High purity CAS 114435-02-8 4-Fluoro-1,3-dioxolan-2-one in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (Flu
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inquiryProduct description: Product name 4-Fluoro-1,3-dioxolan-2-one CAS number 114435-02-8 Assay ≥99% Appearance Colorless transparent liquid Capacity 500mt/year Application Electr
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inquiry4-Fluoro-1,3-dioxolan-2-one CAS 114435-02-8 Fluoroethylene carbonate CAS no 114435-02-8 1,3-Dioxolan-2-one,4-fluoro- 4-Fluoro-1,3-dioxolan-2-one 1,3-Dioxolan-2-one,4-fluoro- Fluoroethylene carbonate 4-Fluoro-1,3-dioxolan-2-one CAS 114435-02-8
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inquiryStock products, own laboratory Product number 37473 English Name Fluoroethylene carbonate CAS Number 114435-02-8 Purity 98% Molecular for
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inquiryAbout Product Details 4-Fluoro-1,3-dioxolan-2-one Basic information Product Name: 4-Fluoro-1,3-dioxolan-2-one Synonyms:
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inquiryProduct Name Fluoroethylene Carbonate; FEC CAS No. 114435-02-8 MF C3H3FO3 Appearance Colorless transparent liquid or white crystal
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inquiry[1,3]-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With N-fluorobis(benzenesulfon)imide at 120℃; for 0.5h; Reagent/catalyst; Sealed tube; | 98.2% |
With fluorine at 5℃; Electrolysis; | 94% |
With fluorine at 50℃; | 70% |
4-chloro-1,3-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With potassium fluoride; 5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene; carbonic acid dimethyl ester at 60℃; for 1.5h; Reagent/catalyst; Temperature; | 95.6% |
With triethylamine tris(hydrogen fluoride); triethylamine In ethyl acetate at 80℃; for 1h; Product distribution / selectivity; | 70% |
[1,3]-dioxolan-2-one
C
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With fluorine at 45 - 55℃; under 73.5576 Torr; Product distribution / selectivity; | A n/a B n/a C 78.4% D n/a |
With fluorine at 23.9 - 31.2℃; under 15.0015 Torr; Inert atmosphere; |
4-(p-chlorophenylthio)-1,3-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With triethylamine pentahydrogen fluoride salt In dichloromethane at 20℃; Electrolysis; Pt electrodes; | 75% |
4-(p-chlorophenylthio)-1,3-dioxolan-2-one
A
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Electrolysis; Pt electrodes; | A 20 % Spectr. B 70% |
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Product distribution; Further Variations:; Reagents; Solvents; Fluorination; Electrolysis; | A 20 % Spectr. B 80 % Spectr. |
4-(p-bromophenylthio)-1,3-dioxolan-2-one
A
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Electrolysis; Pt electrodes; | A 4 % Spectr. B 66% |
A
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Electrolysis; Pt electrodes; | A 28 % Spectr. B 44% |
With tetraethylammonium fluoride In dichloromethane at 20℃; Product distribution; Further Variations:; Reagents; Solvents; Fluorination; Electrolysis; | A 29 % Spectr. B 16 % Spectr. |
With triethylamine pentahydrogen fluoride salt In dichloromethane at 20℃; Electrolysis; Pt electrodes; | A 67 % Spectr. B n/a |
4-(p-tolylthio)-1,3-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With triethylamine pentahydrogen fluoride salt In dichloromethane at 20℃; Electrolysis; Pt electrodes; | 40 % Spectr. |
4-(p-tolylthio)-1,3-dioxolan-2-one
A
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Electrolysis; Pt electrodes; | A 23 % Spectr. B 4 % Spectr. C 5 % Spectr. D 14 % Spectr. |
4-(p-methoxyphenylthio)-1,3-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With triethylamine pentahydrogen fluoride salt In dichloromethane at 20℃; Electrolysis; Pt electrodes; | 62 % Spectr. |
4-(p-methoxyphenylthio)-1,3-dioxolan-2-one
A
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With tetraethylammonium fluoride In 1,2-dimethoxyethane at 20℃; Electrolysis; Pt electrodes; | A 41 % Spectr. B n/a C 12 % Spectr. |
4-(p-bromophenylthio)-1,3-dioxolan-2-one
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With triethylamine pentahydrogen fluoride salt In dichloromethane at 20℃; Electrolysis; Pt electrodes; | 54 % Spectr. |
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With triethylamine pentahydrogen fluoride salt; tetraethylammonium chloride at 20℃; Electrochemical reaction; | 89 %Spectr. |
With triethylamine pentahydrogen fluoride salt; tetraethylammonium bromide In dichloromethane at 20℃; Electrochemical reaction; | 78 %Spectr. |
[1,3]-dioxolan-2-one
B
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With fluorine at 50℃; Product distribution / selectivity; Inert atmosphere; |
[1,3]-dioxolan-2-one
C
trifluoroethylene carbonate
D
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With fluorine at 20.8 - 25.8℃; under 1875.19 Torr; Inert atmosphere; |
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With fluorine | A 5% B 11% C 59% |
4-fluoro-1,3-dioxolane-2-one
Conditions | Yield |
---|---|
With N-chloro-succinimide In tetrahydrofuran at 35℃; for 8h; Reagent/catalyst; Solvent; Temperature; |
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