Our Company main product 一:suzuki reaction customization 二:Boronic acid derivative ①:phenylboronic acid derivative ②:Phenylboronic acid pinacol ester derivative ③:Potassium phenyltrifluoroborate derivative ④:Phenylboronic acid MIDA ester derivative
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inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryThe company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:white crystalline powder Storage:Sealed
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inquiryProduct description: Product name 2-Fluoro-3-methoxybenzeneboronic acid CAS number 352303-67-4 Assay ≥99% Appearance White powder Capacity 200mt/year Application OLED/pharmac
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryHigh purity CAS 352303-67-4 2-FLUORO-3-METHOXYPHENYLBORONIC ACID in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLE
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
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inquiryBenzenemethanol, -alpha-,2,3-trimethyl- (9CI) Basic information Product Name: Benzenemethanol, -alpha-,2,3-trimethyl- (9CI) Synonyms: Benzenemethanol, -alpha
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla
Cas:352303-67-4
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
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inquiry2-FLUORO-3-METHOXYPHENYLBORONIC ACID CAS:352303-67-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qu
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
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inquiryTriumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and quality c
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inquiryOur company provides one-stop services of research - development - production for a variety of special prouducts. Not only do we make effective use of our strong technological strength, but also establish of cooperative relations with several well-
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:352303-67-4
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:352303-67-4
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:352303-67-4
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inquiryEstablished in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site
Cas:352303-67-4
Min.Order:10 Gram
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inquiryHangzhou Huarong Pharm Co., Ltd. established since 2009 , has been always focusing on supplying products and services to our clients in the field of small molecule drug. Huarong Pharm has built platforms for the research, development and manufac
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
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inquiry1,In No Less 8 years exporting experience. 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Onchem specialized in APIs, chemical intermediates, herbal
Cas:352303-67-4
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inquiryProduct Name: 2-FLUORO-3-METHOXYPHENYLBORONIC ACID Synonyms: Fluoro-3-Methoxyphenylboronic;2-F,3-MeOC6H3B(OH)2;3-Borono-2-fluoroanisole;2-FLUORO-3-METHOXYPHENYLBORONIC ACID;2-FLUORO-3-METHOXYBENZENEBORONIC ACID;2-Fluoro-3-Methoxyphenylboroni;2-
Cas:352303-67-4
Min.Order:1 Gram
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inquiryProduct name: 2-Fluoro-3-Methoxyphenylboronic Acid CAS No.:352303-67-4 Molecule Formula:C7H8BFO3 Molecule Weight:169.94 Purity: 99% Package: 20kg/drum Description:White or off-white powder Manufacture Standards:Enterprise Standard
Cas:352303-67-4
Min.Order:1 Kilogram
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Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:352303-67-4
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inquiryn-butyllithium
Trimethyl borate
1-fluoro-2-methoxybenzene
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
In tetrahydrofuran | 26% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With hydrogenchloride |
1-bromo-2-fluoro-3-methoxybenzene
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
Stage #1: 2-fluoro-3-methoxy-1-bromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.166667h; Inert atmosphere; Stage #2: With Triisopropyl borate In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere; Stage #3: With water; ammonium chloride In tetrahydrofuran for 0.5h; |
tert-butyl {[5-bromo-1-(pyridin-3-ylsulfonyl)-1H-pyrrol-3-yl]methyl}methylcarbamate
(2-fluoro-3-methoxyphenyl)boronic acid
tert-butyl {[5-(2-fluoro-3-methoxyphenyl)-1-(pyridin-3-ylsulfonyl)-1H-pyrrol-3-yl]methyl}methylcarbamate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 100℃; for 2h; | 100% |
(2-fluoro-3-methoxyphenyl)boronic acid
(2-fluoro-3-hydroxyphenyl)boronic acid
Conditions | Yield |
---|---|
Stage #1: (2-fluoro-3-methoxyphenyl)boronic acid With boron tribromide In dichloromethane at 5 - 20℃; Inert atmosphere; Stage #2: With sodium hydrogencarbonate In ethanol; dichloromethane Cooling; | 96% |
With boron tribromide In dichloromethane at 5 - 20℃; for 1h; Inert atmosphere; | 96% |
Stage #1: (2-fluoro-3-methoxyphenyl)boronic acid With boron tribromide In dichloromethane at 0℃; for 1h; Stage #2: With methanol In dichloromethane at 0℃; for 1h; |
(2-fluoro-3-methoxyphenyl)boronic acid
2-fluoro-3-methoxyphenol
Conditions | Yield |
---|---|
With dihydrogen peroxide In 1,4-dioxane at 20℃; Cooling with ice; | 96% |
With dihydrogen peroxide; acetic acid In tetrahydrofuran; water at 0 - 20℃; | 81% |
With water; triethylamine In acetonitrile at 20℃; for 36h; Irradiation; | 72% |
2-bromothiophene
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water for 4h; Suzuki Coupling; Inert atmosphere; Reflux; | 96% |
(6-bromopyridin-2-yl)-(4-fluoro-3-methoxyphenyl)-methanone
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 95% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 94% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
In methanol; water at 70℃; for 24h; | 94% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 93% |
3-bromo-2-chlorobenzenamine
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With [1,1′-bis(di-cyclohexylphosphino)ferrocene]dichloropalladium (II); sodium carbonate In 1,4-dioxane; water at 90℃; for 2h; Inert atmosphere; | 93% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 92% |
(6-bromopyridin-2-yl)(2-methoxyphenyl)methanone
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 92% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 92% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
Stage #1: [14C]1-(2-fluoro-6-(trifluoromethyl)benzyl)-5-iodo-6-methylpyrimidine-2,4(1H,3H)-dione; (2-fluoro-3-methoxyphenyl)boronic acid With potassium hydroxide; tri tert-butylphosphoniumtetrafluoroborate In acetone at 45℃; for 0.5h; Inert atmosphere; Stage #2: With palladium diacetate In acetone at 55℃; for 1.5h; Inert atmosphere; | 92% |
3-bromo-2-fluorobenzaldehyde
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water Suzuki Coupling; Reflux; | 90.3% |
methyl 2-bromo-5-nitrobenzoate
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene for 18h; Suzuki coupling; Heating; | 90% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane; water at 100℃; for 3h; Suzuki Coupling; Inert atmosphere; | 90% |
{(R)-2-[5-bromo-3-(2-fluoro-6-trifluoromethyl-benzyl)-4-methyl-2,6-dioxo-3,6-dihydro-2H-pyrimidin-1-yl]-1-phenyl-ethyl}-carbamic acid tert-butyl ester
Pamoic acid
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
Stage #1: {(R)-2-[5-bromo-3-(2-fluoro-6-trifluoromethyl-benzyl)-4-methyl-2,6-dioxo-3,6-dihydro-2H-pyrimidin-1-yl]-1-phenyl-ethyl}-carbamic acid tert-butyl ester; (2-fluoro-3-methoxyphenyl)boronic acid With sodium carbonate In 1,4-dioxane; water for 0.25h; Inert atmosphere; Stage #2: With tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 95 - 100℃; Inert atmosphere; Stage #3: Pamoic acid Further stages; | 90% |
(2-fluoro-3-methoxyphenyl)boronic acid
3-[(2R)-amino-2-phenylethyl]-5-(2-fluoro-3-methoxyphenyl)-1-[2-fluoro-6-(trifluoromethyl)benzyl]-6-methyl-2,4(1H,3H)-pyrimidinedione trifluoroacetate
Conditions | Yield |
---|---|
With potassium phosphate tribasic trihydrate; palladium diacetate; tri tert-butylphosphoniumtetrafluoroborate In water; acetone at 20 - 60℃; for 20h; Time; Inert atmosphere; | 89.2% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 150℃; for 1h; Suzuki Coupling; Inert atmosphere; Microwave irradiation; | 89% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 89% |
1-{[2-fluoro-6-(trifluoromethyl)phenyl]methyl}-5-iodo-6-methylpyrimidine-2,4(1H,3H)-dione
(2-fluoro-3-methoxyphenyl)boronic acid
5-(2-fluoro-3-methoxyphenyl)-1-{[2-fluoro-6-(trifluoromethyl)phenyl]methyl}-6-methylpyrimidine-2,4(1H,3H)-dione
Conditions | Yield |
---|---|
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); potassium hydroxide In water; acetone at 40 - 45℃; for 2.5h; | 88.4% |
Stage #1: 1-{[2-fluoro-6-(trifluoromethyl)phenyl]methyl}-5-iodo-6-methylpyrimidine-2,4(1H,3H)-dione; (2-fluoro-3-methoxyphenyl)boronic acid With potassium hydroxide In water; acetone for 0.5 - 1h; Stage #2: 1,1-(bis-di-t-butylphosphino)ferrocene palladium dichloride In water; acetone at 40 - 45℃; for 2.5h; Product distribution / selectivity; | 87% |
Stage #1: 1-{[2-fluoro-6-(trifluoromethyl)phenyl]methyl}-5-iodo-6-methylpyrimidine-2,4(1H,3H)-dione; (2-fluoro-3-methoxyphenyl)boronic acid With potassium hydroxide; tri tert-butylphosphoniumtetrafluoroborate In water; acetone at 15 - 45℃; for 0.833333h; Stage #2: With palladium diacetate In water; acetone | 85% |
3-bromo-2-fluorobenzoic acid
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With potassium phosphate; potassium dihydrogenphosphate; dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) In 1,2-dimethoxyethane; ethanol; water at 60℃; for 5h; Suzuki Coupling; | 88% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 88% |
1-(3-bromophenyl)-2-phenylethane-1,2-dione
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In 1,4-dioxane; water at 100℃; for 3h; Inert atmosphere; | 88% |
5-bromo-N-methyl-N-(3-methylphenyl)thiophene-2-carboxamide
(2-fluoro-3-methoxyphenyl)boronic acid
5-(2-fluoro-3-methoxyphenyl)-N-methyl-N-(m-tolylthiophene)-2-carboxamide
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 80℃; for 14h; Inert atmosphere; | 85% |
(2R)-4-(4-iodo-2-oxopyridin-1(2H)-yl)-2-methyl-2-(methylsulfonyl)-N-(tetrahydro-2H-pyran-2-yloxy)butanamide
(2-fluoro-3-methoxyphenyl)boronic acid
(2R)-4-[4-(2-fluoro-3-methoxyphenyl)-2-oxopyridin-1(2H)-yl]-2-methyl-2-(methylsulfonyl)-N-(tetrahydro-2H-pyran-2-yloxy)butanamide
Conditions | Yield |
---|---|
With potassium carbonate In ethanol; water at 70℃; Suzuki-Miyaura coupling; | 84% |
5-bromo-N-(3-methoxyphenyl)thiophene-2-carboxamide
(2-fluoro-3-methoxyphenyl)boronic acid
5-(2-fluoro-3-methoxyphenyl)-N-(3-methoxyphenyl)thiophene-2-carboxamide
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 80℃; for 14h; Inert atmosphere; | 84% |
2-chloro-3-cyanopyrazine
(2-fluoro-3-methoxyphenyl)boronic acid
3-(2'-fluoro-3'-methoxyphenyl)pyrazine-2-carbonitrile
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; sodium carbonate In 1,2-dimethoxyethane; water at 80℃; for 0.25h; Suzuki Coupling; Inert atmosphere; | 84% |
(2-fluoro-3-methoxyphenyl)boronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,2-dimethoxyethane; water at 80℃; Suzuki Coupling; Inert atmosphere; | 84% |
{(R)-2-[5-bromo-3-(2-fluoro-6-trifluoromethyl-benzyl)-4-methyl-2,6-dioxo-3,6-dihydro-2H-pyrimidin-1-yl]-1-phenyl-ethyl}-carbamic acid tert-butyl ester
(2-fluoro-3-methoxyphenyl)boronic acid
(R)-(2-(5-(2-fluoro-3-methoxyphenyl)-3-(2-fluoro-6-(trifluoromethyl)benzyl)-4-methyl-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl)-1-phenylethyl)carbamic acid tert-butyl ester
Conditions | Yield |
---|---|
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 90℃; Suzuki Coupling; | 83% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water at 90℃; Suzuki coupling; Inert atmosphere; | 83% |
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 90℃; Suzuki Coupling; | 83% |
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