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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic DIMETHYL METHYLGLUTARATE 14035-94-0 Manufacturer

Cas:14035-94-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Methylpentanedioic acid dimethyl ester CAS:14035-94-0

Cas:14035-94-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Pentanedioic acid, 2-methyl-, 1,5-dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Pentanedioic acid, 2-methyl-, 1,5-dimethyl ester

Cas:14035-94-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Pentanedioic acid, 2-methyl-, 1,5-dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

factory?direct?sale Application:healing drugs

Pentanedioic acid, 2-methyl-, 1,5-dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:light yellow liquid Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pr

Pentanedioic acid, 2-methyl-, dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-Methylpentanedioicaciddimethylester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

14035-94-0

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Ikg Chemical Co., Ltd.

IKGCHEM is a leading manufacturer and supplier of chemical in China.As a Professional chemical raw material supplier,our products are produced in accordance with ISO 9001:2015 Quality Management System and ISO14001:2015 Environmental Management Syste

2-Methylpentanedioic Acid Dimethyl Ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Springchem New Material Technology Co.,Limited

1. High quality2. The best price3. The fastest delivery4. Offer high quality fine chemicals, accroding to customer’s needSpringchem can quickly and efficiently provide a variety of organic compounds, OLED intermediates . Main including: Boronic acid

Dimethyl 2-methylpentanedioate

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Dano Pharmaceutical Co.,Ld.

manufacturer Application:Pharmaceutical-Intermediate

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Co.Ltd

2-Methylpentanedioic acid dimethyl ester Application:Pharmaceutical-Intermediate

2-Methylpentanedioic acid dimethyl ester

Cas:14035-94-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

2-methylglutaric acid
18069-17-5

2-methylglutaric acid

C6H11NO3

C6H11NO3

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With sulfuric acid In water at 60℃; for 3h; Temperature; Inert atmosphere;86.1%
2,6-dimethyl-1-cyclohexen-1-yl acetate
6203-89-0

2,6-dimethyl-1-cyclohexen-1-yl acetate

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

methyl 2-methyl-5-oxopentanoate
79664-96-3

methyl 2-methyl-5-oxopentanoate

C

6-oxo-2-methyl-heptanoic acid methyl ester
2570-90-3

6-oxo-2-methyl-heptanoic acid methyl ester

Conditions
ConditionsYield
With lithium perchlorate In methanol; acetic acid at 2 - 3℃; electrolysis; Yield given;A n/a
B n/a
C 72%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

buta-1,3-diene
106-99-0

buta-1,3-diene

A

hexanedioic acid dimethyl ester
627-93-0

hexanedioic acid dimethyl ester

B

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

C

dimethyl 2-propylmaleate
69665-13-0

dimethyl 2-propylmaleate

Conditions
ConditionsYield
2-6-dimethoxybenzoic acid; palladium diacetate In methoxybenzene at 170℃; under 30003 Torr; for 10h; Product distribution / selectivity;A 59%
B 19%
C 13%
methanol
67-56-1

methanol

4-Diethylcarbamoyl-pentanoic acid methyl ester
26682-69-9

4-Diethylcarbamoyl-pentanoic acid methyl ester

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With toluene-4-sulfonic acid
propanoic acid methyl ester
554-12-1

propanoic acid methyl ester

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With sodium methylate
vinyl acetate
108-05-4

vinyl acetate

propanoic acid methyl ester
554-12-1

propanoic acid methyl ester

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

hexane-1,3,5-tricarboxylic acid trimethyl ester
100316-11-8

hexane-1,3,5-tricarboxylic acid trimethyl ester

C

3,5-Bis-methoxycarbonyl-2,3-dimethyl-octanedioic acid dimethyl ester

3,5-Bis-methoxycarbonyl-2,3-dimethyl-octanedioic acid dimethyl ester

D

4,6-Bis-methoxycarbonyl-4-methyl-nonanedioic acid dimethyl ester

4,6-Bis-methoxycarbonyl-4-methyl-nonanedioic acid dimethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 135 - 140℃; for 3h; Yield given. Further byproducts given. Yields of byproduct given;
vinyl acetate
108-05-4

vinyl acetate

propanoic acid methyl ester
554-12-1

propanoic acid methyl ester

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

hexane-1,3,5-tricarboxylic acid trimethyl ester
100316-11-8

hexane-1,3,5-tricarboxylic acid trimethyl ester

C

3,5-Bis-methoxycarbonyl-2,3-dimethyl-octanedioic acid dimethyl ester

3,5-Bis-methoxycarbonyl-2,3-dimethyl-octanedioic acid dimethyl ester

D

4,6-Bis-methoxycarbonyl-2-methyl-nonanedioic acid dimethyl ester

4,6-Bis-methoxycarbonyl-2-methyl-nonanedioic acid dimethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 135 - 140℃; for 3h; Yield given. Further byproducts given. Yields of byproduct given;
vinyl acetate
108-05-4

vinyl acetate

propanoic acid methyl ester
554-12-1

propanoic acid methyl ester

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

hexane-1,3,5-tricarboxylic acid trimethyl ester
100316-11-8

hexane-1,3,5-tricarboxylic acid trimethyl ester

C

4,6-Bis-methoxycarbonyl-4-methyl-nonanedioic acid dimethyl ester

4,6-Bis-methoxycarbonyl-4-methyl-nonanedioic acid dimethyl ester

D

4,6-Bis-methoxycarbonyl-2-methyl-nonanedioic acid dimethyl ester

4,6-Bis-methoxycarbonyl-2-methyl-nonanedioic acid dimethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 135 - 140℃; for 3h; Yield given. Further byproducts given. Yields of byproduct given;
2,6-dimethyl-1-cyclohexen-1-yl acetate
6203-89-0

2,6-dimethyl-1-cyclohexen-1-yl acetate

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

methyl 2-methyl-5-oxopentanoate
79664-96-3

methyl 2-methyl-5-oxopentanoate

C

6-oxo-2-methyl-heptanoic acid methyl ester
2570-90-3

6-oxo-2-methyl-heptanoic acid methyl ester

D

2,6-dimethyl-2-cyclohexen-1-one
40790-56-5

2,6-dimethyl-2-cyclohexen-1-one

E

2,6-dimethyl-2-methoxycyclohexanone
79664-90-7

2,6-dimethyl-2-methoxycyclohexanone

Conditions
ConditionsYield
With lithium perchlorate In methanol; acetic acid Product distribution; Mechanism; var. electrolysis conditions, other cycloalkanone enol acetates, var. 2-oxocycloalkan-1-ols;
carbon monoxide
201230-82-2

carbon monoxide

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

1,3-bis(methoxycarbonyl)-1-butene
53358-17-1

1,3-bis(methoxycarbonyl)-1-butene

B

propanoic acid methyl ester
554-12-1

propanoic acid methyl ester

C

4-oxobutanoic acid methyl ester
13865-19-5

4-oxobutanoic acid methyl ester

D

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

E

4-oxo-heptanedioic acid dimethyl ester
22634-92-0

4-oxo-heptanedioic acid dimethyl ester

Conditions
ConditionsYield
With water; Co(CO)8-diphos at 135℃; under 76000 Torr; for 10h; Product distribution; Mechanism; var. solvents; var. time, pressure and temperature; also acrylonitrile;A 1.3 mmol
B 0.15 mmol
C 0.20 mmol
D 0.20 mmol
E 32.7 mmol
carbon monoxide
201230-82-2

carbon monoxide

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

1,3-bis(methoxycarbonyl)-1-butene
53358-17-1

1,3-bis(methoxycarbonyl)-1-butene

B

4-oxobutanoic acid methyl ester
13865-19-5

4-oxobutanoic acid methyl ester

C

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

D

4-oxo-heptanedioic acid dimethyl ester
22634-92-0

4-oxo-heptanedioic acid dimethyl ester

Conditions
ConditionsYield
With water; dicobalt octacarbonyl; 1,2-bis-(diphenylphosphino)ethane In 1,4-dioxane at 135℃; under 76000 Torr; for 10h; Further byproducts given;A 1.3 mmol
B 0.20 mmol
C 0.20 mmol
D 32.7 mmol
(E)-(1-methoxyprop-1-enyloxy)trimethylsilane
72658-09-4

(E)-(1-methoxyprop-1-enyloxy)trimethylsilane

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With hydrogenchloride; aluminum ion-exchanged montmorillonite 1.) -78 deg C, 1 h, CH2Cl2, 2.) r.t.; Yield given. Multistep reaction;
2-Methoxycarbonyl-4-methyl-pentanedioic acid dimethyl ester
35299-08-2

2-Methoxycarbonyl-4-methyl-pentanedioic acid dimethyl ester

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
Stage #1: 2-Methoxycarbonyl-4-methyl-pentanedioic acid dimethyl ester With potassium hydroxide
Stage #2: With hydrogenchloride
methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

divinylbenzene

divinylbenzene

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: NaOMe / methanol
2.1: KOH
2.2: HCl
View Scheme
2-diethylamino-6-methoxy-3-methyl-4H-pyran

2-diethylamino-6-methoxy-3-methyl-4H-pyran

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aq. HCl
2: TsOH
View Scheme
methanol
67-56-1

methanol

2-methylglutaric acid
18069-17-5

2-methylglutaric acid

A

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

B

4-methoxycarbonylpentanoic acid
34927-41-8

4-methoxycarbonylpentanoic acid

C

4-methoxycarbonyl-2-R-methylbutyric acid
62115-18-8

4-methoxycarbonyl-2-R-methylbutyric acid

Conditions
ConditionsYield
at 60℃; for 1h;
dimethyl 2-methylenepentanedioate
5621-44-3

dimethyl 2-methylenepentanedioate

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; C61H52N2O2P2; (S)-(phenylcarbamoyl)-N-valine; hydrogen; N-ethyl-N,N-diisopropylamine In dichloromethane at 25℃; under 7500.75 Torr; for 16h; Inert atmosphere; Autoclave;
cyclobutanone
1191-95-3

cyclobutanone

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

Dimethyl glutarate
1119-40-0

Dimethyl glutarate

B

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

C

2-methylcyclobutanone
1517-15-3

2-methylcyclobutanone

D

methyl cyclobutane-2-one-1-carboxylate
52903-53-4

methyl cyclobutane-2-one-1-carboxylate

E

2-Cyclobutylidenecyclobutanone
10432-55-0

2-Cyclobutylidenecyclobutanone

Conditions
ConditionsYield
With magnesium oxide at 260℃; for 5h; Autoclave;
cyclobutanone
1191-95-3

cyclobutanone

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

Dimethyl glutarate
1119-40-0

Dimethyl glutarate

B

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

C

2-methylcyclobutanone
1517-15-3

2-methylcyclobutanone

D

2-Cyclobutylidenecyclobutanone
10432-55-0

2-Cyclobutylidenecyclobutanone

Conditions
ConditionsYield
With magnesium oxide at 260℃; for 5h; Autoclave;
cyclobutanone
1191-95-3

cyclobutanone

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

Dimethyl glutarate
1119-40-0

Dimethyl glutarate

B

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

C

methyl cyclobutane-2-one-1-carboxylate
52903-53-4

methyl cyclobutane-2-one-1-carboxylate

D

2-Cyclobutylidenecyclobutanone
10432-55-0

2-Cyclobutylidenecyclobutanone

Conditions
ConditionsYield
With magnesium oxide at 260℃; for 5h; Autoclave;
methanol
67-56-1

methanol

rac-homocitrato γ-lactone acid
91912-46-8

rac-homocitrato γ-lactone acid

A

hexanedioic acid dimethyl ester
627-93-0

hexanedioic acid dimethyl ester

B

1,2,4-butanetricarboxylic acid trimethyl ester
4339-27-9, 64591-19-1

1,2,4-butanetricarboxylic acid trimethyl ester

C

ethylbutanedioic acid dimethyl ester
14035-95-1

ethylbutanedioic acid dimethyl ester

D

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen In water at 150℃; under 10343.2 Torr; for 4h; Temperature; Reagent/catalyst;
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

A

hexanedioic acid dimethyl ester
627-93-0

hexanedioic acid dimethyl ester

B

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

Conditions
ConditionsYield
With platinum(II) bis(acetylacetonate); C28H36P2; toluene-4-sulfonic acid at 120℃; under 30402 Torr; for 20h; Sealed tube; Inert atmosphere; Autoclave; Overall yield = 98 percent;
methyl 1-{[(benzyloxy)carbonyl]amino}-2-methylpropylphosphinate
939403-19-7

methyl 1-{[(benzyloxy)carbonyl]amino}-2-methylpropylphosphinate

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

dimethyl 2-{[(1-{[(benzyloxy)carbonyl]amino}-2-methylpropyl)(methoxy)phosphoryl]methyl}pentanedioate
939403-21-1

dimethyl 2-{[(1-{[(benzyloxy)carbonyl]amino}-2-methylpropyl)(methoxy)phosphoryl]methyl}pentanedioate

Conditions
ConditionsYield
With sodium methylate In methanol at 20℃;39.2%
methyl 1-{[(benzyloxy)carbonyl]amino}-2-methylbutylphosphinate
939403-20-0

methyl 1-{[(benzyloxy)carbonyl]amino}-2-methylbutylphosphinate

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

dimethyl 2-{[(1-{[(benzyloxy)carbonyl]amino}-2-methylbutyl)(methoxy)phosphoryl]methyl}pentanedioate
939403-22-2

dimethyl 2-{[(1-{[(benzyloxy)carbonyl]amino}-2-methylbutyl)(methoxy)phosphoryl]methyl}pentanedioate

Conditions
ConditionsYield
With sodium methylate In methanol at 20℃;34.2%
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

2-methylglutaric acid
18069-17-5

2-methylglutaric acid

Conditions
ConditionsYield
(hydrolysis);
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

2-Methyl-1,5-bis(trimethylsiloxy)-1,5-dimethoxypenta-1,4-diene
86554-38-3

2-Methyl-1,5-bis(trimethylsiloxy)-1,5-dimethoxypenta-1,4-diene

Conditions
ConditionsYield
With lithium diisopropyl amide 1) THF, -78 deg C, 10 min, 2) -78 deg C - room temp.; Yield given. Multistep reaction;
With lithium diisopropyl amide 1.) THF, -78 deg C, 20 min, 2.) room temp, 2 h; Multistep reaction;
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

methyl 8-hydroxy-7-(methoxycarbonyl)-2-methyl-1-oxo-1,2,3,4-tetrahydro-3-naphthylacetate
107182-00-3

methyl 8-hydroxy-7-(methoxycarbonyl)-2-methyl-1-oxo-1,2,3,4-tetrahydro-3-naphthylacetate

Conditions
ConditionsYield
With n-butyllithium; calcium acetate; sodium hydride 1.) THF, hexane, 1 h, room temperature, 2.) MeOH, 2 h, reflux; Yield given. Multistep reaction;
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

(S)-(+)-dimethyl-2-methylglutarate
10171-92-3

(S)-(+)-dimethyl-2-methylglutarate

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

(R)-(-)-4-methylglutaric acid 1-monomethyl ester
80986-17-0

(R)-(-)-4-methylglutaric acid 1-monomethyl ester

Conditions
ConditionsYield
With sodium hydroxide; phosphate buffer at 30℃; esterase from Pseudomonas putida MR-2068;
With sodium hydroxide; esterase from Pseudomonas putida MR-2068 In various solvent(s) at 30℃; pH=7.0;
formaldehyd
50-00-0

formaldehyd

dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

dimethyl 2-methyl-4-methylenepentanedioate
34019-71-1

dimethyl 2-methyl-4-methylenepentanedioate

Conditions
ConditionsYield
With piperidine; pyridine Stetter reaction; Heating;
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

2-methyl-4-methylenepentanedioic acid
3290-56-0

2-methyl-4-methylenepentanedioic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: pyridine; piperidine / Heating
2: ethanolic KOH / 2 h / Heating
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

anti-dimethyl 2-ethyl-4-methylpentanedioate

anti-dimethyl 2-ethyl-4-methylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / 20 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

syn-dimethyl 2-ethyl-4-methylpentanedioate

syn-dimethyl 2-ethyl-4-methylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / 20 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

anti-dimethyl 2-methyl-4-propylpentanedioate

anti-dimethyl 2-methyl-4-propylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / -78 °C
View Scheme
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / benzene; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; AIBN / benzene; diethyl ether; hexane / 4 h / 70 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

syn-dimethyl 2-methyl-4-propylpentanedioate

syn-dimethyl 2-methyl-4-propylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / -78 °C
View Scheme
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / benzene; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; AIBN / benzene; diethyl ether; hexane / 4 h / 70 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

anti-dimethyl 2-methyl-4-neopentylpentanedioate

anti-dimethyl 2-methyl-4-neopentylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / benzene; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; AIBN / benzene; diethyl ether; hexane / 3 h / 70 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

syn-dimethyl 2-methyl-4-neopentylpentanedioate

syn-dimethyl 2-methyl-4-neopentylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / benzene; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; AIBN / benzene; diethyl ether; hexane / 3 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: 100 percent / n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / -78 °C
View Scheme
dimethyl 2-methylglutarate
14035-94-0

dimethyl 2-methylglutarate

anti-dimethyl 2-(cyclohexylmethyl)-4-methylpentanedioate

anti-dimethyl 2-(cyclohexylmethyl)-4-methylpentanedioate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / benzene; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; AIBN / benzene; diethyl ether; hexane / 4 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1.1: pyridine; piperidine / Heating
2.1: MgBr2*OEt2 / CH2Cl2; diethyl ether / 0.5 h / 20 °C
2.2: n-Bu3SnH; Et3B; O2 / CH2Cl2; diethyl ether; hexane / 4 h / -20 °C
View Scheme

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