Encyclopedia

  • Stephen Aldehyde Synthesis

    Stephen Aldehyde Synthesis H. Stephen, J. Chem. Soc. 127, 1874 (1925); T. Stephen, H. Stephen, ibid. 1956, 4695. Reaction sequence employed to convert n

  • Staudinger Reaction

    Staudinger Reaction H. Staudinger, J. Meyer, Helv. Chim. Acta 2, 635 (1919). Synthesis of phosphazo compounds by the reaction of tertiary phosphines wit

  • Sommelet Reaction

    Sommelet Reaction M. Sommelet, Compt. Rend. 157, 852 (1913); Bull. Soc. Chim. France [4] 23, 95 (1918). Preparation of aldehydes from aralkyl halides by

  • Smiles Rearrangement

    Smiles Rearrangement; Truce-Smiles Rearrangement A. A. Levi et al., J. Chem. Soc. 1931, 3264; W. J. Evans, S. Smiles, ibid. 1935, 181; 1936, 329. Intram

  • Skraup Reaction

    Skraup Reaction Z. H. Skraup, Ber. 13, 2086 (1880). Synthesis of quinolines from aromatic amines, glycerol, an oxidizing agent and sulfuric acid:

  • Simonis Chromone Cyclization

    Simonis Chromone Cyclization E. Petschek, H. Simonis, Ber. 46, 2014 (1913). Formation of chromones from phenol and β-keto esters in the presence of

  • Simonini Reaction

    Simonini Reaction A. Simonini, Monatsh. 13, 320 (1892); 14, 81 (1893). The preparation of aliphatic esters by the reaction of the silver salt of a carbo

  • Simmons-Smith Reaction

    Simmons-Smith Reaction H. E. Simmons, R. D. Smith, J. Am. Chem. Soc. 80, 5323 (1958). Stereospecific synthesis of cyclopropanes by treatment of olefins

  • Sharpless Oxyamination

    Sharpless Oxyamination K. B. Sharpless et al., J. Am. Chem. Soc. 97, 2305 (1975). -mediated cis-addition of nitrogen and oxygen moieties to mono-, di- a

  • Sharpless Epoxidation

    Sharpless Epoxidation T. Katsuki, K. B. Sharpless, J. Am. Chem. Soc. 102, 5974 (1980). -catalyzed asymmetric epoxidation of allylic alcohols employing t

  • Sharpless Dihydroxylation

    Sharpless Dihydroxylation E. N. Jacobsen et al., J. Am. Chem. Soc. 110, 1968 (1988). -catalyzed asymmetric cis-dihydroxylation of olefins:

  • Serini Reaction

    Serini Reaction A. Serini et al., Ber. 72, 391 (1939). -promoted rearrangement of 17-hydroxy-20-acetoxysterol derivatives into C-20 ketones; the reactio

  • Semmler-Wolff Reaction

    Semmler-Wolff Reaction (Wolff-Semmler Aromatization, Wolff Aromatization) W. Semmler, Ber. 25, 3352 (1892); L. Wolff, Ann. 322, 351 (1902). Rearrangemen

  • Schöllkopf Bis-Lactim Amino Acid Synthesis

    Schöllkopf Bis-Lactim Amino Acid Synthesis U. Schöllkopf et al., Angew. Chem. Int. Ed. 18, 863 (1979); 20, 798 (1981). Asymmetric amino acid s

  • Scholl Reaction

    Scholl Reaction R. Scholl, C. Seer, Ann. 394, 111 (1912). Coupling of aromatic molecules by treatment with Lewis acid catalysts:

  • Schmidt Reaction

    Schmidt Reaction R. F. Schmidt, Ber. 57, 704 (1924). Acid-catalyzed addition of hydrazoic acid to carboxylic acids, aldehydes and ketones to give amines

  • Sandmeyer Isonitrosoacetanilide Isatin Synthesis

    Sandmeyer Isonitrosoacetanilide Isatin Synthesis T. Sandmeyer, Helv. Chim. Acta 2, 234 (1919). Formation of isonitrosoacetodiphenylamidine by condensati

  • Sandmeyer Diphenylurea Isatin Synthesis

    Sandmeyer Diphenylurea Isatin Synthesis T. Sandmeyer, Z. Farb. Textile Chem. 2, 129 (1903). Formation of a cyanoformamidine by treatment of a symmetrica

  • Saegusa Oxidation

    Saegusa Oxidation Y. Ito et al., J. Org. Chem. 43, 1011 (1978). Conversion of silyl enol ethers into corresponding α,β-eneones using stoichio

  • Sabatier-Senderens Reduction

    Sabatier-Senderens Reduction P. Sabatier, J. B. Senderens, Compt. Rend. 128, 1173 (1899). Catalytic hydrogenation of organic compounds in the vapor phas

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