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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 239-35-0 Naphtho[1,2-b][1]benzothiophene Manufacturer

Cas:239-35-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

BENZO(B)NAPHTHO(2,1-D)THIOPHENE CAS:239-35-0

Cas:239-35-0

Min.Order:1 Kilogram

FOB Price: $8.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 239-35-0 with best price

Cas:239-35-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

BENZO(B)NAPHTHO(2,1-D)THIOPHENE CAS:239-35-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

BENZO(B)NAPHTHO(2,1-D)THIOPHENE CAS:239-35-0

Cas:239-35-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

naphtho[1,2-b][1]benzothiole

Cas:239-35-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

239-35-0 BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Benzo(B)Naphtho(2,1-D)Thiophene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Benzo[b]naphtho[2,1-d]thiopheneAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Benzo[b]naphtho[2,1-d]thiophene cas 239-35-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Benzo[b]naphtho[2,1-d]thiophene cas 239-35-0

Cas:239-35-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Benzo[b]naphtho[2,1-d]thiophene CAS NO.239-35-0

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Quality: 1. Testing before each delivery, including Nuclear Magnetic Resonance(NMR), Gas Chromatography(GC)/High Performance Liquid Chromatography(HPLC), Mass detection(MS), Optical rotation for chiral products. There are many other methods avail

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the BENZO(B)NAPHTHO(2,1-D)THIOPHENE, CAS:239-35-0 with the most competitive price and the

BENZO(B)NAPHTHO(2,1-D)THIOPHENE

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

239-35-0

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

1,2-Benzodiphenylenesulphide

Cas:239-35-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

11-thiabenzo[a]fluorene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Co.Ltd

Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en

Benzo[b]naphtho[2,1-d]thiophene

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

1,2-benzodiphenylene sulfide is a rare constituent of coal tar. Photodeoxygenation of 1,2-benzodiphenylene sulfoxide, generates an intermediate capable of oxidizing the solvent benzene to phenol. Liquid-phase photolysis of 1,2-benzodiphenylene sulfid

1,2-Benzodiphenylene sulfide

Cas:239-35-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-[2-(1-chloro-vinyl)-phenyl]-benzo[b]thiophene

2-[2-(1-chloro-vinyl)-phenyl]-benzo[b]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
at 800℃; under 0.1 Torr; Cyclization; Pyrolysis;92%
1-Naphthalenethiol
529-36-2

1-Naphthalenethiol

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); cesium pivalate; bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl acetamide at 140℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;92%
cis,trans-2,5-dimethoxytetrahydrofuran
696-59-3

cis,trans-2,5-dimethoxytetrahydrofuran

naphtho[1,2-b]thiophene
234-41-3

naphtho[1,2-b]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;90%
2-(2-ethynylphenyl)benzo[b]thiophene

2-(2-ethynylphenyl)benzo[b]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With silver(I) hexafluorophosphate; [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] In chlorobenzene at -78 - 120℃; for 20h; Inert atmosphere;90%
C16H10S

C16H10S

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With platinum(II) chloride In toluene at 100℃; for 12h; Inert atmosphere;85%
C16H12OS

C16H12OS

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With 5,10,15,20-tetraphenylporphyrinatochromium(III) hexafluoroantimonate In 1,2-dichloro-ethane at 100℃; for 2h; Inert atmosphere; Sealed tube;78%
3-styrylbenzothiophene
4565-13-3

3-styrylbenzothiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With iodine In cyclohexane for 4h; Irradiation;72%
benzo[b]naphtho[2,1-d]iodol-11-ium trifluoromethanesulfonate
1469876-15-0

benzo[b]naphtho[2,1-d]iodol-11-ium trifluoromethanesulfonate

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With triethylammonium N-benzyldithiocarbamate; copper(II) sulfate In acetonitrile at 60℃; for 5h; Sealed tube; Inert atmosphere;71%
3-(2-(2-bromophenyl)-2-(phenylsulfonyl)ethyl)benzo[b]thiophene

3-(2-(2-bromophenyl)-2-(phenylsulfonyl)ethyl)benzo[b]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 80℃; for 2h; Inert atmosphere;65%
1-naphthyl phenyl sulfide
7570-98-1

1-naphthyl phenyl sulfide

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver(I) acetate; Trimethylacetic acid at 130℃; for 24h; Schlenk technique;60%
With palladium(II) trifluoroacetate; silver(I) acetate; potassium carbonate at 130℃; for 24h; Schlenk technique;56%
With n-butyllithium; potassium tert-butylate In tetrahydrofuran; diethyl ether; hexane at 20℃;36%
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; potassium tert-butylate In tetrahydrofuran; diethyl ether at 25℃; for 0.0166667h; Inert atmosphere;32%
Benzo[b]thiophene
95-15-8

Benzo[b]thiophene

A

benzothiophene-1,1-dioxide
825-44-5

benzothiophene-1,1-dioxide

B

benzo[b]naphtho[2,1-d]thiophene 11-oxide
121823-04-9

benzo[b]naphtho[2,1-d]thiophene 11-oxide

C

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

rac-(6aS,11S,11aR)-6a,11a-dihydrobenzo[b]naphtho[2,1-d]thiophene 11-oxide

rac-(6aS,11S,11aR)-6a,11a-dihydrobenzo[b]naphtho[2,1-d]thiophene 11-oxide

rac-(6aS,11R,11aR)-6a,11a-dihydrobenzo[b]naphtho[2,1-d]thiophene 11-oxide

rac-(6aS,11R,11aR)-6a,11a-dihydrobenzo[b]naphtho[2,1-d]thiophene 11-oxide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃;A 60%
B 0.026 g
C 0.018 g
D 0.045 g
E 0.015 g
C22H16S
1146542-57-5

C22H16S

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In CH3Cl at 65℃;42%
2-ethynyl-thiophene
4298-52-6

2-ethynyl-thiophene

2-(benzo[b]thiophen-2-yl)benzenamine
38210-45-6

2-(benzo[b]thiophen-2-yl)benzenamine

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

6-(thiophen-2-yl)benzo[b]naphtho[2,1-d]thiophene

6-(thiophen-2-yl)benzo[b]naphtho[2,1-d]thiophene

Conditions
ConditionsYield
With tris[2-phenylpyridinato-C2,N]iridium(III); tert.-butylnitrite In acetonitrile at 20℃; for 15h; Irradiation;A n/a
B 40%
1-Iodonaphthalene
90-14-2

1-Iodonaphthalene

2-bromothiophenol
6320-02-1

2-bromothiophenol

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); cesium pivalate; bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl acetamide at 140℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;30%
2-(2-ethynylphenyl)benzo[b]thiophene

2-(2-ethynylphenyl)benzo[b]thiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

aceanthrylene
202-03-9

aceanthrylene

Conditions
ConditionsYield
at 800℃; under 0.1 Torr; Cyclization; rearrangement; Pyrolysis;A 9%
B 24%
2-(cyclohex-1-en-1-yl)naphthalene
54607-03-3

2-(cyclohex-1-en-1-yl)naphthalene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

2-phenylnaphthalene
612-94-2

2-phenylnaphthalene

Conditions
ConditionsYield
With hydrogen sulfide at 550℃; for 4.5h; Mechanism; Product distribution; object of study: sulfur bridging reaction;A 9.2%
B 2.8%
C 8%
3-(2-methylbenzoyl)benzothiophene
22720-67-8

3-(2-methylbenzoyl)benzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

<1>benzothieno<2,3-b>-1,4-naphthoquinone
21503-35-5

<1>benzothieno<2,3-b>-1,4-naphthoquinone

Conditions
ConditionsYield
at 350℃;
1-chloro-benzo[b]naphtho[2,1-d]thiophene

1-chloro-benzo[b]naphtho[2,1-d]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With pyridine; copper(I) oxide; acetic anhydride at 200℃;
7,8,9,10-tetrahydrobenzonaphtho<2,1-d>thiophene
16587-63-6

7,8,9,10-tetrahydrobenzonaphtho<2,1-d>thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With selenium at 300℃;
With selenium
1-chloro-7,8,9,10-tetrahydro-benzo[b]naphtho[2,1-d]thiophene
573722-57-3

1-chloro-7,8,9,10-tetrahydro-benzo[b]naphtho[2,1-d]thiophene

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With selenium at 300℃;
benzo[b]naphtho[2,1-d]thiophene-1,4-quinone
125847-44-1

benzo[b]naphtho[2,1-d]thiophene-1,4-quinone

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With tetrahydrofuran; lithium aluminium tetrahydride
2-methyl-3-benzoylbenzothiophene
65628-46-8

2-methyl-3-benzoylbenzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

<1>benzothieno<2,3-b>-1,4-naphthoquinone
21503-35-5

<1>benzothieno<2,3-b>-1,4-naphthoquinone

D

3-benzyl-2-methylbenzothiophene

3-benzyl-2-methylbenzothiophene

Conditions
ConditionsYield
at 360℃; for 2.5h; Yield given. Further byproducts given. Title compound not separated from byproducts;A 2 % Turnov.
B 4 % Turnov.
C n/a
D 40 % Turnov.
2-methyl-3-benzoylbenzothiophene
65628-46-8

2-methyl-3-benzoylbenzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

<1>benzothieno<2,3-b>-1,4-naphthoquinone
21503-35-5

<1>benzothieno<2,3-b>-1,4-naphthoquinone

D

3-benzyl-2-methylbenzothiophene

3-benzyl-2-methylbenzothiophene

E

11-hydroxybenzonaphtho<2,3-d>thiophene
91704-83-5

11-hydroxybenzonaphtho<2,3-d>thiophene

Conditions
ConditionsYield
at 420℃; for 0.5h; Product distribution; other temperatures; other time;A 4 % Turnov.
B 6 % Turnov.
C n/a
D 12.5 % Turnov.
E n/a
2-methyl-3-benzoylbenzothiophene
65628-46-8

2-methyl-3-benzoylbenzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

3-benzyl-2-methylbenzothiophene

3-benzyl-2-methylbenzothiophene

D

11-hydroxybenzonaphtho<2,3-d>thiophene
91704-83-5

11-hydroxybenzonaphtho<2,3-d>thiophene

Conditions
ConditionsYield
at 360℃; for 2.5h; Further byproducts given. Title compound not separated from byproducts;A 2 % Turnov.
B 4 % Turnov.
C 40 % Turnov.
D n/a
at 360℃; for 2.5h; Yield given. Further byproducts given;A 2 % Turnov.
B 4 % Turnov.
C 40 % Turnov.
D n/a
3-(2-methylbenzoyl)benzothiophene
22720-67-8

3-(2-methylbenzoyl)benzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

<1>benzothieno<2,3-b>-1,4-naphthoquinone
21503-35-5

<1>benzothieno<2,3-b>-1,4-naphthoquinone

C

11-hydroxybenzonaphtho<2,3-d>thiophene
91704-83-5

11-hydroxybenzonaphtho<2,3-d>thiophene

D

3-(2-methylbenzyl)benzothiophene
74881-99-5

3-(2-methylbenzyl)benzothiophene

Conditions
ConditionsYield
at 420℃; for 0.5h;A 64.5 % Turnov.
B n/a
C n/a
D 11 % Turnov.
at 420℃; for 0.5h; Product distribution; other temperatures; other time;A 64.5 % Turnov.
B n/a
C n/a
D 11 % Turnov.
at 360℃; for 2.5h; Yield given;A 36 % Turnov.
B n/a
C n/a
D 3 % Turnov.
at 420℃; for 0.5h; Title compound not separated from byproducts;A 64.5 % Turnov.
B n/a
C n/a
D 11 % Turnov.
2-(2-methylbenzoyl)benzothiophene
74882-00-1

2-(2-methylbenzoyl)benzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

<1>benzothieno<2,3-b>-1,4-naphthoquinone
21503-35-5

<1>benzothieno<2,3-b>-1,4-naphthoquinone

D

6-hydroxybenzonaphtho<2,3-d>thiophene
91704-82-4

6-hydroxybenzonaphtho<2,3-d>thiophene

E

2-(2-methylbenzyl)benzothiophene
83656-83-1

2-(2-methylbenzyl)benzothiophene

Conditions
ConditionsYield
at 420℃; for 0.5h; Product distribution; other temperatures; other time;A 2.5 % Turnov.
B 30 % Turnov.
C n/a
D n/a
E 0.5 % Turnov.
2-(2-methylbenzoyl)benzothiophene
74882-00-1

2-(2-methylbenzoyl)benzothiophene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

benzo[b]naphtho[2,3-d]thiophene
243-46-9

benzo[b]naphtho[2,3-d]thiophene

C

6-hydroxybenzonaphtho<2,3-d>thiophene
91704-82-4

6-hydroxybenzonaphtho<2,3-d>thiophene

D

2-(2-methylbenzyl)benzothiophene
83656-83-1

2-(2-methylbenzyl)benzothiophene

Conditions
ConditionsYield
at 420℃; for 0.5h; Further byproducts given;A 2.5 % Turnov.
B 30 % Turnov.
C n/a
D 0.5 % Turnov.
at 360℃; for 2.5h; Title compound not separated from byproducts;A 3.3 % Turnov.
B 2.2 % Turnov.
C n/a
D 19.5 % Turnov.
benzo[b]naphtho[2,1-d]thiophene 11-oxide
121823-04-9

benzo[b]naphtho[2,1-d]thiophene 11-oxide

benzene
71-43-2

benzene

A

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
In acetonitrile at 20℃; Irradiation; Title compound not separated from byproducts.;
bituminous housecoal

bituminous housecoal

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

Conditions
ConditionsYield
With air Formation of xenobiotics; Heating;
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

5-nitrobenzonaphtho<2,1-d>thiophene
76113-31-0

5-nitrobenzonaphtho<2,1-d>thiophene

Conditions
ConditionsYield
With nitric acid; acetic acid for 0.166667h; Heating;90%
With nitric acid; acetic acid for 2h; Ambient temperature;90%
With nitric acid In dichloromethane; water at 0℃; for 0.5h;76%
With sulfuric acid; nitric acid In acetic acid at 0℃; for 0.0833333h;67%
With nitric acid; acetic acid
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

5-bromobenzonaphtho<2,1-d>thiophene
76113-28-5

5-bromobenzonaphtho<2,1-d>thiophene

Conditions
ConditionsYield
With bromine In chloroform for 3h; Ambient temperature;81%
Multi-step reaction with 3 steps
1: 90 percent / nitric acid, glacial acetic acid / 2 h / Ambient temperature
2: 80 percent / SnCl2*2H2O, HCl / various solvent(s) / 1 h / Heating
3: 1.) HCl, NaNO2, 2.) CuBr, 40percent HBr / 1.) H2O, 0 deg C, 2.) H2O, 80 deg C, 1 h
View Scheme
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

acetyl chloride
75-36-5

acetyl chloride

5-acetylbenzonaphtho<2,1-d>thiophene
76113-35-4

5-acetylbenzonaphtho<2,1-d>thiophene

Conditions
ConditionsYield
With tin(IV) chloride In benzene for 2h; Heating;80%
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

benzonaphtho<2,1-d>thiophene-5-sulfonic acid
76113-17-2

benzonaphtho<2,1-d>thiophene-5-sulfonic acid

Conditions
ConditionsYield
With chlorosulfonic acid In chloroform for 0.5h; Ambient temperature;80%
With chlorosulfonic acid In dichloromethane at 22℃; for 2h;3%
With chlorosulfonic acid In chloroform
[Rh(H)(Ph)(η5-pentamethylcyclopentadienyl)(PMe3)]
81971-46-2

[Rh(H)(Ph)(η5-pentamethylcyclopentadienyl)(PMe3)]

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

((CH3)5C5)Rh(P(CH3)3)(C16H10S)
177586-20-8

((CH3)5C5)Rh(P(CH3)3)(C16H10S)

Conditions
ConditionsYield
In Cyclohexane-d12 N2-atmosphere, sealed NMR tube; 68°C (70 h); evapn.; elem. anal.;75%
formaldehyd
50-00-0

formaldehyd

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

5-chloromethylbenzonaphtho<2,1-d>thiophene
76113-34-3

5-chloromethylbenzonaphtho<2,1-d>thiophene

Conditions
ConditionsYield
With hydrogenchloride; acetic acid; zinc(II) chloride at 60℃; for 10h;74%
1-chloro 4-iodobutane
10297-05-9

1-chloro 4-iodobutane

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

C20H18ClS(1+)*BF4(1-)

C20H18ClS(1+)*BF4(1-)

Conditions
ConditionsYield
With silver tetrafluoroborate In 1,2-dichloro-ethane at 25℃; Inert atmosphere;72%
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

acetic anhydride
108-24-7

acetic anhydride

5-acetylbenzonaphtho<2,1-d>thiophene
76113-35-4

5-acetylbenzonaphtho<2,1-d>thiophene

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide 1.) 10 deg C, 1 h, 2.) 45 deg C, 3 h;69%
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

2-phenylnaphthalene
612-94-2

2-phenylnaphthalene

Conditions
ConditionsYield
sulfided catalyst CMA-2 In methanol; benzene at 450℃; Product distribution;69%
nickel In ethanol at 78.3℃; for 1h; Rate constant;
4-chlorobutyl bromide
6940-78-9

4-chlorobutyl bromide

11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

C20H18ClS(1+)*BF4(1-)

C20H18ClS(1+)*BF4(1-)

Conditions
ConditionsYield
With silver tetrafluoroborate In 1,2-dichloro-ethane at 25℃; Inert atmosphere;52%
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

benzo[b]naphtho[2,1-d]thiophene 11,11-dioxide
20841-60-5

benzo[b]naphtho[2,1-d]thiophene 11,11-dioxide

Conditions
ConditionsYield
With dihydrogen peroxide; acetic acid for 12h; Reflux;48%
With dihydrogen peroxide; acetic acid
With dihydrogen peroxide In acetic acid for 1h; Heating;
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

A

benzo[b]naphtho[2,1-d]thiophene-5,8-disulfonic acid

benzo[b]naphtho[2,1-d]thiophene-5,8-disulfonic acid

B

benzo[b]naphtho[2,1-d]thiophene-5,9-disulfonic acid

benzo[b]naphtho[2,1-d]thiophene-5,9-disulfonic acid

Conditions
ConditionsYield
With chlorosulfonic acid In dichloromethane at 0 - 22℃; Temperature;A 46%
B 40%
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

A

2-phenylnaphthalene
612-94-2

2-phenylnaphthalene

B

methylphenylnaphthalene

methylphenylnaphthalene

Conditions
ConditionsYield
sulfided catalyst CMA-2 In methanol; benzene at 350℃; Product distribution;A 42%
B n/a
11-thiabenzo[a]fluorene
239-35-0

11-thiabenzo[a]fluorene

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

C16H10SCr(CO)3

C16H10SCr(CO)3

Conditions
ConditionsYield
boiling;;15%
boiling;;15%

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