |
potassium phenylacetate
4-Nitrophenacyl bromide
2-(4-nitrophenyl)-2-oxoethyl 2-phenylacetate
Conditions | Yield |
---|---|
With β‐cyclodextrin In water; acetone at 50℃; | 89% |
N-methylphthalimide
potassium phenylacetate
3-benzyl-3-hydroxy-2-methyl-1,3-dihydroisoindol-1(3H)-one
Conditions | Yield |
---|---|
In water; acetone at 15℃; Irradiation; | 88% |
In water; acetone at 15 - 20℃; for 20h; Irradiation; | 88% |
In acetone Flow reactor; Green chemistry; | 84% |
In water; acetone at 15 - 20℃; for 1h; Inert atmosphere; UV-irradiation; | 80% |
With water In acetone for 0.666667h; Irradiation; Inert atmosphere; | 100 %Spectr. |
potassium phenylacetate
para-bromophenacyl bromide
2-(4-bromophenyl)-2-oxoethyl 2-phenylacetate
Conditions | Yield |
---|---|
With β‐cyclodextrin In water; acetone at 50℃; | 88% |
2-(2-bromoethyl)isoindoline-1,3-dione
potassium phenylacetate
Conditions | Yield |
---|---|
In acetone for 0.333333h; pH=7; Solvent; Flow reactor; Irradiation; | 87% |
In acetone Flow reactor; Green chemistry; | 86% |
2-chloro-ethanol
2-hydroxyethyl 2-phenylacetate
Conditions | Yield |
---|---|
triethylamine at 135℃; for 3.5h; | 84% |
tris-(o-tolyl)antimony(V) dibromide
potassium phenylacetate
Conditions | Yield |
---|---|
In toluene at 20℃; for 12h; | 84% |
benzhydryl 7-aminocephalosporanate
potassium phenylacetate
(6R,7R)-benzhydryl 3-(acetyloxymethyl)-8-oxo-7-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate
Conditions | Yield |
---|---|
With triethylamine; 2-chloro-1-methylpyridinium sulfate In dichloromethane for 0.5h; | 83% |
Conditions | Yield |
---|---|
With air In 1-methyl-pyrrolidin-2-one at 120℃; for 6h; | 80% |
potassium phenylacetate
Chloromethyltrimethylsilane
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Heating; | 78% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere; | 76% |
2-(3-bromopropyl)isoindole-1,3-dione
potassium phenylacetate
A
9b-benzyl-2,3-dihydrooxazolo[2,3-a]isoindol-5-(9bH)-one
Conditions | Yield |
---|---|
In acetone Flow reactor; Green chemistry; | A n/a B 74% |
triethylchloromethylsilane
potassium phenylacetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 3h; Heating; | 63.1% |
N-phthaloylglycine methyl ester
potassium phenylacetate
C18H17NO4
Conditions | Yield |
---|---|
In water; acetone at 15 - 20℃; for 4h; Inert atmosphere; UV-irradiation; | 60% |
styrene
potassium phenylacetate
(1-fluoropropane-1,3-diyl)dibenzene
Conditions | Yield |
---|---|
With silver nitrate; Selectfluor In 1,4-dioxane; water at 20℃; for 12h; Inert atmosphere; Schlenk technique; chemoselective reaction; | 60% |
2-bromo-1-(4-chlorophenyl)-2-phenylethanone
potassium phenylacetate
4-chlorobezoin phenylacetate
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile for 2h; Heating; | 55% |
N-methoxyphthalimide
potassium phenylacetate
Conditions | Yield |
---|---|
In water; acetone for 1h; Irradiation; Schlenk technique; Inert atmosphere; chemoselective reaction; | 52% |
(chloromethyl)trimethoxysilane
potassium phenylacetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Heating; | 45.8% |
chloromethyltriethoxysilane
potassium phenylacetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Heating; | 43.8% |
2-(4-acetoxybenzyl) isoindoline-1,3-dione
potassium phenylacetate
C24H21NO4
Conditions | Yield |
---|---|
With water In acetone for 5h; Irradiation; Inert atmosphere; | 43% |
The Potassium phenylacetate, with the CAS registry number 13005-36-2 and EINECS registry number 235-845-6, has the IUPAC name of potassium 2-phenylacetate. The molecular formula of the chemical is C8H7KO2.
The characteristics of this chemical are as followings: (1)ACD/LogP: 1.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.28; (4)ACD/LogD (pH 7.4): -1.51; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 9.26; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 37.3 Å2 ; (13)Flash Point: 156.2 °C; (14)Enthalpy of Vaporization: 53.18 kJ/mol; (15)Boiling Point: 265.5 °C at 760 mmHg; (16)Vapour Pressure: 0.00456 mmHg at 25°C.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [K+].O=C([O-])Cc1ccccc1
(2)InChI: InChI=1/C8H8O2.K/c9-8(10)6-7-4-2-1-3-5-7;/h1-5H,6H2,(H,9,10);/q;+1/p-1
(3)InChIKey: JFOZPCWVLIBFCH-REWHXWOFAG
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