Chinese Name: deoxyarbutin English Name: deoxyarbutin CAS No.: 53936-56-4 Molecular formula: C11H14O3 Molecular weight: one hundred and ninety-four point two three Product performance: as a competitive tyrosinase inhibitor, deoxyarbutin can regu
Cas:53936-56-4
Min.Order:1 Kilogram
FOB Price: $1000.0
Type:Trading Company
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Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------
Cas:53936-56-4
Min.Order:1 Gram
FOB Price: $100.0 / 500.0
Type:Trading Company
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Min.Order:1 Kilogram
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inquiryProduct description: Product name Deoxyarbutin CAS number 53936-56-4 Assay ≥99% Appearance White powder Capacity 200mt/year Application Cosmetic additive for skin whitening
Cas:53936-56-4
Min.Order:10 Gram
FOB Price: $12.0
Type:Lab/Research institutions
inquiryUnique advantages for Deoxyarbutin Cas 53936-56-4 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Almost white powder Storage:Store in dry and cool place Package:1kg/foil bag;25
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Min.Order:1 Kilogram
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Type:Trading Company
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inquiryProduct Description Product Name Deoxyarbutin Powder Chemical name Tetrahydropyranyloxyphenol
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Cas:53936-56-4
Min.Order:1 Gram
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Type:Manufacturers
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Min.Order:5 Kiloliter
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Type:Manufacturers
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Type:Lab/Research institutions
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Type:Trading Company
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Min.Order:10 Gram
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Type:Trading Company
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Cas:53936-56-4
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Name Deoxyarbutin CAS NO. 53936-56-4 Molecular Formula C11H14O3 Specification 98% Test Method HPLC Appearan
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Cas:53936-56-4
Min.Order:100 Gram
Negotiable
Type:Other
inquiryAppearance:White to off-white powder Storage:under inert gas (nitrogen or Argon) at 2-8°C Package:25kg/drum Application:Deoxyarbutin acts as a skin whitening agent through the inhibition of tyrosinase. A safer alternative to the use of hydroquinone
Cas:53936-56-4
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Lab/Research institutions
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Type:Lab/Research institutions
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Cas:53936-56-4
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Type:Trading Company
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Cas:53936-56-4
Min.Order:100 Gram
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Type:Trading Company
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Cas:53936-56-4
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
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Min.Order:1 Kilogram
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Type:Lab/Research institutions
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inquiryDeoxyarbutin CAS: 53936-56-4 Specification Product name Deoxyarbutin CAS number 53936-56-4 Assay ≥99% Appearance White powder Capacity 200mt/year Application Cosmetic add
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Type:Lab/Research institutions
inquiry4-benzyloxyphenyl 2-tetrahydropyranyl ether
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; hydrogen In ethanol at 20℃; under 3000.3 Torr; for 3h; Autoclave; | 100% |
With aluminum oxide; hydrogen; palladium on activated charcoal In ethyl acetate at 20℃; Product distribution / selectivity; | 82% |
With hydrogen; calcium carbonate; palladium on activated charcoal In ethyl acetate at 20℃; Product distribution / selectivity; | 80% |
2-(4-Acetoxyphenoxy)tetrahydropyran
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium perborate In methanol at 25℃; for 0.25h; | 84% |
3,4-dihydro-2H-pyran
hydroquinone
A
2-(4-(tetrahydro-2H-pyran-2-yloxy)phenoxy)tetrahydro-2H-pyran
B
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With iron(III) sulfate In acetone for 1h; | A 12% B 72% |
With aluminium trichloride |
Conditions | Yield |
---|---|
With ruthenium(III) acetate at 20℃; for 12h; | 72% |
With pyridinium p-toluenesulfonate In dichloromethane at 10 - 25℃; for 16h; Inert atmosphere; | 52.7% |
With pyridinium p-toluenesulfonate In tetrahydrofuran at 20℃; for 16h; Inert atmosphere; | 49.6% |
(4-((tetrahydro-2H-pyran-2-yl)oxy)phenyl)magnesium bromide
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With air In tetrahydrofuran at -25℃; under 12929 Torr; for 0.0566667h; Green chemistry; | 64% |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium acetate; nickel In N,N-dimethyl-formamide for 18h; Ambient temperature; | 25% |
4-Benzyloxyphenol
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 8 h / 20 °C / Inert atmosphere; Cooling with ice 2: 5%-palladium/activated carbon; hydrogen / ethanol / 3 h / 20 °C / 3000.3 Torr / Autoclave View Scheme | |
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 6 h / 20 °C / Inert atmosphere; Cooling with ice 2: pyridine; 5%-palladium/activated carbon; hydrogen / tetrahydrofuran; ethanol / 8 h / 50 °C / 3750.38 Torr View Scheme | |
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 7 h / 20 °C / Cooling with ice 2: 5%-palladium/activated carbon; hydrogen / ethanol; tetrahydrofuran / 8 h / 50 °C / 3750.38 Torr View Scheme |
3,4-dihydro-2H-pyran
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 8 h / 20 °C / Inert atmosphere; Cooling with ice 2: 5%-palladium/activated carbon; hydrogen / ethanol / 3 h / 20 °C / 3000.3 Torr / Autoclave View Scheme | |
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 6 h / 20 °C / Inert atmosphere; Cooling with ice 2: pyridine; 5%-palladium/activated carbon; hydrogen / tetrahydrofuran; ethanol / 8 h / 50 °C / 3750.38 Torr View Scheme | |
Multi-step reaction with 2 steps 1: pyridinium p-toluenesulfonate / dichloromethane / 7 h / 20 °C / Cooling with ice 2: 5%-palladium/activated carbon; hydrogen / ethanol; tetrahydrofuran / 8 h / 50 °C / 3750.38 Torr View Scheme |
6-(2-acryloyloxyethoxy)capronic acid
4-(tetrahydro-2H-2-pyranyloxy)phenol
C22H30O7
Conditions | Yield |
---|---|
With dmap; 2,6-di-tert-butyl-4-methyl-phenol; dicyclohexyl-carbodiimide In chloroform at 20℃; Inert atmosphere; Cooling with ice; | 94% |
Conditions | Yield |
---|---|
With potassium carbonate In ISOPROPYLAMIDE at 90 - 100℃; Inert atmosphere; | 91% |
With potassium carbonate In N,N-dimethyl-formamide at 90 - 100℃; Inert atmosphere; | 91% |
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere; | 84.9% |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With potassium carbonate In isopropyl alcohol for 3h; Reflux; | 91% |
phosphonic acid diethyl ester
4-(tetrahydro-2H-2-pyranyloxy)phenol
O,O-diethyl O-4-tetrahydro-2H-2-pyranyloxyphenyl phosphate
Conditions | Yield |
---|---|
With triethylamine In tetrachloromethane | 88% |
4-(tetrahydro-2H-2-pyranyloxy)phenol
3-(4-bromobutoxy)oxetane
2-{4-[4-(oxetan-3-yloxy)-butoxy]-phenoxy}-tetrahydro-pyran
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 80℃; Etherification; | 87% |
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 25℃; for 16h; Inert atmosphere; Cooling with ice; | 83.6% |
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃; for 7h; Inert atmosphere; Cooling with ice; | 9 g |
4-Methyl-1-pentanol
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 78% |
3-bromo-2-(4-fluorophenyl)-6-methoxybenzo[b]thiophene 1-oxide
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Stage #1: 4-(tetrahydro-2H-2-pyranyloxy)phenol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.166667h; Stage #2: 3-bromo-2-(4-fluorophenyl)-6-methoxybenzo[b]thiophene 1-oxide In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 2h; | 75% |
Conditions | Yield |
---|---|
With caesium carbonate In dimethyl sulfoxide at 120℃; for 3h; | 75% |
2-chloromethyl-3-chloroprop-1-ene
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Stage #1: 2-chloromethyl-3-chloroprop-1-ene; 4-(tetrahydro-2H-2-pyranyloxy)phenol With sodium hydride In N,N-dimethyl-formamide Substitution; Stage #2: In ethanol alcoholysis; acidic solution; | 74% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 85℃; for 16h; | 56% |
ethylene dibromide
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran at 20℃; for 24h; Reflux; | 46% |
In tetrahydrofuran for 24h; Reflux; Alkaline conditions; |
chloroform
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol at 70℃; for 3h; Reimer-Tiemann reaction; | 41% |
4-(tetrahydro-2H-2-pyranyloxy)phenol
2-bromoethanol
2-(4-((tetrahydro-2H-pyran-2-yl)oxy)phenoxy)ethanol
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere; | 32% |
With potassium carbonate In N,N-dimethyl-formamide | |
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 100℃; for 4h; |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With potassium tert-butylate In 1-methyl-pyrrolidin-2-one at 15 - 140℃; for 2h; Microwave irradiation; | 29% |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 70℃; Alkylation; |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
With sodium methylate In N,N-dimethyl-formamide at 55℃; for 16h; | 111.5 g |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: NaH / dimethylformamide 1.2: 74 percent / ethanol / acidic solution 2.1: 1 percent Spectr. / NaH / dimethylformamide / 24 h / 65 °C View Scheme |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: NaH / dimethylformamide 1.2: 74 percent / ethanol / acidic solution 2.1: 24 percent Spectr. / NaH / dimethylformamide / 24 h / 65 °C View Scheme |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: NaH / dimethylformamide 1.2: 74 percent / ethanol / acidic solution 2.1: 4 percent Spectr. / NaH / dimethylformamide / 24 h / 65 °C View Scheme |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: NaH / dimethylformamide 1.2: 74 percent / ethanol / acidic solution 2.1: 4 percent Spectr. / NaH / dimethylformamide / 24 h / 65 °C View Scheme |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: NaH / dimethylformamide / 70 °C 2: H3O+ / ethanol View Scheme |
4-(tetrahydro-2H-2-pyranyloxy)phenol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: NaH / dimethylformamide / 70 °C 2: H3O+ / ethanol 3: 38 percent / NaH / dimethylformamide / 70 °C View Scheme |
4-[4-(3-ethyloxetane-3-ylmethoxy)butyloxy]benzoic acid
4-(tetrahydro-2H-2-pyranyloxy)phenol
C23H28O6
Conditions | Yield |
---|---|
Stage #1: 4-[7-(3-ethyl-3-oxetanyl)-1,6-dioxaheptyl]benzoic acid; 4-(tetrahydro-2H-2-pyranyloxy)phenol With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 2h; Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 0.5h; |
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