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inquiry17-year experience in Phytochemicals Each product has passed very strict tests (NMR\MS\HPLC) Agents in 13 countries Certified by ISO 9001:2008 quality management system Leader Supplier of Botanical Reference Materials in China
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inquiryShanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu
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inquiryChengdu Biopurify Phytochemicals Ltd. is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medic
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inquiryWhy Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu
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inquiryWhy is SINOWAY:1) Specialized in pharmaceutical and healthcare industrial since 19872) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days.4) We have warehouse in USA with quickly shipment . Application:Herbal extr
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inquiryhigh quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
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inquirybest price high quality Storage:Room Temperature Application:For pharmacy chemicals Transportation:by sea, air
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inquirySanguinarium chloride cas 5578-73-4Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
SANGUINARINE CHLORIDEAppearance:fine powder Storage:cool, dry place and avoid strongl light Package:1kg/bag, 25kg/drum Application:health supplement Transportation:DHL,TNT,FEDEX,EMS, by air, by sea
*stable and better quality products*efficient and meticulous servicesAppearance:Powder Storage:Store in dry, cool and ventilated place Package:1kg/tin 5kg/tin 25kg/carton Application:Use in healthcare products. Use in food products. Use in Cosmetic p
BOC Sciences provides a wide range of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds.Appearanc
good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:20mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any por
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
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HENAN SUNLAKE ENTERPRISE CORPORATION Our company advantages: 1、The highest quality with the competitive price. 2、Professional human services. 3、The fastest and safest delivery service. 4、The faster and safest delivery service. 5、The hig
Conditions | Yield |
---|---|
Stage #1: oxysanguinarine With lithium aluminium tetrahydride In tetrahydrofuran at 20℃; for 0.333333h; Inert atmosphere; Stage #2: With hydrogenchloride In water at 20℃; | 98% |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hydroxide; jones reagent In acetone at 0℃; for 0.5h; | 85.4% |
With sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene | |
With sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone In water; benzene for 1h; Ambient temperature; | 2.1 g |
Stage #1: dihydrosanguinarine With 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide In toluene at 20℃; for 2h; Stage #2: With hydrogenchloride | |
Stage #1: dihydrosanguinarine With 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide In water; toluene at 20℃; for 1h; Stage #2: With hydrogenchloride In chloroform; water at 0℃; |
C20H17NO4
sanguinarine chloride
Conditions | Yield |
---|---|
With hydrogenchloride; palladium on activated charcoal; maleic acid In water; acetic acid | 47% |
Conditions | Yield |
---|---|
(methylation); | |
Multi-step reaction with 2 steps 1.1: sodium tetrahydroborate / 40 °C 2.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide / toluene; water / 1 h / 20 °C 2.2: 0 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
With hydrogenchloride In water Heating; |
sanguinarine chloride
Conditions | Yield |
---|---|
With iron(III) chloride |
sanguinarine chloride
Conditions | Yield |
---|---|
With mercury(II) diacetate |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 9.8 g / pyridine / 6 h / Ambient temperature 2: HgO / acetic acid / 4 h / Heating 3: 2.1 g / 2,3-dichloro-5,6-dicyano-p-benzoquinone, 5percent NaOH / benzene; H2O / 1 h / Ambient temperature View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: HgO / acetic acid / 4 h / Heating 2: 2.1 g / 2,3-dichloro-5,6-dicyano-p-benzoquinone, 5percent NaOH / benzene; H2O / 1 h / Ambient temperature View Scheme |
13-methyl-6,7,13,14-tetrahydro-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridine
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: Pd-C 2: DDQ, aq. NaOH / benzene View Scheme |
Conditions | Yield |
---|---|
Acidic aq. solution; |
methyl 5-iodobenzo[d][1,3]dioxole-4-carboxylate
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: bis-triphenylphosphine-palladium(II) chloride; triethylamine; zinc(II) chloride; zinc / tetrahydrofuran / 24 h / 60 °C / Inert atmosphere 2.1: potassium hydroxide / aacetone / 2 h / Reflux; Inert atmosphere 3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 4.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 4.2: 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: 0.5 h / Inert atmosphere 2.1: bis-triphenylphosphine-palladium(II) chloride; triethylamine; zinc(II) chloride; zinc / tetrahydrofuran / 24 h / 60 °C / Inert atmosphere 3.1: potassium hydroxide / aacetone / 2 h / Reflux; Inert atmosphere 4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 5.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 5.2: 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: potassium hydroxide / aacetone / 2 h / Reflux; Inert atmosphere 2.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 3.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 3.2: 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 2.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 2.2: 20 °C View Scheme |
5-iodobenzo[d][1,3]dioxole-4-carboxylic acid
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / Inert atmosphere 2.1: 0.5 h / Inert atmosphere 3.1: bis-triphenylphosphine-palladium(II) chloride; triethylamine; zinc(II) chloride; zinc / tetrahydrofuran / 24 h / 60 °C / Inert atmosphere 4.1: potassium hydroxide / aacetone / 2 h / Reflux; Inert atmosphere 5.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 6.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 6.2: 20 °C View Scheme |
5-iodobenzo[d][1,3]dioxole-4-carbaldehyde
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 7 steps 1.1: dihydrogen peroxide; potassium hydroxide / methanol; water / 0.5 h / 65 °C / Inert atmosphere 2.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / Inert atmosphere 3.1: 0.5 h / Inert atmosphere 4.1: bis-triphenylphosphine-palladium(II) chloride; triethylamine; zinc(II) chloride; zinc / tetrahydrofuran / 24 h / 60 °C / Inert atmosphere 5.1: potassium hydroxide / aacetone / 2 h / Reflux; Inert atmosphere 6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / benzene / 2 h / Inert atmosphere; Reflux 7.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 7.2: 20 °C View Scheme |
sanguinarine acetate
sanguinarine chloride
Conditions | Yield |
---|---|
Stage #1: sanguinarine acetate With potassium hydroxide In water Stage #2: With hydrogenchloride In water |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 2: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 3: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 4: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 5: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 5 steps 1: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 2: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 3: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 4: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 5: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 7 steps 1.1: cerium(III) chloride / tetrahydrofuran / 0.08 h / -78 °C / Inert atmosphere 1.2: -78 - 20 °C / Inert atmosphere 2.1: toluene-4-sulfonic acid / dichloromethane / 0.5 h / Inert atmosphere 3.1: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 4.1: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 5.1: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 6.1: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 7.1: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 7 steps 1.1: cerium(III) chloride / tetrahydrofuran / 0.08 h / -78 °C / Inert atmosphere 1.2: -78 - 20 °C / Inert atmosphere 2.1: toluene-4-sulfonic acid / dichloromethane / 0.5 h / Inert atmosphere 3.1: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 4.1: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 5.1: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 6.1: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 7.1: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 2: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 3: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 2: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 3: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
5-bromo-benzo[1,3]dioxole-4-carbaldehyde
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: methanol / 3 h / 20 °C / Inert atmosphere 2: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 3: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 4: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 5: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 5 steps 1: methanol / 3 h / 20 °C / Inert atmosphere 2: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 3: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 4: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 5: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 6 steps 1.1: sodium tetrahydroborate; methanol / 0.5 h / 0 °C 2.1: pyridine; phosphorus tribromide / dichloromethane / 1 h / 0 - 20 °C 3.1: potassium carbonate / N,N-dimethyl-formamide / 110 °C 4.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 16 h / 90 - 110 °C / Inert atmosphere 5.1: sodium tetrahydroborate / 40 °C 6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide / toluene; water / 1 h / 20 °C 6.2: 0 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 2: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 3: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 2: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 3: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
C9H8BrNO2
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 2: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 3: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 4: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 4 steps 1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 2: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 3: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 4: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 2: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: toluene-4-sulfonic acid / dichloromethane / 0.5 h / Inert atmosphere 2: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 3: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 4: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 5: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 6: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 6 steps 1: toluene-4-sulfonic acid / dichloromethane / 0.5 h / Inert atmosphere 2: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 18 h 3: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 4: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 5: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 6: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 2: zinc(II) chloride / dichloromethane; diethyl ether / 18 h / 55 °C / Inert atmosphere; Microwave irradiation 3: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 4: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme | |
Multi-step reaction with 4 steps 1: IO4(1-)*Na(1+)*O2Si / dichloromethane / 1 h / Inert atmosphere 2: zinc(II) chloride / diethyl ether; 1,2-dichloro-ethane / 36 h / 55 °C / Inert atmosphere; Microwave irradiation 3: 2.9-dimethyl-1,10-phenanthroline; potassium tert-butylate / benzene / 5 h / 100 °C / Inert atmosphere; Schlenk technique 4: sodium hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 2 h / 20 °C View Scheme |
2,3-methylenedioxy-5-nitronaphthalene
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C / 760.05 Torr 2.1: potassium carbonate / N,N-dimethyl-formamide / 110 °C 3.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 16 h / 90 - 110 °C / Inert atmosphere 4.1: sodium tetrahydroborate / 40 °C 5.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide / toluene; water / 1 h / 20 °C 5.2: 0 °C View Scheme |
naphtho[2,3-d][1,3]dioxol-5-amine
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: potassium carbonate / N,N-dimethyl-formamide / 110 °C 2.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 16 h / 90 - 110 °C / Inert atmosphere 3.1: sodium tetrahydroborate / 40 °C 4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide / toluene; water / 1 h / 20 °C 4.2: 0 °C View Scheme |
N-(6'-bromo-2',3'-methylenedioxybenzyl)-6,7-methylenedioxy-1-naphthylamine
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 16 h / 90 - 110 °C / Inert atmosphere 2.1: sodium tetrahydroborate / 40 °C 3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium hydroxide / toluene; water / 1 h / 20 °C 3.2: 0 °C View Scheme |
Conditions | Yield |
---|---|
With copper(II) chloride dihydrate; oxygen at 80℃; for 10h; | 99% |
With sodium carbonate In water |
propan-1-ol
sanguinarine chloride
13-methyl-14-propoxy-13,14-dihydro-[1,3]dioxolo[4,5-i][1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridine
Conditions | Yield |
---|---|
With copper(II) chloride dihydrate; oxygen at 80℃; for 10h; | 99% |
sanguinarine chloride
isopropyl alcohol
C23H21NO5
Conditions | Yield |
---|---|
With copper(II) chloride dihydrate; oxygen at 80℃; for 10h; | 98% |
Conditions | Yield |
---|---|
With copper(II) chloride dihydrate; oxygen at 80℃; for 10h; | 97% |
methanol
sanguinarine chloride
6-methoxy-5,6-dihydrosanguinarine
Conditions | Yield |
---|---|
With copper(II) chloride dihydrate; oxygen at 80℃; for 10h; | 96% |
Conditions | Yield |
---|---|
In water at 60℃; for 0.5h; | 83% |
Conditions | Yield |
---|---|
With cesium fluoride In acetonitrile at 20℃; | 59% |
Conditions | Yield |
---|---|
With methanol; sodium tetrahydroborate at 20℃; for 0.5h; Darkness; | 55% |
With sodium tetrahydroborate In methanol at 20℃; for 0.5h; | 36% |
With 1,4-dihydronicotinamide adenine dinucleotide In water at 25℃; Rate constant; Kinetics; Thermodynamic data; other coenzyme, var. pH, ΔH(excit.), ΔS(excit.); | |
With sodium tetrahydroborate In methanol |
sodium methylate
sanguinarine chloride
6-methoxy-5,6-dihydrosanguinarine
Conditions | Yield |
---|---|
In methanol for 6h; pH=10; Reflux; | 51% |
sanguinarine chloride
9H-carbazole
6-(carbazol-1-yl)-5,6-dihydrosanguinarine
Conditions | Yield |
---|---|
Stage #1: 9H-carbazole With sodium hydride In tetrahydrofuran Inert atmosphere; Sonication; Stage #2: sanguinarine chloride In tetrahydrofuran at 20℃; | 45% |
Conditions | Yield |
---|---|
With hydrogenchloride; potassium hydroxide; potassium hexacyanoferrate(III) In water at 90℃; for 3h; | 43% |
With sodium hydroxide |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0 - 20℃; for 10h; | 29% |
Conditions | Yield |
---|---|
With triethylamine In acetonitrile for 10h; Reflux; | 17.4% |
Conditions | Yield |
---|---|
With water |
Conditions | Yield |
---|---|
With sodium hydroxide | |
With potassium hydroxide |
sanguinarine chloride
acetone
(+/-)-6-acetonyldihydrosanguinarine
Conditions | Yield |
---|---|
With sodium carbonate Heating; |
Conditions | Yield |
---|---|
at 207℃; for 0.116667h; |
sanguinarine chloride
Conditions | Yield |
---|---|
With sodium carbonate In water |
sanguinarine chloride
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 0.12 h / 207 °C 2: 1.3 g / NaBH4 / hexamethylphosphoric acid triamide / 2 h / 50 °C View Scheme |
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