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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

9H-Fluoren-2-amine,N-hydroxy-

Cas:53-94-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

N-Hydroxy-2-aminofluorene

Cas:53-94-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

N-Hydroxy-2-aminofluorene

Cas:53-94-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

9H-Fluoren-2-amine,N-hydroxy-

Cas:53-94-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents

9H-Fluoren-2-amine,N-hydroxy-

Cas:53-94-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

N-Hydroxy-2-aminofluorene

Cas:53-94-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-nitro-9H-fluorene
607-57-8

2-nitro-9H-fluorene

N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

Conditions
ConditionsYield
With ammonium chloride; D,L-histidine; zinc at 20 - 30℃; for 0.75h; pH=7.4 - 7.5;91%
With hydrazine hydrate In ethanol; 1,2-dichloro-ethane for 1h;66%
With hydrazine hydrate; palladium on activated charcoal In tetrahydrofuran at 0℃; for 1h;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

benzaldehyde
100-52-7

benzaldehyde

α-phenyl-N-(2-aminofluorenyl)nitrone
411240-48-7

α-phenyl-N-(2-aminofluorenyl)nitrone

Conditions
ConditionsYield
In ethanol at 0 - 15℃;95%
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

acetyl chloride
75-36-5

acetyl chloride

N-Hydroxy-2-acetylaminofluoren
53-95-2

N-Hydroxy-2-acetylaminofluoren

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether at 20℃; for 1h;78%
With sodium hydrogencarbonate; triethylamine 1) THF, rt, 30 min, 2) 30 min, rt; Yield given. Multistep reaction;
With sodium hydrogencarbonate In diethyl ether at 0℃;
Acetyl cyanide
631-57-2

Acetyl cyanide

N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

O-Acetyl-N-(2-fluorenyl)hydroxylamin
64253-17-4

O-Acetyl-N-(2-fluorenyl)hydroxylamin

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at -40℃; for 2h; all steps at -40 deg C (at least);60%
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

benzyl N-[(3S,6S)-2-(9H-fluoren-2-yl)-6-methyl-3,6-dihydro-2H-1,2-oxazin-3-yl]carbamate

benzyl N-[(3S,6S)-2-(9H-fluoren-2-yl)-6-methyl-3,6-dihydro-2H-1,2-oxazin-3-yl]carbamate

Conditions
ConditionsYield
Stage #1: N-(9H-fluoren-2-yl)hydroxylamine With 3-chloro-benzenecarboperoxoic acid In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With (S)-3,3'-bis(2,4,6-tri-iso-propylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate In toluene at -65℃; for 0.0833333h; Inert atmosphere;
Stage #3: With benzyl ((1E,3E)-penta-1,3-dien-1-yl)carbamate In toluene at -65℃; for 72h; Diels-Alder Cycloaddition; Inert atmosphere; stereoselective reaction;
59%
n-Butyl nitrite
544-16-1

n-Butyl nitrite

N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

N-fluoren-2-yl-N-nitroso-hydroxylamine

N-fluoren-2-yl-N-nitroso-hydroxylamine

Methoxyacetyl chloride
38870-89-2

Methoxyacetyl chloride

N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

N-(2-fluorenyl)methoxyacetohydroxamic acid

N-(2-fluorenyl)methoxyacetohydroxamic acid

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
nitrourea
556-89-8

nitrourea

N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

N-hydroxy-N-(2-fluorenyl)urea

N-hydroxy-N-(2-fluorenyl)urea

Conditions
ConditionsYield
In water for 3h; Heating; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

2,2'-azoxyfluorene

2,2'-azoxyfluorene

Conditions
ConditionsYield
With 4-nitrophenol acetate In ethanol-d6 at 22℃; for 48h;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

propionyl chloride
79-03-8

propionyl chloride

N-hydroxy-N-propionyl-2-aminofluorene

N-hydroxy-N-propionyl-2-aminofluorene

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

acetic anhydride
108-24-7

acetic anhydride

N-Hydroxy-2-acetylaminofluoren
53-95-2

N-Hydroxy-2-acetylaminofluoren

Conditions
ConditionsYield
In chloroform-d1 at 22℃;
With triethylamine In ethyl acetate at 20℃; for 0.5h;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

benzoyl chloride
98-88-4

benzoyl chloride

N-hydroxy-N-2-fluorenylbenzamide
3671-71-4

N-hydroxy-N-2-fluorenylbenzamide

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

n-valeryl chloride
638-29-9

n-valeryl chloride

Pentanoic acid (9H-fluoren-2-yl)-hydroxy-amide

Pentanoic acid (9H-fluoren-2-yl)-hydroxy-amide

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

methyl isocyanate
624-83-9

methyl isocyanate

N-hydroxy-N-(2-fluorenyl)-N'-methylurea

N-hydroxy-N-(2-fluorenyl)-N'-methylurea

Conditions
ConditionsYield
In benzene Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

butyryl chloride
141-75-3

butyryl chloride

N-(9H-Fluoren-2-yl)-N-hydroxy-butyramide

N-(9H-Fluoren-2-yl)-N-hydroxy-butyramide

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

methyl chloroformate
79-22-1

methyl chloroformate

methyl N-hydroxy-N-(2-fluorenyl)carbamate

methyl N-hydroxy-N-(2-fluorenyl)carbamate

Conditions
ConditionsYield
In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

phenyl chloroformate
1885-14-9

phenyl chloroformate

phenyl N-hydroxy-N-(2-fluorenyl)carbamate

phenyl N-hydroxy-N-(2-fluorenyl)carbamate

Conditions
ConditionsYield
In diethyl ether Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

phenylacetyl chloride
103-80-0

phenylacetyl chloride

N-(9H-Fluoren-2-yl)-N-hydroxy-2-phenyl-acetamide

N-(9H-Fluoren-2-yl)-N-hydroxy-2-phenyl-acetamide

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

Cyclobutanecarbonyl chloride
5006-22-4

Cyclobutanecarbonyl chloride

Cyclobutanecarboxylic acid (9H-fluoren-2-yl)-hydroxy-amide

Cyclobutanecarboxylic acid (9H-fluoren-2-yl)-hydroxy-amide

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether Ambient temperature; Yield given;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

[8-13C]Guo
247226-75-1

[8-13C]Guo

A

C8-(2-aminofluorenyl)Guo

C8-(2-aminofluorenyl)Guo

B

N7-(2-aminofluorenyl)Guo

N7-(2-aminofluorenyl)Guo

Conditions
ConditionsYield
With ethylene diamine tetraacetic acid tetrasodium salt; aspirin In phosphate buffer at 23℃; for 0.283333h; pH=7.0; Product distribution; Further Variations:; Reaction partners; reaction time;
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

2-fluoren
73051-69-1

2-fluoren

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 95 percent / ethanol / 0 - 15 °C
2: 87 percent / benzene / 0.17 h / 0 °C
3: 22 percent / ethanol; various solvent(s) / 12 h / 60 °C / pH 7.0
4: 96 percent / Na2CO3; MeOH / 8 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 60 percent / Et3N / tetrahydrofuran / 2 h / -40 °C / all steps at -40 deg C (at least)
2: 14 percent / tetrahydrofuran; H2O / 1. -40 deg C 2. room temperature
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

N-acetoxy-N-benzoyl-2-fluorenylamine
29968-75-0

N-acetoxy-N-benzoyl-2-fluorenylamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 95 percent / ethanol / 0 - 15 °C
2: 87 percent / benzene / 0.17 h / 0 °C
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

N-(benzoyl)-N-(deoxyguanosin-8-yl)-2-aminofluorene
411240-49-8

N-(benzoyl)-N-(deoxyguanosin-8-yl)-2-aminofluorene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 95 percent / ethanol / 0 - 15 °C
2: 87 percent / benzene / 0.17 h / 0 °C
3: 22 percent / ethanol; various solvent(s) / 12 h / 60 °C / pH 7.0
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

>-2-aminofluorene
137390-96-6

>-2-aminofluorene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) NEt3, 2) aq. NaHCO3 / 1) THF, rt, 30 min, 2) 30 min, rt
2: 1) N-methylmorpholine, ClCOOiBu / 1) DMF, 15 min, -20 deg C, 2) -20 deg C, 5 min, then rt, 15 min
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

8-[acetyl(9H-fluoren-2-yl)amino]-3',5'-bis-O-(tert-butyldimethylsilyl)-2'-deoxyguanosine
1009639-13-7

8-[acetyl(9H-fluoren-2-yl)amino]-3',5'-bis-O-(tert-butyldimethylsilyl)-2'-deoxyguanosine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydrogencarbonate / diethyl ether / 0 °C
2: caesium carbonate / 1,2-dimethoxyethane / 20 °C / Inert atmosphere
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

fluorene
37819-60-6

fluorene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium hydrogencarbonate / diethyl ether / 0 °C
2: caesium carbonate / 1,2-dimethoxyethane / 20 °C / Inert atmosphere
3: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

8-[acetyl(2-fluorenyl)amino]-N2-[(dimethylamino)methylene]-2'-deoxyguanosine

8-[acetyl(2-fluorenyl)amino]-N2-[(dimethylamino)methylene]-2'-deoxyguanosine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: sodium hydrogencarbonate / diethyl ether / 0 °C
2: caesium carbonate / 1,2-dimethoxyethane / 20 °C / Inert atmosphere
3: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran
4: pyridine / 20 °C / Inert atmosphere
View Scheme
N-(9H-fluoren-2-yl)hydroxylamine
53-94-1

N-(9H-fluoren-2-yl)hydroxylamine

8-[acetyl(2-fluorenyl)amino]-5'-O-dimethoxytrityl-N2-[(dimethylamino)methylene]-2'-deoxyguanosine

8-[acetyl(2-fluorenyl)amino]-5'-O-dimethoxytrityl-N2-[(dimethylamino)methylene]-2'-deoxyguanosine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: sodium hydrogencarbonate / diethyl ether / 0 °C
2: caesium carbonate / 1,2-dimethoxyethane / 20 °C / Inert atmosphere
3: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran
4: pyridine / 20 °C / Inert atmosphere
5: pyridine / 20 °C / Inert atmosphere
View Scheme

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