Encyclopedia

  • Nef Synthesis

    Nef Synthesis J. U. Nef, Ann. 308, 281 (1899). Addition of sodium acetylides to aldehydes and ketones to yield acetylenic carbinols; occasionally and er

  • Nef Reaction

    Nef Reaction J. U. Nef, Ann. 280, 263 (1894). Formation of aldehydes and ketones from primary and secondary nitroalkanes, respectively, by treatment of

  • Neber Rearrangement

    Neber Rearrangement P. W. Neber, A. v. Friedolsheim, Ann. 449, 109 (1926); P. W. Neber, G. Huh, ibid. 515, 283 (1935). Formation of α-amino ketone

  • Nazarov Cyclization Reaction

    Nazarov Cyclization Reaction I. N. Nazarov et al., Izv. Akad. Nauk S.S.S.R., Otd. Khim. Nauk 1942, 200. Protic or Lewis acid-catalyzed electrocyclic rin

  • Ziegler-Natta Polymerization

    Ziegler-Natta Polymerization K. Ziegler et al., Angew. Chem. 67, 426, 541 (1955); G. Natta, ibid. 68, 393 (1956). Polymerization of vinyl monomers under

  • Nametkin Rearrangement

    Nametkin Rearrangement S. S. Nametkin, Ann. 432, 207 (1923). A special case of carbonium ion rearrangement in camphene hydrochloride derivatives involvi

  • Nagata Hydrocyanation

    Nagata Hydrocyanation W. Nagata et al., Tetrahedron Letters 1962, 461. Alkylaluminum-mediated 1,4-addition of hydrogen cyanide to α,β-unsatur

  • Sonn-Müller Method

    Sonn-Müller Method A. Sonn, E. Müller, Ber. 52, 1927 (1919). Reaction sequence employed to convert aromatic anilides to aldehydes. Treatment o

  • Mukaiyama Aldol Reaction

    Mukaiyama Aldol Reaction T. Mukaiyama et al., Chem Lett. 1973, 1011; idem et al., ibid. 1974, 323; eidem, J. Am. Chem. Soc. 96, 7503 (1974). Formation o

  • Wessely-Moser Rearrangement

    Wessely-Moser Rearrangement F. Wessely, G. H. Moser, Monatsh. 56, 97 (1930). Rearrangement of flavones and flavanones possessing a 5-hydroxyl group, thr

  • Moore Myers Cyclization

    Moore Myers Cyclization; Moore Cyclization; Myers Cyclization J. O. Karlsson et al., J. Am. Chem. Soc. 107, 3392 (1985); A. G. Myers et al., ibid. 111, 8057 (1989); R. Nag

  • Swern Oxidation

    Swern Oxidation (Moffatt-Swern Oxidation) K. Omura, D. Swern, Tetrahedron 34, 1651 (1978). Mild oxidation of primary and secondary alcohols, promoted by

  • Pfitzner-Moffatt Oxidation

    Pfitzner-Moffatt Oxidation (Moffatt Oxidation) K. E. Pfitzner, J. G. Moffatt, J. Am. Chem. Soc. 85, 3027 (1963). Mild oxidation of primary and secondary

  • Mitsunobu Reaction

    Mitsunobu Reaction O. Mitsunobu et al., Bull. Chem. Soc. Japan 40, 935 (1967); O. Mitsunobu, Y. Yamada, ibid. 2380. Condensation of alcohols and acidic

  • Milas Hydroxylation of Olefins

    Milas Hydroxylation of Olefins N. A. Milas et al., J. Am. Chem. Soc. 58, 1302 (1936); 59, 543, 2342, 2345 (1937); 61, 1844 (1939); 62, 1841 (1940). Form

  • Mignonac Reaction

    Mignonac Reaction G. Mignonac, Compt. Rend. 172, 223 (1921). Formation of amines by catalytic hydrogenation of aldehydes or ketones in liquid ammonia an

  • Miescher Degradation

    Miescher Degradation C. Meystre et al., Helv. Chim. Acta 27, 1815 (1944). Adaptation of the Barbier-Wieland degradation, q.v., to permit simultaneous el

  • Mukaiyama-Michael Reaction

    Mukaiyama-Michael Reaction K. Narasaka et al., Bull. Chem. Soc. Japan 49, 779 (1976). Formation of 1,5-dicarbonyl compounds by reaction of ketene silyl

  • Meyers Aldehyde Synthesis

    Meyers Aldehyde Synthesis A. I. Meyers et al., J. Am. Chem. Soc. 91, 763 (1969); eidem, J. Org. Chem. 38, 36 (1973). Synthesis of aldehydes from alkylha

  • Meyer-Schuster Rearrangement

    Meyer-Schuster Rearrangement; Rupe Rearrangement K. H. Meyer, K. Schuster, Ber. 55, 819 (1922); H. Rupe, E. Kambli, Helv. Chim. Acta 9, 672 (1926). Acid

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