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Qingdao Beluga Import and Export Co., LTD

PETASIN CAS:26577-85-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, s

PETASIN CAS:26577-85-5

Cas:26577-85-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

PETASIN

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

PETASIN

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruican Trade Co., Ltd.

Natural plant butterbur extract powder 10% petasin petasites hybridus 1.Petasin is responsible for the antispasmodic properties of the plant by reducing ; 2.Spasms in smooth muscle and vascular walls, in additi

Natural plant butterbur extract powder 10% petasin petasites hybridus

Cas:26577-85-5

Min.Order:1 Kilogram

FOB Price: $10.0 / 30.0

Type:Trading Company

inquiry

Chengdu Push Bio-technology Co., Ltd

Chengdu Push Bio-technology Co., Ltd. provides more than 4,000 natural monomeric substances, including approximately 6,000 products at different grades, specifications and purities. We have specialized in the R&D of medicinally active ingredients sta

Petasin

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Topbatt Chemical Co., Ltd.

Topbatt Chemical Co., Ltd., Established in 2019, located in Shenzhen, Guangdong Province, is a Manufacturer and Trading company which specialized in fine chemicals like Pharmaceutical Reference Standards and Stable Isotopes. Our Stable Isotopes produ

Petasin

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

26577-85-5

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

High purity Application:Pharmaceutical intermediates, Material synthesis and analyzing the expectant ingredients

Petasin

Cas:26577-85-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-methylbut-2-enoic acid (1R,2R,7S,8aR)-7-(1-hydroxy-1-methylethyl)-1,8a-dimethyl-6-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl ester
164414-38-4

2-methylbut-2-enoic acid (1R,2R,7S,8aR)-7-(1-hydroxy-1-methylethyl)-1,8a-dimethyl-6-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl ester

A

Isopetasin
469-26-1

Isopetasin

B

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
With trifluoromethylsulfonic anhydride; N-ethyl-N,N-diisopropylamine In dichloromethane at -78℃; for 1h;A 17%
B 69%
2-methylbut-2-enoic acid (1R,2R,7S,8aR)-7-(1-hydroxy-1-methylethyl)-1,8a-dimethyl-6-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl ester
164414-38-4

2-methylbut-2-enoic acid (1R,2R,7S,8aR)-7-(1-hydroxy-1-methylethyl)-1,8a-dimethyl-6-oxo-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl ester

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
With trifluoromethylsulfonic anhydride; N-ethyl-N,N-diisopropylamine In dichloromethane at -78℃; for 1h;69%
Angelic acid
565-63-9

Angelic acid

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: Et3N / toluene / 2 h / Ambient temperature
2: Et3N / toluene / 24 h / 80 °C
3: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
(2Z)-2-methyl-2-butenoic 2,4,6-trichlorobenzoic anhydride
137601-32-2

(2Z)-2-methyl-2-butenoic 2,4,6-trichlorobenzoic anhydride

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Et3N / toluene / 24 h / 80 °C
2: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
(4aR,5R,6R)-(+)-6-(tert-butyldimethylsiloxy)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one
122052-66-8

(4aR,5R,6R)-(+)-6-(tert-butyldimethylsiloxy)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 1.) HMDS, 3.) ZnCl2
2: 94 percent / 50percent aq. HF / acetonitrile / 2 h / Ambient temperature
3: Et3N / toluene / 24 h / 80 °C
4: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
(3S,4aR,5R,6R)-(+)-6-hydroxy-3-(1-hydroxy-1-methylethyl)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one
164577-44-0

(3S,4aR,5R,6R)-(+)-6-hydroxy-3-(1-hydroxy-1-methylethyl)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Et3N / toluene / 24 h / 80 °C
2: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
(1R,2R,3R)-(-)-<3-(tert-butyldimethylsiloxy)-1,2-dimethyl-6-oxocyclohexyl>propionic acid
164414-36-2

(1R,2R,3R)-(-)-<3-(tert-butyldimethylsiloxy)-1,2-dimethyl-6-oxocyclohexyl>propionic acid

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: toluene / 5 h / 80 °C
2: ethanol / 15 h / Heating
3: 1.) HMDS, 3.) ZnCl2
4: 94 percent / 50percent aq. HF / acetonitrile / 2 h / Ambient temperature
5: Et3N / toluene / 24 h / 80 °C
6: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
(3S,4aR,5R,6R)-(+)-6-(tert-butyldimethylsiloxy)-3-(1-hydroxy-1-methylethyl)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one
164414-37-3

(3S,4aR,5R,6R)-(+)-6-(tert-butyldimethylsiloxy)-3-(1-hydroxy-1-methylethyl)-4a,5-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 94 percent / 50percent aq. HF / acetonitrile / 2 h / Ambient temperature
2: Et3N / toluene / 24 h / 80 °C
3: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme
5-[(1R,2R,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-1,2-dimethyl-6-oxo-cyclohexyl]-3-oxo-2-(triphenyl-λ5-phosphanylidene)-pentanoic acid phenylamide

5-[(1R,2R,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-1,2-dimethyl-6-oxo-cyclohexyl]-3-oxo-2-(triphenyl-λ5-phosphanylidene)-pentanoic acid phenylamide

Petasin
26577-85-5

Petasin

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: ethanol / 15 h / Heating
2: 1.) HMDS, 3.) ZnCl2
3: 94 percent / 50percent aq. HF / acetonitrile / 2 h / Ambient temperature
4: Et3N / toluene / 24 h / 80 °C
5: 69 percent / (CF3SO2)O, i-Pr2NEt / CH2Cl2 / 1 h / -78 °C
View Scheme

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