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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Nitrobenzoic acid Methyl ester(618-95-1)

Cas:618-95-1

Min.Order:100 Gram

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

Methyl 3-nitrobenzoate Product name: Methyl 3-nitrobenzoate CAS NO. : 618-95-1 Molecular formula: C8H7NO4 Structural formula: Molecular weight:

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Nitrobenzoic acid methyl ester

Cas:618-95-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

618-95-1 Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 618-95-1 with best quality

Cas:618-95-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name Methyl 3-nitrobenzoate CAS 618-95-1 Package 25kg/drum Purity 99.0% Appearance: White powder Storage:Store in cool and d

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid, 3-nitro-,methyl ester 618-95-1

Cas:618-95-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:beige crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used t

Benzoic acid, 3-nitro-,methyl ester

Cas:618-95-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Nitrobenzoic acid methyl ester

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

FOB Price: $30.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Methyl 3-Nitrobenzoate CAS No.:618-95-1 Molecule Formula:C8H7NO4 Molecule Weight:181.15 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

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Changzhou Anchor Biological Technology Co., Ltd.

Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an

Methyl 3-nitrobenzoate Manufacturer/High quality/Best price/In stock CAS NO.618-95-1

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

METHYL 3-NITROBENZOATE cas no. 618-95-1 98%

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

3-Nitrobenzoic acid Methyl ester

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3-Nitrobenzoic acid methyl ester

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Methyl 3-Nitrobenzoate 500g

Cas:618-95-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Nanjing Fred Technology Co.,Ltd.

Fredchem focus on CRO/CMO business and its own R&D of API/Intermediates Package:Grams, Kilograms Application:Pharmaceutical field Transportation:According to customer request Port:Shanghai

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methyl 3-Nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

Methyl 3-nitrobenzoate

Cas:618-95-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methanol
67-56-1

methanol

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With 1-(ferrocenylbutyl)-4-(3-methylimidazolium) tetrafluoroborate; iodine; potassium carbonate at 50 - 60℃; for 24h; Inert atmosphere;100%
With palladium 10% on activated carbon; oxygen; sodium carbonate at 90℃; under 15001.5 Torr; for 2h; Microwave irradiation; Green chemistry;98%
With 3-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methyl-1-(2,4,6-trimethylphenyl)-1H-imidazol-3-ium bis(trifluoromethanesulfonimide) salt; caesium carbonate In toluene at 60℃; for 3h;98%
3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
In 2-methyltetrahydrofuran; diethyl ether at 20℃; for 0.486667h; Flow reactor;99%
With diethyl ether
In diethyl ether
at 0℃; for 0.25h;62.3 mg
methanol
67-56-1

methanol

3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With 4-methyl-morpholine; 2-chloro-4-methoxy-6-(N-phenylbenzamido)-1,3,5-triazine at 20℃; for 1h;99%
With oxone at 65℃; for 30h;98%
Stage #1: 3-nitrobenzoic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃;
Stage #2: methanol In dichloromethane for 0.0833333h;
98%
methanol
67-56-1

methanol

m-iodonitrobenzene
645-00-1

m-iodonitrobenzene

carbon monoxide
201230-82-2

carbon monoxide

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With triethylamine at 100℃; under 3750.38 Torr; for 1.5h; Inert atmosphere;99%
methanol
67-56-1

methanol

3-nitrophenylglyoxal
6890-77-3

3-nitrophenylglyoxal

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With oxone at 65℃; for 30h;99%
3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 20℃; for 2h;98%
In acetonitrile for 8h; Inert atmosphere; Alkaline conditions;
methanol
67-56-1

methanol

3-Nitrobenzyl alcohol
619-25-0

3-Nitrobenzyl alcohol

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With sodium carbonate; palladium; silver(l) oxide at 80℃; for 48h; Molecular sieve;98%
Stage #1: 3-Nitrobenzyl alcohol In toluene at 80℃; for 2h; Sonication;
Stage #2: methanol With Oxone In toluene for 1.5h; Sonication;
90%
With dibromamine-T; potassium carbonate In acetonitrile at 20℃; for 0.5h; Reagent/catalyst; Solvent;88%
methanol
67-56-1

methanol

2-(3-nitrophenyl)-2-oxoacetic acid
6330-40-1

2-(3-nitrophenyl)-2-oxoacetic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With oxone at 65℃; for 30h;98%
methanol
67-56-1

methanol

methyl 2-(3-nitrophenyl)-2-oxoacetate
149621-25-0

methyl 2-(3-nitrophenyl)-2-oxoacetate

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With oxone at 65℃; for 30h;95%
dimethyl sulfate
77-78-1

dimethyl sulfate

3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
Stage #1: 3-nitrobenzoic acid With potassium carbonate In acetone for 0.5h;
Stage #2: dimethyl sulfate In acetone at 20℃; for 2h;
94.3%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With trifluoromethylsulfonic anhydride; ethylammonium nitrate at -5 - 20℃; for 2h; Inert atmosphere; regioselective reaction;94%
With sulfuric acid; guanidine nitrate at 0 - 5℃; for 3h;76%
With boron trifluoride; nitric acid
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0166667h; microwave irradiation;94%
With layered double hydroxide - supported L-methionine at 180℃; for 6h; Autoclave; chemoselective reaction;89%
3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl salicylate
119-36-8

methyl salicylate

A

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

B

salicylic acid
69-72-7

salicylic acid

Conditions
ConditionsYield
Stage #1: 3-nitrobenzoic acid With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl salicylate at 110℃; for 24h;
A 93%
B n/a
(4-(methoxycarbonyl)-2-nitrophenyl)boronic acid
85107-55-7

(4-(methoxycarbonyl)-2-nitrophenyl)boronic acid

A

dimethyl 2,2’-dinitro-[1,1’-biphenyl]-4,4’-dicarboxylate
65235-35-0

dimethyl 2,2’-dinitro-[1,1’-biphenyl]-4,4’-dicarboxylate

B

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); potassium fluoride dihydrate; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran for 1h; Suzuki-Miyaura Coupling; Inert atmosphere; Reflux; Schlenk technique;A 10%
B 88%
methanol
67-56-1

methanol

3'-nitropropiophenone
17408-16-1

3'-nitropropiophenone

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With N,N-dimethyl-formamide dimethyl acetal for 16h; Heating;87%
3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
In methanol; toluene at 20℃; for 1.5h;87%
In methanol; toluene at 20℃; for 1.5h;86.79%
methyl 2-iodo-3-nitrobenzoate
93415-79-3

methyl 2-iodo-3-nitrobenzoate

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With air; tributyl borane; water In benzene at 20℃;85%
methanol
67-56-1

methanol

1-(3-nitrophenyl)-1-butanone
50766-86-4

1-(3-nitrophenyl)-1-butanone

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With N,N-dimethyl-formamide dimethyl acetal for 16h; Heating;84%
tris(o-methoxyphenyl)phosphine
4731-65-1

tris(o-methoxyphenyl)phosphine

3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With dirhodium tetraacetate In cyclohexane at 120℃; for 12h; Schlenk technique; Inert atmosphere;81%
methanol
67-56-1

methanol

3-nitrobenzaldoxime
3431-62-7

3-nitrobenzaldoxime

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With 2-nitrobenzeneseleninic acid; dihydrogen peroxide at 20℃; for 48h;80%
methyl 2-iodo-3-nitrobenzoate
93415-79-3

methyl 2-iodo-3-nitrobenzoate

phenylacetylene
536-74-3

phenylacetylene

A

methyl 3-nitro-2-(2-phenylethynyl)benzoate
894854-29-6

methyl 3-nitro-2-(2-phenylethynyl)benzoate

B

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With copper(l) iodide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 45℃; for 48h; Sonogashira coupling;A 80%
B 28%
trimethoxysilane
2487-90-3

trimethoxysilane

(3-nitrophenyl)acetonitrile
621-50-1

(3-nitrophenyl)acetonitrile

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With pyridine; ferric(III) bromide; oxygen In chlorobenzene at 130℃; for 9h; Sealed tube;80%
methanol
67-56-1

methanol

3-nitrobenzaldehyde O-methyl oxime
33499-33-1

3-nitrobenzaldehyde O-methyl oxime

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With 2-nitrobenzeneseleninic acid; dihydrogen peroxide at 65℃; for 48h;79%
[3-(methoxycarbonyl)phenyl]boronic acid
99769-19-4

[3-(methoxycarbonyl)phenyl]boronic acid

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Inert atmosphere;78%
Multi-step reaction with 2 steps
1.1: potassium hydrogen bifluoride / methanol; water / 0.03 h / 0 - 20 °C / Inert atmosphere
1.2: 0.02 h / 20 °C
2.1: Oxone / water; acetone / 2 h / 60 °C
View Scheme
(E,E)-1-(N,N-dimethylamino)-4-nitro-1,3-butadiene
108030-46-2

(E,E)-1-(N,N-dimethylamino)-4-nitro-1,3-butadiene

propynoic acid methyl ester
922-67-8

propynoic acid methyl ester

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
In xylene for 8h; Heating;74.8%
methanol
67-56-1

methanol

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

A

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

B

3-nitrobenzoic acid
121-92-6

3-nitrobenzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; calcium chloride at 65℃; for 48h; Reagent/catalyst;A 74%
B n/a
With dihydrogen peroxide at 20 - 70℃; for 15h; Green chemistry;A 68%
B 31%
With dihydrogen peroxide at 20℃; for 8h;
propan-1-ol
71-23-8

propan-1-ol

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
Stage #1: propan-1-ol; 3-nitro-benzaldehyde With sodium hypochlorite; sodium iodide In water for 0.166667h; Cooling with ice;
Stage #2: With sodium hypochlorite In water for 1.33333h; Cooling with ice;
74%
methanol
67-56-1

methanol

2-nitro-1-(3-nitrophenyl)ethan-1-one
14367-80-7

2-nitro-1-(3-nitrophenyl)ethan-1-one

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With potassium carbonate at 80℃; for 2h; Schlenk technique; Inert atmosphere;74%
With potassium carbonate at 80℃; for 2h; Inert atmosphere; Sealed tube;74%
Trimethyl borate
121-43-7

Trimethyl borate

(3-nitrophenyl)acetonitrile
621-50-1

(3-nitrophenyl)acetonitrile

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With pyridine; ferric(III) bromide; oxygen In chlorobenzene at 130℃; for 9h; Sealed tube;74%
methanol
67-56-1

methanol

CYANAMID
420-04-2

CYANAMID

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

A

methyl N-cyano-3-nitrobenzimidate
1196908-12-9

methyl N-cyano-3-nitrobenzimidate

B

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Conditions
ConditionsYield
With N-Bromosuccinimide; sodium t-butanolate at 50℃; for 12h;A 72%
B 16%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

Methyl 3-aminobenzoate
4518-10-9

Methyl 3-aminobenzoate

Conditions
ConditionsYield
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran; water at 20℃; for 0.5h;100%
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran at 20℃; for 0.5h;100%
With 5%-palladium/activated carbon; hydrogen In methanol at 20℃;100%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

methyl 3-(hydroxylamino)benzoate
36475-13-5

methyl 3-(hydroxylamino)benzoate

Conditions
ConditionsYield
With 5% Rh/C; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere; Schlenk technique; Sealed tube;100%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;99%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere;99%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

ethylenediamine
107-15-3

ethylenediamine

2-(3-nitrophenyl)-2-imidazoline
31659-42-4

2-(3-nitrophenyl)-2-imidazoline

Conditions
ConditionsYield
With sulfur In methanol at 65℃; for 5h; Time;96.4%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

3-nitrobenzoic acid hydrazide
618-94-0

3-nitrobenzoic acid hydrazide

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 4h; Reflux;96%
With hydrazine hydrate In ethanol at 85℃; for 4h;96.2%
With hydrazine hydrate In ethanol for 0.2h; Reflux; Microwave irradiation;95%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

methyl 3-{[(4-methylphenyl)sulfonyl]amino}benzoate
173436-66-3

methyl 3-{[(4-methylphenyl)sulfonyl]amino}benzoate

Conditions
ConditionsYield
With trans-N,N'-dimethyl-1,2-cyclohexyldiamine; sodium hydrogen sulfite; iron(II) chloride In dimethyl sulfoxide at 60℃; for 12h; Sealed tube; Inert atmosphere;95%
With sodium hydrogensulfite In water at 60℃; for 20h; chemoselective reaction;86%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

3-nitro benzhydroxamic acid
7335-34-4

3-nitro benzhydroxamic acid

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium hydroxide In methanol at 20℃; pH=> 10;93%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

3-nitrobenzamide
645-09-0

3-nitrobenzamide

Conditions
ConditionsYield
Stage #1: methyl 3-nitrobenzoate With ammonia In ethylene glycol at 40 - 45℃; for 20h;
Stage #2: sodium methylate In ethylene glycol at 40 - 45℃; for 5h; Conversion of starting material;
92%
With ammonia; sodium methylate In methanol at 60 - 65℃; for 26h; Conversion of starting material;68%
Stage #1: methyl 3-nitrobenzoate With ammonia In butan-1-ol at 40 - 45℃; for 20h;
Stage #2: sodium methylate In butan-1-ol at 40 - 45℃; for 8h; Conversion of starting material;
phenyl benzyl ketone
451-40-1

phenyl benzyl ketone

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

C22H18O3

C22H18O3

Conditions
ConditionsYield
With potassium phosphate; bis(acetylacetonato)palladium(II); dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine In cyclohexane at 130℃; for 24h; Inert atmosphere;92%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

3-Nitrobenzyl alcohol
619-25-0

3-Nitrobenzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate; ethanol; cerium(III) chloride heptahydrate at 20℃; for 24h; chemospecific reaction;91%
With sodium tetrahydroborate; zinc phthalocyanine In PEG-400 at 100℃; for 10h;90%
With sodium tetrahydroborate In 1,4-dioxane; water for 2h; Ambient temperature;80%
1-Bromo-2,4-dimethoxybenzene
17715-69-4

1-Bromo-2,4-dimethoxybenzene

methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

2,2',4,4'-tetramethoxy-3''-nitrotrityl alcohol
864745-95-9

2,2',4,4'-tetramethoxy-3''-nitrotrityl alcohol

Conditions
ConditionsYield
Stage #1: 1-Bromo-2,4-dimethoxybenzene With iodine; magnesium In tetrahydrofuran for 0.333333h;
Stage #2: methyl 3-nitrobenzoate In tetrahydrofuran at -78℃;
91%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

methyl 3-bromo-5-nitrobenzoate
6307-87-5

methyl 3-bromo-5-nitrobenzoate

Conditions
ConditionsYield
With sulfuric acid; dibromoisocyanuric acid90%
With sulfuric acid; dibromoisocyanuric acid at 20℃; for 2h;86%
With sulfuric acid; dibromoisocyanuric acid at 20℃; for 2h; Inert atmosphere; Schlenk technique;86%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

5-nitrosalicylic acid
96-97-9

5-nitrosalicylic acid

Conditions
ConditionsYield
With potassium hydroxide; Cumene hydroperoxide In ammonia at -33℃;90%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

propan-1-ol-3-amine
156-87-6

propan-1-ol-3-amine

N-(3-Hydroxypropyl)-3-nitrobenzamide
254454-76-7

N-(3-Hydroxypropyl)-3-nitrobenzamide

Conditions
ConditionsYield
In toluene at 94℃; for 3.5h; Acylation;90%
methyl 3-nitrobenzoate
618-95-1

methyl 3-nitrobenzoate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

3-nitro-benzoic acid t-butyl ester
58656-99-8

3-nitro-benzoic acid t-butyl ester

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane for 1h;89%

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