Conditions | Yield |
---|---|
In hydrogenchloride byproducts: CO2; Zr(CO3)2 dissolved in concd. HCl, refluxed for 1 h; cooled, filtered, washed with cold concd. HCl, recrystd. from aq. HCl, air dried; |
ziconium(IV) oxychloride octahydrate
dimethyl methane phosphonate
Conditions | Yield |
---|---|
With aq. HCl In water reflux (24 h or 112 h); aq. HBr or H2O alone may also be used; filtration, washing (H2O; acetone), drying (40°C, 18 h, then 200°C, 24 h); elem. anal.; | 99% |
Conditions | Yield |
---|---|
In water | 95% |
Conditions | Yield |
---|---|
In water | 95% |
Conditions | Yield |
---|---|
In water | 95% |
Conditions | Yield |
---|---|
In water | 95% |
Conditions | Yield |
---|---|
In water | 95% |
ziconium(IV) oxychloride octahydrate
sodium tungstate (VI) dihydrate
Conditions | Yield |
---|---|
With hydrogenchloride In water at 160℃; Autoclave; | 95% |
ziconium(IV) oxychloride octahydrate
Acetylenedicarboxylic acid
Conditions | Yield |
---|---|
Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In N,N-dimethyl-formamide Sonication; Stage #2: In N,N-dimethyl-formamide at 85℃; for 6h; Sealed tube; | 94% |
ziconium(IV) oxychloride octahydrate
Acetylenedicarboxylic acid
Conditions | Yield |
---|---|
Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In water; N,N-dimethyl-formamide for 0.0333333h; Sonication; Stage #2: at 85℃; for 6h; Sealed tube; | 94% |
ziconium(IV) oxychloride octahydrate
ammonium fluoride
Conditions | Yield |
---|---|
Stage #1: ziconium(IV) oxychloride octahydrate; potassium oleate With Elaidic Acid; oleylamine at 20℃; for 2h; Stage #2: ammonium fluoride; potassium fluoride In water at 50 - 200℃; for 12.5h; Reagent/catalyst; Autoclave; | A 89.4% B n/a |
ziconium(IV) oxychloride octahydrate
ammonium fluoride
Conditions | Yield |
---|---|
Stage #1: ziconium(IV) oxychloride octahydrate; potassium oleate With Elaidic Acid; oleylamine at 20℃; for 2h; Stage #2: ammonium fluoride; potassium fluoride In water at 50 - 200℃; for 12.5h; Autoclave; | 89.4% |
ziconium(IV) oxychloride octahydrate
(2E)-but-2-enedioic acid
Conditions | Yield |
---|---|
With acetic acid In water at 85℃; Microwave irradiation; Flow reactor; Green chemistry; | 88% |
ziconium(IV) oxychloride octahydrate
water
Conditions | Yield |
---|---|
With hydrogen fluoride In methanol at 80℃; for 48h; | 86% |
ziconium(IV) oxychloride octahydrate
piperidinomethylphosphonic acid
hydrogen fluoride
Conditions | Yield |
---|---|
In propan-1-ol; water a soln. piperidine-compound in n-propanol-water was added to a soln. of Zr-compound and HF, maintained in closed plastic vessel at 80°C for 3 days; ppt. was centrifuged, washed with propanol-water, dried in an oven at 70°C; elem. anal.; | 85% |
ziconium(IV) oxychloride octahydrate
formic acid
benzene-1,3,5-tricarboxylic acid
N,N-dimethyl-formamide
Conditions | Yield |
---|---|
at 130℃; for 0.48h; | 85% |
ziconium(IV) oxychloride octahydrate
1,10-Phenanthroline
salicylaldehyde anthranilic acid
Conditions | Yield |
---|---|
In ethanol for 12h; Reflux; | 84% |
ziconium(IV) oxychloride octahydrate
ammonium fluoride
sodium oleate
Conditions | Yield |
---|---|
Stage #1: ziconium(IV) oxychloride octahydrate; sodium oleate With Elaidic Acid; oleylamine at 20℃; for 6h; Stage #2: ammonium fluoride; sodium fluoride In water at 25℃; for 12.5h; | 83.1% |
ziconium(IV) oxychloride octahydrate
water
Conditions | Yield |
---|---|
at 80℃; for 3h; | 82% |
ziconium(IV) oxychloride octahydrate
benzene-1,3,5-tricarboxylic acid
Conditions | Yield |
---|---|
With acetic acid In water at 95℃; for 5h; Microwave irradiation; Green chemistry; Large scale; | 81% |
ziconium(IV) oxychloride octahydrate
carbamazepin
Conditions | Yield |
---|---|
In ethanol for 3h; Reflux; | 79.8% |
Conditions | Yield |
---|---|
In methanol methanolic soln. of ZrOCl2*8H2O was added to moxifloxacin in methanol, stirred at room temp. for 22 h; slow evapn., ppt. was filtered off, washed with bidistilled water several times, dried over CaCl2 in desecrator, ppt. was filtered off, dried invac. over CaCl2; elem. anal.; | 78.34% |
ziconium(IV) oxychloride octahydrate
Conditions | Yield |
---|---|
In ethanol at 70℃; for 3h; | 74% |
ziconium(IV) oxychloride octahydrate
(3E)-2-(hydroxyimino)-N-p-tolyl-3-(p-tolylimino)butanamide
Conditions | Yield |
---|---|
In ethanol; N,N-dimethyl acetamide Reflux; | 73% |
ziconium(IV) oxychloride octahydrate
water
Conditions | Yield |
---|---|
With sodium hydroxide for 72h; pH=3.5; Reflux; | 72% |
With sodium hydroxide for 72h; pH=3.5; Reflux; | 72% |
ziconium(IV) oxychloride octahydrate
formic acid
N,N-dimethyl-formamide
Conditions | Yield |
---|---|
at 120℃; for 48h; Autoclave; | 72% |
ziconium(IV) oxychloride octahydrate
N-phosphonoethyl-4-carboxypyridinium chloride
hydrogen fluoride
C8H9F3NO5PZr
Conditions | Yield |
---|---|
at 80℃; for 72h; | 71% |
ziconium(IV) oxychloride octahydrate
Thiophene-2,5-dicarboxylic acid
Conditions | Yield |
---|---|
With acetic acid In water at 95℃; for 1h; Microwave irradiation; Green chemistry; Large scale; | 70% |
ziconium(IV) oxychloride octahydrate
formic acid
benzene-1,3,5-tricarboxylic acid
water
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Schlenk technique; | 70% |
ziconium(IV) oxychloride octahydrate
diethyl amine hydrochloride
Conditions | Yield |
---|---|
With Na2CO3; HCl In water to a soln. of polyoxotungstate in water was added Na2CO3, stirred for 20min., ZrCl2O*8H2O was added, stirred for 5 min, 1 M aq. HCl was added f or 1 min, stirred for 15 min, a soln. of Hf-compound in aq. HCl was added, stirred for 30 min; passed through a folded filter paper, evapd. at 40°C, stirred for1 min in a water bath at more than 90°C, (C2H5)2NH2Cl was added, stirred for 5 min, cooled to roomtemp., filtered, washed with C2H5OH, d ried in vac. for 2 h; elem. anal.; | 69.7% |
ziconium(IV) oxychloride octahydrate
N-(phosphonemethyl)glycine
hydrogen fluoride
Conditions | Yield |
---|---|
at 80℃; for 48h; pH=2.17; | 68% |
The Zirconyl chloride oxide octahydrate is an organic compound with the formula ZrOCl2.8(H2O). The IUPAC name of this chemical is oxozirconium octahydrate dihydrochloride. With the CAS registry number 13520-92-8, it is also named as Zirconium oxychloride octahydrate. The product's classification codes are Mutation data; Tumor data. Besides, it should be stored in a dry and well-ventilated place. It is used to manufacture zirconia. It is also used as rubber additives, paint drying, refractories, ceramics, glaze, and fiber treatment agent. It is widely used in rubber additives, paint driers, refractory and ceramic glaze.
Physical properties about Zirconyl chloride oxide octahydrate are: (1)#H bond acceptors: 1; (2)Polar Surface Area: 17.07 Å2.
Preparation: this chemical can be prepared by zircon and caustic soda. This reaction will need reagent sulfuric acid, ammonia, hydrochloric acid.
ZrSiO3+4NaOH→Na2ZrO3+NazSiO3+2H2O
Na2ZrO3+3H2SO4→Zr(SO4)2+Na2SO4+3H2O
Zr(SO4)2+4NH3.H2O→Zr(OH)4↓+2(NH4)2SO4
Zr(OH)4+2HCl+5H2O→ZrOCl2.8(H2O)
When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed. Please take off immediately all contaminated clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: O=[Zr].Cl.Cl.O.O.O.O.O.O.O.O
(2)InChI: InChI=1/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;/r2ClH.OZr.8H2O/c;;1-2;;;;;;;;/h2*1H;;8*1H2
(3)InChIKey: FUBACIUATZGHAC-FUJGLDTFAK
(4)Std. InChI: InChI=1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;
(5)Std. InChIKey: FUBACIUATZGHAC-UHFFFAOYSA-N
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