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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE) CAS 146406-75-9

Cas:146406-75-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

HPLC 98% CAS 146406-75-9 with high quality products

Cas:146406-75-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2,2':6',2''-Terpyridine,4',4''''-(1,4-phenylene)bis-

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

1,4-Di([2,2":6",2""-terpyridin]-4"-yl)benzene

Cas:146406-75-9

Min.Order:1 Gram

FOB Price: $2254.0

Type:Trading Company

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,4-di([2,2':6',2''-terpyridin]-4'-yl)benzene

Cas:146406-75-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,2':6',2''-Terpyridine,4',4''''-(1,4-phenylene)bis-

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2,2':6',2''-Terpyridine,4',4''''-(1,4-phenylene)bis-

Cas:146406-75-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

1,4-Bis(2,2':6',2''-terpyridin-4'-yl)benzene

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4′,4′′′′-(1,4-Phenylene)bis(2,2′:6′,2′′-terpyridine) 5g

Cas:146406-75-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Manufacturers

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

best price high quality Storage:Room Temperature Application:For pharmacy chemicals Transportation:by sea.air

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

factory?direct?sale Application:healing drugs

2,2':6',2''-Terpyridine,4',4''''-(1,4-phenylene)bis-

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

"HANGZHOU TIANYE CHEMICALS Co.LTD , Located in Eastern Science and Innovation Park Hangzhou .We are a high-tech enterprise specialized in technical research and development, production, development and trade of chemical products. We supply Multiple s

4-[4-(2,6-dipyridin-2-ylpyridin-4-yl)phenyl]-2,6-dipyridin-2-ylpyridine

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:100mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any po

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

1,4-Di([2,2&#39:6&#39,2&#39&#39-terpyridin]-4&#39-yl)benzene

Cas:146406-75-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

ENAO Chemical Co, Limited

For quick quotation, please send us the inquiry include CAS#, Structure, Chemical Name, quantity, purity, as well as any additional specifications you require, we will try to get back to you within 24 hours. Our Services Besides manufacturing,

1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

146406-75-9

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai PotentPharm Science and Technology Co.,Ltd

1 good quality, better price and bettter service;2 Timely delivery;3 100% refunded if parcel is t delivered or poor quality.We will try to satisfy you upon receipt of your reply. I hope that we can become a long-term cooperative partner. Application:

2,2':6',2''-Terpyridine,4',4''''-(1,4-phenylene)bis-

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Run-Biotech Co., Ltd.

1.We have rich experience in the development and production 2.Our factory is in Shanghai of China,We have convenient traffic conditions.3.We have advanced testing equipment and shipping line. Package:5g, 10g, 50g, 100g, 1kg Application:Pharmaceutical

Sino-Biochemical Laboratory Co.,Ltd

High quality ,special structure, regular with stock , custom synthese ,quotation with 24hrsAppearance:light yellow Package:From Gram to KG to Mt Application:With high quality for lab research work esp. new drug discovery ! With stock or custom synth

1,4-di([2,2':6',2''-terpyridin]-4'-yl)benzene

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Sigma-Aldrich Chemie GmbH

Package:500 mg in glass bottle

4',4''''-(1,4-Phenylene)bis(2,2':6',2''-terpyridine)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HETCAT

more details? Please contact us

4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE)

Cas:146406-75-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-acetylpyridine
1122-62-9

2-acetylpyridine

terephthalaldehyde,
623-27-8

terephthalaldehyde,

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
With ammonium hydroxide; potassium tert-butylate In ethanol for 20h; Inert atmosphere;77%
With ammonium hydroxide; sodium hydroxide In ethanol; water at 25℃; for 10h;62%
With ammonium hydroxide; potassium hydroxide In water for 48h; Reflux;50%
With potassium hydroxide; ammonium hydroxide In methanol for 48h; Heating;39%
With ammonium hydroxide; potassium hydroxide In ethanol at 60℃; for 24h; Inert atmosphere;
1,4-bis<1,5-dioxo-1,5-bis(2-pyridyl)pentan-3-yl>benzene

1,4-bis<1,5-dioxo-1,5-bis(2-pyridyl)pentan-3-yl>benzene

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
With ammonium acetate In ethanol for 120h; Reflux;72%
With ammonium acetate In ethanol for 120h; Heating;39%
With ammonium hydroxide In various solvent(s) at 100℃; for 2h;
methyl (4-pyridyl) ketone
1122-54-9

methyl (4-pyridyl) ketone

terephthalaldehyde,
623-27-8

terephthalaldehyde,

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
Stage #1: methyl (4-pyridyl) ketone; terephthalaldehyde, With ammonia; sodium hydroxide In ethanol; water at 0℃; for 1h;
Stage #2: In ethanol; water at 80℃; for 24h;
55%
3-[4-(3-oxo-3-pyridin-2-yl-propenyl)-phenyl]-1-pyridin-2-yl-propenone
210306-18-6

3-[4-(3-oxo-3-pyridin-2-yl-propenyl)-phenyl]-1-pyridin-2-yl-propenone

2-acetylpyridine pyridinium hexafluorophosphate

2-acetylpyridine pyridinium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
With ammonium acetate
2-acetylpyridine
1122-62-9

2-acetylpyridine

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaOH / various solvent(s) / 2 h / 0 °C
2: aq. NH3 / various solvent(s) / 2 h / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 46 percent / 3percent aq. KOH / ethanol / 2 h
2: NH4(OAc)
View Scheme
Multi-step reaction with 2 steps
1: 64 percent / aq. NaOH / ethanol / 8 h / Ambient temperature
2: 39 percent / ammonium acetate / ethanol / 120 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: potassium hydroxide / methanol; water / 48 h / 20 °C
2: potassium hydroxide / ethanol; water / Reflux
3: ammonium acetate / ethanol / 120 h / Reflux
View Scheme
terephthalaldehyde,
623-27-8

terephthalaldehyde,

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaOH / various solvent(s) / 2 h / 0 °C
2: aq. NH3 / various solvent(s) / 2 h / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 46 percent / 3percent aq. KOH / ethanol / 2 h
2: NH4(OAc)
View Scheme
Multi-step reaction with 2 steps
1: 64 percent / aq. NaOH / ethanol / 8 h / Ambient temperature
2: 39 percent / ammonium acetate / ethanol / 120 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: potassium hydroxide / methanol; water / 48 h / 20 °C
2: potassium hydroxide / ethanol; water / Reflux
3: ammonium acetate / ethanol / 120 h / Reflux
View Scheme
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

bis(pentamethylcyclopentadienyl)ytterbium * Et2O

bis(pentamethylcyclopentadienyl)ytterbium * Et2O

[(C5Me5)2Yb](1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)[Yb(C5Me5)2]

[(C5Me5)2Yb](1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)[Yb(C5Me5)2]

Conditions
ConditionsYield
In toluene under Ar or He; room temp. toluene soln. of Yb complex (2 equiv.) added to solid ligand with stirring; solvent removed under vac.; elem. anal.;99%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate
241152-08-9

[(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate

[((η5-indenyl)Ru(PPh3))2(1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene)]PF6

[((η5-indenyl)Ru(PPh3))2(1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene)]PF6

Conditions
ConditionsYield
In benzene Ru complex was refluxed with ligand in benzene for 4 h; concd. (vac.); Et2O added; filtered; washed (methanol; Et2O);90%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate
529499-17-0

[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate

[((C5Me5)Ru(PPh3))2(1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene)]PF6

[((C5Me5)Ru(PPh3))2(1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene)]PF6

Conditions
ConditionsYield
In benzene Ru complex was refluxed with ligand in benzene for 4 h; concd. (vac.); Et2O added; filtered; washed (methanol; Et2O);90%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Ru(C15H11N3)((C15H10N3)2C6H4RuCl3)(2+)*2PF6(1-)*5H2O=[Ru(C15H11N3)((C15H10N3)2C6H4)RuCl3](PF6)2*5H2O

Ru(C15H11N3)((C15H10N3)2C6H4RuCl3)(2+)*2PF6(1-)*5H2O=[Ru(C15H11N3)((C15H10N3)2C6H4)RuCl3](PF6)2*5H2O

{Ru(C5H3N(C5H4N)2)}2{C5H2N(C5H4N)2}2C6H4(4+)*4PF6(1-)={{Ru(C5H3N(C5H4N)2)}2{C5H2N(C5H4N)2}2C6H4}{PF6}4

{Ru(C5H3N(C5H4N)2)}2{C5H2N(C5H4N)2}2C6H4(4+)*4PF6(1-)={{Ru(C5H3N(C5H4N)2)}2{C5H2N(C5H4N)2}2C6H4}{PF6}4

Conditions
ConditionsYield
In methanol Ar-atmosphere; refluxing Ru-complex with slight excess of ligand for 18 h, cooling, filtration (celite), treatment with excess NH4PF6 (pptn.); filtration, drying; elem. anal.;82%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

copper(ll) sulfate pentahydrate

copper(ll) sulfate pentahydrate

water
7732-18-5

water

[Zn2(1,4-bis(2,2':6',2''-terpyridine-4-yl)benzene)(SO4)2]*2H2O

[Zn2(1,4-bis(2,2':6',2''-terpyridine-4-yl)benzene)(SO4)2]*2H2O

Conditions
ConditionsYield
In water High Pressure; under hydrothermal conditions, in Parr acid digestion bomb; mixt. of Cu salt, ligand and H2O (molar ratio 1.7:1:340) heated at 200°C for 98 h; crystals isolated;80%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[(CoCl2)2(μ-(1,4-bis[(2,2′:6',2"-terpyridyl)-4'-yl]benzene))]*4(dimethylformamide)

[(CoCl2)2(μ-(1,4-bis[(2,2′:6',2"-terpyridyl)-4'-yl]benzene))]*4(dimethylformamide)

Conditions
ConditionsYield
at 160℃; for 72h; Autoclave;80%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

bromopentacarbonylmanganese(I)
14516-54-2

bromopentacarbonylmanganese(I)

C42H24Br2Mn2N6O6

C42H24Br2Mn2N6O6

Conditions
ConditionsYield
In acetone for 15h; Inert atmosphere; Reflux;78%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]
136276-24-9

[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]

(4'-p-tolyl-2,2':6',2''-terpyridin)(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

(4'-p-tolyl-2,2':6',2''-terpyridin)(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

Conditions
ConditionsYield
With AgBF4 In N,N-dimethyl-formamide; acetone; acetonitrile byproducts: AgCl; mixt. Ru-complex and AgBF4 refluxed in acetone (2h, in air), mixt. filtered (removal of AgCl), addn. DMF, evapn. acetone, soln. slowly added tohot soln. (80°C) of the terpyridine/DMF, mixt. refluxed (1 h, under Ar), evapn., addn. KPF6 and CH3CN; addn. water (pptn.), evapn. of CH3CN, ppt. washed (1. water (twice), 2.ethr (twice)), column chromy. (silica gel, acetonitrile);77%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

C36H24N6*2Ag(1+)*2CF3O3S(1-)

C36H24N6*2Ag(1+)*2CF3O3S(1-)

Conditions
ConditionsYield
In methanol at 20℃; for 16h; Inert atmosphere; Darkness;76%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[Pt(C6F4CF3)2(S(C2H5)2)2]
198560-46-2

[Pt(C6F4CF3)2(S(C2H5)2)2]

[(Pt(C6F4CF3)2)2C36H24N6]
217639-52-6

[(Pt(C6F4CF3)2)2C36H24N6]

Conditions
ConditionsYield
In not given (N2); elem. anal.;73%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

manganese(II) chloride tetrahydrate

manganese(II) chloride tetrahydrate

C36H28Cl4Mn2N6O2*2H2O

C36H28Cl4Mn2N6O2*2H2O

Conditions
ConditionsYield
In water at 119.84℃; for 24h; Autoclave;73%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]
136276-24-9

[trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)]

(4'-p-tolyl-2,2':6',2''-terpyridin)(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

(4'-p-tolyl-2,2':6',2''-terpyridin)(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

Conditions
ConditionsYield
With silver tetrafluoroborate In N,N-dimethyl-formamide byproducts: AgCl; Ru and Ag compds. refluxed in acetone for 3 h, filtered, concd. (vac.), DMF added, acetone removed, soln. added to a soln. of ligand (1.5 equiv)at 80°C, refluxed (Ar, 2 h), cooled, added to a soln. of NH4PF6 (H2O); ppt. filtered, washed (H2O, diethyl ether), solvent removed (vac.), chromy. (alumina, CH3CN/KNO3/H2O/N(C2H5)3), repptd. (NH4PF6); elem. anal.;70%
With silver tetrafluoroborate In N,N-dimethyl-formamide; acetone Ru-complex was reacted with AgBF4 in acetone, refluxed for 3 h, ligand in DMF was added, refluxed for 2 h under Ar, aq. NH4PF6 was added; column chromy. on alumina with MeCN/satd. KNO3/H2O;70%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

zinc(II) nitrate hexahydrate

zinc(II) nitrate hexahydrate

water
7732-18-5

water

μ-1,4-bis(2,2’:6’,2’’-terpyridin-4’-yl)benzene-κ3N1,N2,N6:κ3N3,N4,N5-bis[(diformato-κO)-zinc(II)] dihydrate

μ-1,4-bis(2,2’:6’,2’’-terpyridin-4’-yl)benzene-κ3N1,N2,N6:κ3N3,N4,N5-bis[(diformato-κO)-zinc(II)] dihydrate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 160℃; for 72h; Autoclave;66.3%
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

(C5(CH3)5RhCl)2((C5H4N)2C5H2N(C6H4)C5H2N(C5H4N)2)(2+)*2BF4(1-)=[(C5(CH3)5RhCl)2((C5H4N)2C5H2N(C6H4)C5H2N(C5H4N)2)](BF4)2

(C5(CH3)5RhCl)2((C5H4N)2C5H2N(C6H4)C5H2N(C5H4N)2)(2+)*2BF4(1-)=[(C5(CH3)5RhCl)2((C5H4N)2C5H2N(C6H4)C5H2N(C5H4N)2)](BF4)2

Conditions
ConditionsYield
In methanol stirring (4 h); evapn., dichloromethane addn.; elem. anal.;60%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)RuCl3
879495-64-4

(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)RuCl3

[(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)Ru(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)Ru(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)](PF6)4*KPF6

[(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)Ru(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)Ru(2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine)](PF6)4*KPF6

Conditions
ConditionsYield
In N,N-dimethyl-formamide suspn. Ru complex and ligand in DMF was refluxed for 1 h, react. mixt. was cooled, KPF6 was added; ppt. was filtered, soln. was evapd., dissolved in MeCN and treated with aq. KPF6, ppt. was filtered, dissolved in MeCN and chromd. on silica (MeCN-aq.KNO3 9:1), aq. KPF6 was added, ppt. was dissolved in MeCN and pptd. with water; elem. anal.;50%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

zinc(II) nitrate hexahydrate

zinc(II) nitrate hexahydrate

water
7732-18-5

water

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

di-μ-oxido-bis{μ-1,4-bis(2,2’:6’,2’’-terpyridin-4’-yl)benzene κ3N1,N2,N6:κ3N3,N4,N5-bis[(formato-κO)-zinc(II)]} monodimethylformamide hexahydrate

di-μ-oxido-bis{μ-1,4-bis(2,2’:6’,2’’-terpyridin-4’-yl)benzene κ3N1,N2,N6:κ3N3,N4,N5-bis[(formato-κO)-zinc(II)]} monodimethylformamide hexahydrate

Conditions
ConditionsYield
at 160℃; for 72h; Autoclave;43.9%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

ruthenium(III) chloride trihydrate

ruthenium(III) chloride trihydrate

bis(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

bis(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)ruthenium(II) hexafluorophosphate

Conditions
ConditionsYield
In N,N-dimethyl-formamide a soln. of ligand (slight excess) added to a soln. of Ru compd., refluxed under Ar for 24 h, cooled, added to a soln. of NH4PF6 (H2O); chromy. (alumina, CH3CN/satd.KNO3/H2O/N(C2H5)3); elem. anal.;40%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

(trimethylplatinum(IV) iodide)4

(trimethylplatinum(IV) iodide)4

[(PtI(CH3)3)2C36H24N6]
217639-55-9

[(PtI(CH3)3)2C36H24N6]

Conditions
ConditionsYield
In not given (N2); elem. anal.;36%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

rhenium(I) pentacarbonyl bromide
14220-21-4

rhenium(I) pentacarbonyl bromide

[(ReBr(CO)3)2C36H24N6]
217639-53-7

[(ReBr(CO)3)2C36H24N6]

Conditions
ConditionsYield
In not given (N2); elem. anal.;35%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

(Ru(C15H10N3)2)2(C6H4)2((C15H11N3)RuCl3)(4+)*4PF6(1-)*9H2O=[(Ru(C15H10N3)2)2(C6H4)2((C15H11N3)RuCl3)](PF6)4*9H2O

(Ru(C15H10N3)2)2(C6H4)2((C15H11N3)RuCl3)(4+)*4PF6(1-)*9H2O=[(Ru(C15H10N3)2)2(C6H4)2((C15H11N3)RuCl3)](PF6)4*9H2O

(Ru(C15H10N3)2C6H4)3(C15H11N3)(6+)*6PF6(1-)=[(Ru(C15H10N3)2C6H4)3(C15H11N3)](PF6)6

(Ru(C15H10N3)2C6H4)3(C15H11N3)(6+)*6PF6(1-)=[(Ru(C15H10N3)2C6H4)3(C15H11N3)](PF6)6

Conditions
ConditionsYield
In methanol Ar-atmosphere; refluxing Ru-complex with slight excess of ligand for 18 h, cooling, filtration (celite), treatment with excess NH4PF6 (pptn.); filtration, drying; elem. anal.;33%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride
124643-10-3

[4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride

A

[(4,4''''-(1,4-phenylene)bis(2,2':6',2''-terpyridine))Os(4'-tolyl-2,2':6',2''-terpyridine)][PF6]2

[(4,4''''-(1,4-phenylene)bis(2,2':6',2''-terpyridine))Os(4'-tolyl-2,2':6',2''-terpyridine)][PF6]2

B

[(4'-tolyl-2,2':6',2''-terpyridine)Os(4,4''''-(1,4-phenylene)bis(2,2':6',2''-terpyridine))Os(4'-tolyl-2,2':6',2''-terpyridine)][PF6]4

[(4'-tolyl-2,2':6',2''-terpyridine)Os(4,4''''-(1,4-phenylene)bis(2,2':6',2''-terpyridine))Os(4'-tolyl-2,2':6',2''-terpyridine)][PF6]4

Conditions
ConditionsYield
In ethylene glycol under N2; a soln. of a ligand (0.81 mmol) and Os-contg. compd. (0.403 mmol) in ethylene glycol was stirred at reflux for 1 h; the mixt. was cooled to room temp.; excess aq. NH4PF6 was added; the ppt. was filtered off, washed with H2O and diethyl ether, and re-dissolved in CH3CN; the filtrate was evapd. and the residue was dried in vac.; column chromy. on silica with CH3CN-aq. KNO3;A 30%
B 22%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)RuCl3
586400-18-2

(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)RuCl3

[(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)Ru(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)Ru(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)](PF6)4*2KPF6

[(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)Ru(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)Ru(4'-(p-bromophenyl)-2,2':6',2''-terpyridine)](PF6)4*2KPF6

Conditions
ConditionsYield
In N,N-dimethyl-formamide suspn. Ru complex and ligand in DMF was refluxed for 15 min, react. mixt. was cooled, KPF6 was added; ppt. was filtered, soln. was evapd., dissolved in MeCN and treated with aq. KPF6, ppt. was filtered, dissolved in MeCN and chromd. on silica (MeCN-aq.KNO3 9:1), aq. KPF6 was added, ppt. was dissolved in MeCN and pptd. with water; elem. anal.;30%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4)
82582-67-0, 72414-17-6

[Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4)

chloroform
67-66-3

chloroform

[Ir2(hydrido)4(triphenylphosphine)4(1,4-bis(2,2':6',2''-terpyridine-4'-yl)benzene)](BF4)2*6CHCl3

[Ir2(hydrido)4(triphenylphosphine)4(1,4-bis(2,2':6',2''-terpyridine-4'-yl)benzene)](BF4)2*6CHCl3

Conditions
ConditionsYield
In chloroform (Ar); using Schlenk techniques; mixing of (IrH2(PPh3)2(acetone)2)(BF4) (1 equiv.) and 1,4-bis(2,2':6',2''-terpyridine-4'-yl)benzene (1 equiv.) in CHCl3 overnight; filtration, placing of filtrate in glass tubes and layering with hexane;sealing of tubes, standing at room temp. for 3 days; elem. anal.;28%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

[Pt(C6F4CF3)2(S(C2H5)2)2]
198560-46-2

[Pt(C6F4CF3)2(S(C2H5)2)2]

[Pt(C6F4CF3)2C36H24N6]
217639-51-5

[Pt(C6F4CF3)2C36H24N6]

Conditions
ConditionsYield
In not given (N2); elem. anal.;28%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

bis(μ-chloro)-bis[1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C(2'),N-iridium chloride]

bis(μ-chloro)-bis[1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C(2'),N-iridium chloride]

[(1,3-dipyridyl-4,6-dimethylbenzene(1-))Ir(tpy-ph-tpy)Ir(1,3-dipyridyl-4,6-dimethylbenzene(1-))](PF6)4

[(1,3-dipyridyl-4,6-dimethylbenzene(1-))Ir(tpy-ph-tpy)Ir(1,3-dipyridyl-4,6-dimethylbenzene(1-))](PF6)4

Conditions
ConditionsYield
In water; ethylene glycol (under Ar); suspn. of Ir-complex and ligand in ethylene glycol refluxed for 45 min, cooled to room temp., H2O added, aq. soln. of KPF6 added; ppt. collected, washed with H2O, dissolved in MeCN, solvent removed, purified on silica gel chromy. with MeCN/H2O/KNO3 100/3/0.3-100/20/2;26%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

RuCl3(C5H2N(SO2CH3)(C5H4N)2)
146082-25-9

RuCl3(C5H2N(SO2CH3)(C5H4N)2)

[C5H4NC5H2(O2SCH3)NC5H4N]Ru[(C5H4NC5H2NC5H4N)2C6H4](2+)*2PF6(1-)=[(C15H10(O2SCH3)N3)Ru((C15H10N3)2C6H4)](PF6)2

[C5H4NC5H2(O2SCH3)NC5H4N]Ru[(C5H4NC5H2NC5H4N)2C6H4](2+)*2PF6(1-)=[(C15H10(O2SCH3)N3)Ru((C15H10N3)2C6H4)](PF6)2

Conditions
ConditionsYield
In methanol; water; ethylene glycol suspn. of the terpyridine and Ru-complex in 1,2-ethanediol refluxed (45min), red soln. allowed to cool, addn. H2O and excess NH4PF6/MeOH (pptn.); ppt. redissolved in min. amt. CH3CN, column chromy. (silica; CH3CN, satd. aq. KNO3, H2O (7:1:0.5 v/v)), main orange fraction collected, addn. H2O and excess NH4PF6/MeOH, partial evapn. (vac.), pptn., recrystn. (acetone/MeOH (1:1));22%
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene
146406-75-9

1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

1,4-butylenediphosphonic acid
4671-77-6

1,4-butylenediphosphonic acid

hydrogen fluoride
7664-39-3

hydrogen fluoride

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

molybdenum(VI) oxide

molybdenum(VI) oxide

A

[Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*4H2O

[Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*4H2O

B

[Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*6H2O

[Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*6H2O

Conditions
ConditionsYield
In hydrogen fluoride aq. HF; High Pressure; mixt. Cu acetate, MoO3, benzene-bis(terpyridine), butylenediphosphonic acid, H2O, and HF (molar ratio=2.11:5.63:1.00:2.48:6010.8:248.43) heatedat 180°C for 2 d;A 20%
B n/a

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