Encyclopedia

  • Combination Reactions

    Two or more reactants form one product in a combination reaction. An example of a combination reaction is the formation of sulfur dioxide when sulfur is burned in air: S (s) + O2 (g

  • Zincke Nitration

    ke Nitration T. Zincke, J. Prakt. Chem. 61, 561 (1900). Replacement of ortho- or para-bromine or iodine atoms (but not fluorine or chlorine atoms) in ph

  • Zincke Disulfide Cleavage

    ke Disulfide Cleavage T. Zincke, Ber. 44, 769 (1911). Formation of sulfenyl halides by three essentially similar methods involving the action of chlorin

  • Zimmermann Reaction

    Zimmermann Reaction W. Zimmermann, Z. Physiol. Chem. 233, 257 (1935). The reaction that occurs between methylene ketones and aromatic polynitro compound

  • Wurtz Reaction

    Wurtz Reaction A. Wurtz, Ann. Chim. Phys. [3] 44, 275 (1855); Ann. 96, 364 (1855). Coupling of two alkyl radicals by treating two moles of alkyl halides

  • Wolff Rearrangement

    Wolff Rearrangement L. Wolff Ann. 394, 25 (1912). Rearrangement of diazoketones to ketenes thermally, photochemically or catalytically. The rearrangemen

  • Wohl-Ziegler Reaction

    Wohl-Ziegler Reaction A. Wohl, Ber. 52, 51 (1919); K. Ziegler et al., Ann. 551, 30 (1942). Allylic bromination of olefins with N-. Peroxides or ultravio

  • Wohl Degradation

    Wohl Degradation; Zemplén Modification A. Wohl, Ber. 26, 730 (1893); 32, 3666 (1899); G. Zemplén, Ber. 59, 1254, 2402 (1926). Method for t

  • [2,3]-Wittig Rearrangement

    [2,3]-Wittig Rearrangement J. Cast et al., J. Chem. Soc. 1960, 3521; U. Schöllkopf, K. Fellenberger, Ber. 698, 80 (1966); Y. Makisumi, S. Notzumoto, Tetrahedron Lette

  • [1,2]-Wittig Rearrangement

    [1,2]-Wittig Rearrangement G. Wittig, L. Löhmann, Ann. 550, 260 (1942); G. Wittig, Experientia 14, 389 (1958). Rearrangement of ethers with alkyl l

  • Williamson Synthesis

    Williamson Synthesis A. W. Williamson, J. Chem. Soc. 4, 229 (1852). Synthesis of ethers by alkylation of alkoxides with alkyl halides or alkyl sulfates:

  • Wichterle Reaction

    Wichterle Reaction O. Wichterle et al., Coll. Czech. Chem. Commun. 13, 300 (1948). Modification of the Robinson annulation, q.v., in which 1,3-dichloro-

  • Whiting Reaction

    Whiting Reaction P. Nayler, M. C. Whiting, J. Chem. Soc. 1954, 4006. Alkynediols are reduced by lithium aluminum hydride in ether or tertiary amines to

  • Wharton Reaction

    Wharton Reaction P. S. Wharton, D. H. Bohlen, J. Org. Chem. 26, 3615 (1961); P. S. Wharton, ibid. 4781. Reduction of α,β-epoxy ketones by hyd

  • Weiss Reaction

    Weiss Reaction U. Weiss, J. M. Edwards, Tetrahedron Letters 1968, 4885. Reaction of 1,2-dicarbonyl compounds with 3-oxoglutarates to yield cis-bicyclo[3

  • Weerman Degradation

    Weerman Degradation R. A. Weerman, Rec. Trav. Chim. 37, 1, 16 (1918). Formation of an aldose with one less carbon from an aldonic acid by a Hofmann-type

  • Wallach Rearrangement

    Wallach Rearrangement O. Wallach, L. Belli, Ber. 13, 525 (1880). Acid-catalyzed rearrangement of azoxybenzenes to p-hydroxyazobenzenes:

  • Walden Inversion

    Walden Inversion P. Walden, Ber. 28, 1287, 2766 (1895). Inversion of configuration of a chiral center in bimolecular nucleophilic substitution (SN2) rea

  • Wacker Oxidation

    Wacker Oxidation J. Smidt et al., Angew. Chem. Int. Ed. 1, 176 (1959). The oxidation of ethylene to employing palladium chloride and cupric chloride as

  • Vorbrüggen Glycosylation

    Vorbrüggen Glycosylation U. Niedballa, H. Vorbrüggen, Angew. Chem. Int. Ed. 9, 461 (1970). The reaction of silylated heterocyclic bases with p

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