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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate. In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so o

TIANFU CHEM 2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole CAS 1000623-98-2

Cas:1000623-98-2

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1000623-98-2 with best quality

Cas:1000623-98-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

3,6-Bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Cas:1000623-98-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Factory Sells2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole Synonyms: 2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole;3,6-Bis(5-broMo-2-thienyl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione;3,6-bis(5-broMo-2-thien

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

3,6-Bis(5-bromo-2-thienyl)-2,5-bis(2-hexyldecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

BOC Sciences

BOC Sciences is a US-based provider of specially designed scaffolds and building blocks products and services for academic and governmental research institutes, pharmaceutical and biotechnology industry. We offer an extensive catalog of building bl

3,6-Bis(5-bromo-2-thienyl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Cas:1000623-98-2

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Low price 3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione manufacturerAppearance:Purple solid Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Use as the material of OPV Transp

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

3,6-Bis(5-bromo-2-thienyl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

DB BIOTECH CO., LTD

best seller Application:API

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Helios Biomedical Science and Technology Co.,LTD.

Changzhou Helios Biochemical Co., Ltd is a leading manufacturer and supplier for medical intermediates and pesticide intermediates . We specialize in custom synthesis of benzene ring, pyridine and pyrimidine derivatives to help customers to accelerat

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Order Science & Technology Co., Ltd

factory?direct?sale Application:healing drugs

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,5-Di(HD)-3,6-di(5-broMothiophen)diketopyrrolopyrrole

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

3,6-Bis(5-bromo-2-thienyl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Cas:1000623-98-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Appearance:powder Storage:Refrigerator Package:Depended Application:150600-72-9 Transportation:by air or by sea Port:China Main Port

Factory price photoelectric material 1000623-98-2

Cas:1000623-98-2

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer and can provide high quality products with factory pric

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

National Research Platform ISO 9001 1000623-98-2

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

1000623-98-2

Cas:1000623-98-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
1044598-80-2

3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Conditions
ConditionsYield
With N-Bromosuccinimide In chloroform at 50℃; for 2h; Inert atmosphere;79.9%
With N-Bromosuccinimide In chloroform for 48h; Darkness;61%
With N-Bromosuccinimide In chloroform for 48h; Darkness;60%
3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
1044598-80-2

3,6-bis(5-bromothien-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

A

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

B

3-(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)-6-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
1423138-95-7

3-(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)-6-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
With N-Bromosuccinimide In chloroform at 0 - 20℃; Darkness;A 17%
B 56%
3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

7-(iodomethyl)pentadecane
1044598-79-9

7-(iodomethyl)pentadecane

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate / N,N-dimethyl-formamide / 120 °C
2: N-Bromosuccinimide / chloroform / 20 °C
View Scheme
thiophene-2-carbonitrile
1003-31-2

thiophene-2-carbonitrile

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium / tert-Amyl alcohol / 120 °C
2: potassium carbonate / N,N-dimethyl-formamide / 120 °C
3: N-Bromosuccinimide / chloroform / 20 °C
View Scheme
Multi-step reaction with 3 steps
1: potassium tert-butylate / tert-Amyl alcohol / 4 h / 110 °C
2: potassium carbonate / N,N-dimethyl-formamide / 24 h / 110 °C
3: N-Bromosuccinimide / chloroform / 48 h / Darkness
View Scheme
Multi-step reaction with 3 steps
1.1: potassium tert-butylate / tert-Amyl alcohol / 5 h / 110 °C / Inert atmosphere
2.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 130 °C / Inert atmosphere
2.2: 130 °C / Inert atmosphere
3.1: N-Bromosuccinimide / chloroform / 2 h / 50 °C / Inert atmosphere
View Scheme
2-hexyldecan-1-ol
2425-77-6

2-hexyldecan-1-ol

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 20 °C
2: potassium carbonate / N,N-dimethyl-formamide / 120 °C
3: N-Bromosuccinimide / chloroform / 20 °C
View Scheme
3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 110 °C
2: N-Bromosuccinimide / chloroform / 48 h / Darkness
View Scheme
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2,5-bis(2-hexyldecyl)-3,6-bis(5-phenylthiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

2,5-bis(2-hexyldecyl)-3,6-bis(5-phenylthiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

Conditions
ConditionsYield
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With tris-(dibenzylideneacetone)dipalladium(0); Aliquat (at)366; triphenylphosphine In water; toluene for 0.25h; Schlenk technique; Inert atmosphere;
Stage #2: With potassium phosphate In water; toluene at 115℃; for 16h; Schlenk technique; Inert atmosphere; Sealed tube;
97%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

A

2,5-bis(2-hexyldecyl)-3,6-bis(5-phenylthiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

2,5-bis(2-hexyldecyl)-3,6-bis(5-phenylthiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

B

C104H150N4O4S4

C104H150N4O4S4

Conditions
ConditionsYield
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With tris-(dibenzylideneacetone)dipalladium(0); Aliquat (at)366; triphenylphosphine In water; toluene Schlenk technique; Inert atmosphere;
Stage #2: With potassium phosphate In water; toluene at 115℃; Schlenk technique; Inert atmosphere; Sealed tube;
A 87%
B 6.6%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-Ethynylanthracene
78053-56-2

2-Ethynylanthracene

3,6-bis(5-(anthracen-2-ylethynyl)thiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

3,6-bis(5-(anthracen-2-ylethynyl)thiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In toluene at 60℃; for 8h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;75%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

C15H15BF2N2
1625689-09-9

C15H15BF2N2

C76H98B2F4N6O2S2

C76H98B2F4N6O2S2

Conditions
ConditionsYield
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In tetrahydrofuran Schlenk technique; Inert atmosphere;
Stage #2: C15H15BF2N2 In tetrahydrofuran at 60℃; for 3h; Inert atmosphere;
75%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

phenylacetylene
536-74-3

phenylacetylene

2,5-bis(2-hexyldecyl)-3,6-bis(5-(phenylethynyl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

2,5-bis(2-hexyldecyl)-3,6-bis(5-(phenylethynyl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In toluene at 60℃; for 8h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;72%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

tributyl(thien-2-yl)stannane
54663-78-4

tributyl(thien-2-yl)stannane

3,6-di([2,2'-bithiophen]-5-yl)-2,5-bis(2-hexyldecyl)pyrrolo [3,4-c]pyrrole-1,4(2H,5H)-dione
1143585-34-5

3,6-di([2,2'-bithiophen]-5-yl)-2,5-bis(2-hexyldecyl)pyrrolo [3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tris-(o-tolyl)phosphine In toluene at 90℃; for 24h; Stille Cross Coupling; Inert atmosphere;72%
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-ethynylnaphthalene
2949-26-0

2-ethynylnaphthalene

2,5-bis(2-hexyldecyl)-3,6-bis(5-(naphthalen-2-ylethynyl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

2,5-bis(2-hexyldecyl)-3,6-bis(5-(naphthalen-2-ylethynyl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In toluene at 60℃; for 8h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;67%
tributyl(3-dodecylcyclopenta-1,3-dien-1-yl)stannane

tributyl(3-dodecylcyclopenta-1,3-dien-1-yl)stannane

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

C78H124N2O2S4
1000623-99-3

C78H124N2O2S4

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In toluene Heating / reflux;
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-(4-dodecylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1173788-58-3

2-(4-dodecylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

C62H97BrN2O2S3

C62H97BrN2O2S3

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 115℃; for 24h; Suzuki coupling;1.062 g
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

3,6-bis(5'-bromo-[2,2'-bithiophen]-5-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
1143585-35-6

3,6-bis(5'-bromo-[2,2'-bithiophen]-5-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tris-(dibenzylideneacetone)dipalladium(0); tris-(o-tolyl)phosphine / toluene / 24 h / 90 °C / Inert atmosphere
2: N-Bromosuccinimide / chloroform / 6 h / 20 °C / Inert atmosphere; Darkness
View Scheme
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

6,6'-([2,2'-bithiophene]-5,5'-diyl)bis(3-(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione)

6,6'-([2,2'-bithiophene]-5,5'-diyl)bis(3-(5-bromothiophen-2-yl)-2,5-bis(2-hexyldecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione)

Conditions
ConditionsYield
With palladium diacetate; N-ethyl-N,N-diisopropylamine In toluene Inert atmosphere; Reflux;
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

2-([2,2'-bithiophen]-5-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
479719-88-5

2-([2,2'-bithiophen]-5-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

C54H75BrN2O2S4

C54H75BrN2O2S4

Conditions
ConditionsYield
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 2-([2,2'-bithiophen]-5-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With tris-(dibenzylideneacetone)dipalladium(0); tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran for 0.5h; Suzuki Coupling; Inert atmosphere; Reflux;
Stage #2: With potassium phosphate In tetrahydrofuran; water Suzuki Coupling; Inert atmosphere; Reflux;
3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione
1000623-98-2

3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione

4,4,5,5-tetramethyl-2-(12,22:25,32-terthiophen-15-yl)-1,3,2-dioxaborolane
849062-17-5

4,4,5,5-tetramethyl-2-(12,22:25,32-terthiophen-15-yl)-1,3,2-dioxaborolane

C58H77BrN2O2S5

C58H77BrN2O2S5

Conditions
ConditionsYield
Stage #1: 3,6-bis(5-bromo-2-thienyl)-2,5-dihydro-2,5-di(2'-hexyldecyl)-pyrrolo[3,4c]pyrrolo-1,4-dione; 4,4,5,5-tetramethyl-2-(12,22:25,32-terthiophen-15-yl)-1,3,2-dioxaborolane With tris-(dibenzylideneacetone)dipalladium(0); tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran for 0.5h; Suzuki Coupling; Inert atmosphere; Reflux;
Stage #2: With potassium phosphate In tetrahydrofuran; water Suzuki Coupling; Inert atmosphere; Reflux;

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