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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Chloromethyltrimethylsilane Manufacturer/High quality/Best price/In stock

Cas:2344-80-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:1

Negotiable

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:Shanghai, Qingdao

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(Chloromethyl)-trimethylsilane

Cas:2344-80-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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LIDE PHARMACEUTICALS LIMITED

We are a professional chemicals, APIs and plant extract leading manufacturer in China. We are specialized in chemical synthesis, process development of pharmaceutical intermediates, active pharmaceutical ingredients (APIs), plant extract and rare c

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Henan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com

TIANFU-CHEM - Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:1 Gram

FOB Price: $1000.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2344-80-1

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi

Chloromethyltrimethylsilane CAS 2344-80-1 with purity 99%

Cas:2344-80-1

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

(Chloromethyl)trimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

(Chloromethyl)trimethylsilane/High quality/Best price

Cas:2344-80-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality (Chloromethyl)Trimethylsilane

Cas:2344-80-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Silane,(chloromethyl)trimethyl-

Cas:2344-80-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in

SAGECHEM/ Chloromethyltrimethylsilane /Manufacturer in China

Cas:2344-80-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

manufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.

chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

(Chloromethyl)Trimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Manufacturers

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

(Chloromethyl)trimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 2344-80-1 with competitive price

Cas:2344-80-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Silane,(chloromethyl)trimethyl-

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Chloromethyltrimethylsilane 2344-80-1

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

TIANFU-CHEM - Chloromethyltrimethylsilane Application:TIANFU-CHEM - Chloromethyltrimethylsilane

TIANFU-CHEM - Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

we produce and sell good chemicals around the world.Appearance:white power Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:SEA OR AIR Port:China Main Po

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Send Pharmaceutical Technology Co., Ltd.

stock,low price,high quality,high purity,good sevice Application:R&D

chloromethyl(trimethyl)silane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Chloromethyltrimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:2344-80-1

(Chloromethyl)trimethylsilane, 98%

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HWRK Chem

in storeAppearance:Corrosive highly flammable colorless transparent liquid Package:100g Application:Organic Chemicals

(Chloromethyl)trimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

(Chloromethyl)trimethylsilane

Cas:2344-80-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

dichloromethane
75-09-2

dichloromethane

A

bis(trimethylsilyl)methane
2117-28-4

bis(trimethylsilyl)methane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With N,N,N,N-tetraethylammonium tetrafluoroborate In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 18.4167h; electroreduction, anode: Al, cathode: stainless steel;A 10%
B 90%
Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With methylmagnesium bromide In not given90%
With CH3MgBr In not given90%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

dichloromethane
75-09-2

dichloromethane

A

bis(trimethylsilyl)methane
2117-28-4

bis(trimethylsilyl)methane

B

1,2-bis(trimethylsilyl)ethane
6231-76-1

1,2-bis(trimethylsilyl)ethane

C

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With N,N,N,N-tetraethylammonium tetrafluoroborate In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 33.5h; electroreduction, anode: Al, cathode: stainless steel;A 88%
B 6%
C 6%
tetramethylsilane
75-76-3

tetramethylsilane

chlorine
7782-50-5

chlorine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
In neat (no solvent, gas phase) vapor phase chlorination at temp. of boiling benzene;;74%
In tetrachloromethane Irradiation (UV/VIS); introduction of gaseous Cl2 into a soln. of Si(CH3)4 in CCl4 under irradiation with sunlight in presence of some PCl5;;33%
Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
42%
With diethyl ether
tetramethylsilane
75-76-3

tetramethylsilane

Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
aluminium trichloride In tetrachloromethane for 6h; Heating; atmospheric pressure;33%
tetramethylsilane
75-76-3

tetramethylsilane

Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
aluminium trichloride In neat (no solvent) at 30 - 40℃; for 19h; Product distribution; atmospheric pressure; other time and solvents, different ratio of the starting materials;A n/a
B 32%
tetramethylsilane
75-76-3

tetramethylsilane

A

methanesulfonyl trimethylsilyl chloride
18143-34-5

methanesulfonyl trimethylsilyl chloride

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With yttrium(III) chloride; sulfuryl dichloride for 8h; Irradiation;A 20%
B 20%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

(chloromethyl)trichlorosilane
1558-25-4

(chloromethyl)trichlorosilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

methyl magnesium iodide
917-64-6

methyl magnesium iodide

(chloromethyl)trichlorosilane
1558-25-4

(chloromethyl)trichlorosilane

A

iodo(trimethylsilyl)methane
4206-67-1

iodo(trimethylsilyl)methane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

diethyl ether
60-29-7

diethyl ether

Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

methylmagnesium chloride
676-58-4

methylmagnesium chloride

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

tetramethylsilane
75-76-3

tetramethylsilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With tetrachloromethane; phosphorus pentachloride; chlorine unter Belichtung;
With tetrachloromethane; potassium carbonate; acetonitrile; bis(triphenylphosphine)platinum(II) dichloride at 120℃; for 16h;2.4 % Chromat.
(chloromethyl)trichlorosilane
1558-25-4

(chloromethyl)trichlorosilane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

methyl magnesium iodide
917-64-6

methyl magnesium iodide

chloromethylmethyldichlorosilane
1558-33-4

chloromethylmethyldichlorosilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

chloromethyldimethylsilane
3144-74-9

chloromethyldimethylsilane

methyl magnesium iodide
917-64-6

methyl magnesium iodide

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

n-Butyl chloride
109-69-3

n-Butyl chloride

(bromomethyl)trimethylsilane
18243-41-9

(bromomethyl)trimethylsilane

A

1-bromo-butane
109-65-9

1-bromo-butane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With triisooctyl amine Equilibrium constant;
n-Butyl chloride
109-69-3

n-Butyl chloride

iodo(trimethylsilyl)methane
4206-67-1

iodo(trimethylsilyl)methane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With triisooctyl amine Equilibrium constant;
trichloromethyltrimethylsilane
5936-98-1

trichloromethyltrimethylsilane

Dilithium N,N'-bis(trimethylsilyl)hydrazide tetramer
15114-92-8, 33509-48-7, 53380-51-1

Dilithium N,N'-bis(trimethylsilyl)hydrazide tetramer

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

(dichloromethyl)trimethylsilane
5926-38-5

(dichloromethyl)trimethylsilane

C

N,N'-bis(trimethylsilyl)hydrazine
692-56-8

N,N'-bis(trimethylsilyl)hydrazine

D

tris(trimethylsilyl)hydrazine
13272-02-1

tris(trimethylsilyl)hydrazine

E

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

F

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
In diethyl ether at -78℃; Product distribution; var.: reagent;
tetrachloromethane
56-23-5

tetrachloromethane

tetramethylsilane
75-76-3

tetramethylsilane

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

chlorine
7782-50-5

chlorine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

bis(chloromethyl)dimethylsilane
2917-46-6

bis(chloromethyl)dimethylsilane

A

tetramethylsilane
75-76-3

tetramethylsilane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With Zn In ethanol; water react. of (CH3)2Si(CH2Cl)2 and Zn powder in aq. ethanol in presence of NaI and Na2CO3;;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

chlorobromomethane
74-97-5

chlorobromomethane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -78℃;
(dichloromethyl)trimethylsilane
5926-38-5

(dichloromethyl)trimethylsilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

tetramethylsilane
75-76-3

tetramethylsilane

C

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With hydrogen at 200℃; under 760.051 Torr; for 1h; Kinetics; Flow reactor;
With hydrogen at 200℃; under 760.051 Torr; for 1h; Kinetics; Flow reactor;
(dichloromethyl)trimethylsilane
5926-38-5

(dichloromethyl)trimethylsilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With hydrogen at 200℃; under 760.051 Torr; for 1h; Kinetics; Flow reactor;
benzylamine
100-46-9

benzylamine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

N-benzyl-1-(trimethylsilyl)-N-((trimethylsilyl)methyl)methanamine
144964-17-0

N-benzyl-1-(trimethylsilyl)-N-((trimethylsilyl)methyl)methanamine

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Heating;100%
With potassium carbonate In acetonitrile for 68h; Heating;76%
4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

lithium hydride
7580-67-8

lithium hydride

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

Conditions
ConditionsYield
In tetrahydrofuran; water; pentane100%
3-fluorosalicylaldehyde
394-50-3

3-fluorosalicylaldehyde

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

3-fluoro-2-((trimethylsilyl)methoxy)benzaldehyde
1346529-53-0

3-fluoro-2-((trimethylsilyl)methoxy)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 65℃; for 12h; Inert atmosphere;100%
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 65℃;98%
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 65℃;
furfural
98-01-1

furfural

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-(2'-furyl)-2-trimethylsilanylethan-1-ol
1578-26-3

1-(2'-furyl)-2-trimethylsilanylethan-1-ol

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether at 20℃; for 1h;
Stage #2: furfural In diethyl ether at 0 - 20℃; for 1h;
99%
With magnesium In diethyl ether at 0 - 20℃; for 12h; Grignard reaction;90%
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether for 1h; Grignard reaction; Heating;
Stage #2: furfural In diethyl ether at 0 - 20℃; for 12h; Addition; Further stages.;
90%
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether for 1h; Heating;
Stage #2: furfural In diethyl ether for 12h; Grignard reaction; Further stages.;
90%
Stage #1: Chloromethyltrimethylsilane With 1,1-Dibromoethane; magnesium In diethyl ether for 18h; Heating;
Stage #2: furfural In diethyl ether at 0 - 23℃; for 18h; Grignard reaction;
2-Mercaptopyridine
2637-34-5

2-Mercaptopyridine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

2-(trimethylsilylmethylmercapto)pyridine
151668-58-5

2-(trimethylsilylmethylmercapto)pyridine

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In ethanol for 1h; Heating;98%
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-(2-thienyl)-2-(trimethylsilyl)ethanol

1-(2-thienyl)-2-(trimethylsilyl)ethanol

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether at 20℃; for 1h;
Stage #2: thiophene-2-carbaldehyde In diethyl ether at 0 - 20℃; for 1h;
98%
Stage #1: Chloromethyltrimethylsilane With magnesium; ethylene dibromide In diethyl ether for 1h; Heating;
Stage #2: thiophene-2-carbaldehyde In diethyl ether at 0 - 20℃; for 21h;
94%
2-bromo-4,5-dichloro-1 H-imidazole
16076-27-0

2-bromo-4,5-dichloro-1 H-imidazole

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

2-bromo-4,5-dichloro-1-[(trimethylsilyl)methyl]-1H-imidazole

2-bromo-4,5-dichloro-1-[(trimethylsilyl)methyl]-1H-imidazole

Conditions
ConditionsYield
With potassium hexamethylsilazane In N,N-dimethyl acetamide at 0 - 100℃; for 4h;98%
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

trimethylsilylmethyl azide
87576-94-1

trimethylsilylmethyl azide

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 80℃; for 44h;97%
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium azide at 80℃; for 12h;95%
With sodium azide In N,N-dimethyl-formamide at 80℃; for 40h; Inert atmosphere;85%
1,8-diazabicyclo[5.4.0]undec-7-ene
6674-22-2

1,8-diazabicyclo[5.4.0]undec-7-ene

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-(methyl trimethylsilane)-1,8-diazobicyclo[5.4.0]undec-7-ene chloride

1-(methyl trimethylsilane)-1,8-diazobicyclo[5.4.0]undec-7-ene chloride

Conditions
ConditionsYield
In neat (no solvent) at 70℃; for 2h; Inert atmosphere;97%
In N,N-dimethyl-formamide at 100℃; for 20h;95%
(+)-(S)-1-Phenyl-3,4,5,6-tetrahydro[1,2]thiazin-1-oxide
210552-40-2

(+)-(S)-1-Phenyl-3,4,5,6-tetrahydro[1,2]thiazin-1-oxide

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(+)-(1S,6S)-6-(trimethylsilyl)methyl-1-phenyl-3,4,5,6-tetrahydro-1λ4-1,2-thiazine 1-oxide
1305338-61-7

(+)-(1S,6S)-6-(trimethylsilyl)methyl-1-phenyl-3,4,5,6-tetrahydro-1λ4-1,2-thiazine 1-oxide

Conditions
ConditionsYield
Stage #1: (+)-(S)-1-Phenyl-3,4,5,6-tetrahydro[1,2]thiazin-1-oxide With n-butyllithium In tetrahydrofuran; hexane at -50 - 20℃;
Stage #2: Chloromethyltrimethylsilane In tetrahydrofuran; hexane at -78 - 20℃; for 18h; optical yield given as %de; diastereoselective reaction;
97%
Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

chloromethyl(dimethyl)(trimethylsilylmethyl)silane
18306-73-5

chloromethyl(dimethyl)(trimethylsilylmethyl)silane

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium; ethylene dibromide In tetrahydrofuran for 2h; Schlenk technique; Inert atmosphere; Reflux;
Stage #2: Chloro(chloromethyl)dimethylsilane In tetrahydrofuran for 20h; Reflux; Schlenk technique; Inert atmosphere;
97%
tert-butylamine
75-64-9

tert-butylamine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

N-tert-butyl<(trimethylsilyl)metyl>amine
79250-80-9

N-tert-butyl<(trimethylsilyl)metyl>amine

Conditions
ConditionsYield
Stage #1: tert-butylamine; Chloromethyltrimethylsilane at 200℃; for 18h;
Stage #2: With sodium hydroxide In water
96%
at 200℃; for 18h; Product distribution / selectivity; Heating / reflux;96%
Stage #1: tert-butylamine; Chloromethyltrimethylsilane at 200℃; for 18h;
Stage #2: With sodium hydroxide In water at 20℃; for 1h; Product distribution / selectivity;
96%
methyltris(trimethylsilyl)silane
2003-86-3

methyltris(trimethylsilyl)silane

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

2-[(trimethylsilyl)methyl]heptamethyltrisilane
1314534-53-6

2-[(trimethylsilyl)methyl]heptamethyltrisilane

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran Inert atmosphere;96%
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1,4-bis(trimethylsilyl)dodecamethylbicyclo[2.2.2]octasilane
79769-61-2

1,4-bis(trimethylsilyl)dodecamethylbicyclo[2.2.2]octasilane

1-(trimethylsilyl)-4-[(trimethylsilyl)methyl]dodecamethylbicyclo[2.2.2]octasilane
1314534-75-2

1-(trimethylsilyl)-4-[(trimethylsilyl)methyl]dodecamethylbicyclo[2.2.2]octasilane

Conditions
ConditionsYield
Stage #1: 1,4-bis(trimethylsilyl)dodecamethylbicyclo[2.2.2]octasilane With potassium tert-butylate In tetrahydrofuran Inert atmosphere;
Stage #2: Chloromethyltrimethylsilane In tetrahydrofuran at 20℃; for 16.1667h; Cooling with ice; Inert atmosphere;
96%
thiophenol
108-98-5

thiophenol

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(phenylsulfanylmethyl)trimethylsilane
17873-08-4

(phenylsulfanylmethyl)trimethylsilane

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water for 4h; Heating;95%
benzylamine
100-46-9

benzylamine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

N-(trimethylsilylmethyl)benzylamine
53215-95-5

N-(trimethylsilylmethyl)benzylamine

Conditions
ConditionsYield
In dimethyl sulfoxide Heating;95%
at 20 - 120℃; for 24h;93.3%
In acetonitrile for 16h; Reflux; Inert atmosphere;93%
p-Chlorothiophenol
106-54-7

p-Chlorothiophenol

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

<(4-chlorophenylthio)methyl>trimethylsilane
112474-70-1

<(4-chlorophenylthio)methyl>trimethylsilane

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water for 4h; Heating;95%
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1,1,1-trichloro-3,3-dimethyl-1,3-disilabutane
16538-62-8

1,1,1-trichloro-3,3-dimethyl-1,3-disilabutane

Conditions
ConditionsYield
With trichlorosilane; tetra-n-butylphosphonium chloride at 150℃; for 4h;95%
With trichlorosilane; benzyltriphenylphosphonium chloride72%
With trichlorosilane; benzyltriphenylphosphonium chloride72%
With tetrachlorosilane; magnesium; methyl iodide 1.) THF, reflux, 0.5 h, 2.) THF, 80 deg C, 4 h; Yield given. Multistep reaction;
2-mercaptobenzimidazole sodium salt
15091-69-7, 26585-65-9

2-mercaptobenzimidazole sodium salt

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

2-Trimethylsilanylmethylsulfanyl-1H-benzoimidazole

2-Trimethylsilanylmethylsulfanyl-1H-benzoimidazole

Conditions
ConditionsYield
In benzene for 4h; Heating;95%
(R)-1-phenyl-ethyl-amine
3886-69-9

(R)-1-phenyl-ethyl-amine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(R)-(+)-N-1-phenylethyl-N-trimethylsilylmethylamine
104942-85-0

(R)-(+)-N-1-phenylethyl-N-trimethylsilylmethylamine

Conditions
ConditionsYield
In dimethyl sulfoxide at 90℃; for 18h;95%
Heating;84%
With potassium carbonate In acetonitrile for 4h; Heating;81%
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-furan-3-yl-2-trimethylsilanyl-ethanol

1-furan-3-yl-2-trimethylsilanyl-ethanol

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether Heating;
Stage #2: furan-3-carboxaldehyde In diethyl ether at 0 - 20℃; for 12h; Further stages.;
95%
Stage #1: Chloromethyltrimethylsilane With 1,1-Dibromoethane; magnesium In diethyl ether for 19h; Heating;
Stage #2: furan-3-carboxaldehyde In diethyl ether at 0 - 23℃; for 18h; Grignard reaction;
1-methyl-4-((phenylsulfonyl)methyl)benzene
19523-24-1

1-methyl-4-((phenylsulfonyl)methyl)benzene

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(2-benzenesulfonyl-2-p-tolyl-ethyl)-trimethyl-silane

(2-benzenesulfonyl-2-p-tolyl-ethyl)-trimethyl-silane

Conditions
ConditionsYield
With lithium methylsulfinyl carbanion at 20℃; for 2h; Product distribution; Further Variations:; Reagents; Temperatures;95%
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-cyclopropyl-5,9-dimethyl-deca-4,8-dien-1-one
714230-48-5

1-cyclopropyl-5,9-dimethyl-deca-4,8-dien-1-one

(E)-2-Cyclopropyl-6,10-dimethyl-1-trimethylsilanyl-undeca-5,9-dien-2-ol
714230-49-6

(E)-2-Cyclopropyl-6,10-dimethyl-1-trimethylsilanyl-undeca-5,9-dien-2-ol

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium In diethyl ether
Stage #2: With cerium(III) chloride In tetrahydrofuran; diethyl ether at 0℃;
Stage #3: 1-cyclopropyl-5,9-dimethyl-deca-4,8-dien-1-one In tetrahydrofuran; diethyl ether at 0 - 20℃;
95%
lithium
7439-93-2

lithium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
In pentane95%
In pentane95%
In pentane at 40℃; for 16h; Argon gasification;80%
ethyl cinnamate
4192-77-2

ethyl cinnamate

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

trimethyl[(3E)-2-methylene-4-phenylbut-3-en-1-yl]silane
80814-92-2, 117747-08-7

trimethyl[(3E)-2-methylene-4-phenylbut-3-en-1-yl]silane

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium In tetrahydrofuran at 20℃; for 3h;
Stage #2: ethyl cinnamate With cerium(III) chloride In tetrahydrofuran at -78 - 20℃;
Stage #3: With silica gel In dichloromethane at 20℃; for 3h; Further stages.;
95%
tributyltin chloride
1461-22-9

tributyltin chloride

magnesium
7439-95-4

magnesium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(trimethylsilyl)(tributylstannyl)methane
77425-85-5

(trimethylsilyl)(tributylstannyl)methane

Conditions
ConditionsYield
With iodine; ammonium chloride In diethyl ether N2-atmosphere; addn. of Me3SiCH2Cl to Mg (activated with I2), refluxing(1 h), addn. of Bu3SnCl, refluxing (18 h); addn. of satd. aq. NH4Cl, extn. of aq. layer (ether), washing of org. layer (satd. aq. NaCl), drying (Na2SO4), evapn. of ether, distn. (vac.);95%
2-chloro-1-(2,4-dichlorophenyl)ethanone
51336-94-8

2-chloro-1-(2,4-dichlorophenyl)ethanone

(trimethylsilyl)methylmagnesium chloride
13170-43-9

(trimethylsilyl)methylmagnesium chloride

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

1-(1-chloromethylethenyl)-2,4-difluorobenzene
156570-10-4

1-(1-chloromethylethenyl)-2,4-difluorobenzene

Conditions
ConditionsYield
Stage #1: (trimethylsilyl)methylmagnesium chloride; Chloromethyltrimethylsilane With magnesium In tert-butyl methyl ether at 55℃; for 4h;
Stage #2: 2-chloro-1-(2,4-dichlorophenyl)ethanone In tert-butyl methyl ether at -10 - 0℃;
Stage #3: With sulfuric acid In tert-butyl methyl ether at 25 - 50℃; for 3h;
95%
(S)-1-phenyl-ethylamine
2627-86-3

(S)-1-phenyl-ethylamine

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

N-(S)-α-methylbenzyl-N-((trimethylsilyl)methyl)amine
135782-16-0

N-(S)-α-methylbenzyl-N-((trimethylsilyl)methyl)amine

Conditions
ConditionsYield
In neat (no solvent) at 200℃; for 3h; Sealed tube;94%
With triethylamine for 16h; Reflux; Inert atmosphere;76%
With potassium carbonate In acetonitrile for 4h; Heating;75%
(Z)-3-bromo-4-trimethylsilyl-3-buten-2-one
1257841-93-2

(Z)-3-bromo-4-trimethylsilyl-3-buten-2-one

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

(Z)-2-bromo-3-methyl-1-trimethylsilyl-1,3-butadiene
1257841-99-8

(Z)-2-bromo-3-methyl-1-trimethylsilyl-1,3-butadiene

Conditions
ConditionsYield
Stage #1: Chloromethyltrimethylsilane With magnesium; ethylene dibromide In diethyl ether for 1h; Inert atmosphere; Reflux;
Stage #2: (Z)-3-bromo-4-trimethylsilyl-3-buten-2-one In diethyl ether at 0℃; Peterson olefination; Inert atmosphere;
Stage #3: With water; acetic acid at 50℃; for 6h; Peterson olefination; Inert atmosphere;
94%
[tris(trimethylsilyl)silyl]potassium

[tris(trimethylsilyl)silyl]potassium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

2-(trimethylsilyl)-2-[(trimethylsilyl)methyl]hexamethyltrisilane
1253730-05-0

2-(trimethylsilyl)-2-[(trimethylsilyl)methyl]hexamethyltrisilane

Conditions
ConditionsYield
In benzene at 0℃; for 2h;94%
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