104636-53-5

Basic information

• Product Name: 1-phenyl-9H-carbazole
• Synonyms: 1-phenyl-9H-carbazole
• CAS NO: 104636-53-5
• Molecular Weight: 243.308
• Mol File: 104636-53-5.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: 1-phenyl-9H-carbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-9H-carbazole(104636-53-5)
• EPA Substance Registry System: 1-phenyl-9H-carbazole(104636-53-5)

Safety Data

• Hazardous Substances Data: 104636-53-5(Hazardous Substances Data)

Usage

General Description

1-phenyl-9H-carbazole, also known as 9-phenylcarbazole, is an organic compound with the chemical formula C18H13N. It is a polycyclic aromatic hydrocarbon and a derivative of carbazole. 1-phenyl-9H-carbazole is often used as a building block in the synthesis of organic semiconductors for applications in the field of optoelectronics. It has also been studied for its potential use in photovoltaic devices and organic light-emitting diodes (OLEDs). Additionally, 1-phenyl-9H-carbazole has shown promise in the field of medicinal chemistry, with research indicating its potential as an anti-cancer agent and its ability to modulate the immune system.

Upstream product

• 34177-06-5 1-phenyl-2,3,4,9-tetrahydro-1H-carbazole 
• 887651-43-6 (9H-carbazol-9-yl)diphenylphosphine oxide 
• 144930-50-7 mesityl(phenyl)iodonium triflouromethanesulfonate 
• 877764-42-6 2,6-(diphenyl)phenyl azide 
• 135554-03-9 2-(1-phenyl-vinyl)-1H-indole 
• 100-58-3 phenylmagnesium bromide 
• 145912-72-7 3-((4'-N,O-dimethyl hydroxyamido)-butan)-indole 
• 133-32-4 4-indol-3-yl-butyric acid 
• 1429926-47-5 (±)-4-(indol-3-yl)-1-phenylbutan-1-ol 
• 4360-63-8 2-bromomethyl-1,3-dioxolane 
• 120-72-9 indole 
• 98-86-2 acetophenone 
• 16807-11-7 1-bromo-9H-carbazole 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

A 1,2-Addition Pathway for C(sp2)?H Activation at a Dinickel Imide

A dinickel imido complex was synthesized using a redox-active naphthyridine-diimine supporting ligand. Upon coordination of an external ligand, the Ni2 core was disrupted, triggering an aromatic C?H activation reaction to generate a Ni2(μ-NHAr)(Ar) species. This intermediate is capable of liberating free carbazole and phenanthridine products upon heating or treatment with excess tBuNC. Collectively, these studies establish a kinetically facile 1,2-addition mechanism for C(sp2)?H activation, taking advantage of cooperative reactivity between two Ni centers.

Bismuth(III) Triflate Catalyzed Three-Component Reactions of Indoles, Ketones, and α-Bromoacetaldehyde Acetals Enable Indole-to-Carbazole Transformation

A three-component reaction of indoles, α-bromoacetaldehyde acetals, and ketones was developed by using bismuth(III) triflate as the catalyst to realize a straightforward approach for synthesizing carbazole derivatives. The reaction was established mechanistically through the autotandem catalysis of Bi(OTf)3 in the following two steps: (i) Friedel-Crafts-type alkylation of indole with α-bromoacetaldehyde acetal, which produced a tryptaldehyde-type intermediate and (ii) [4 + 2] annulation of this intermediate with the ketone component.

Temporary (P=O) directing group enabled carbazoleorthoarylationviapalladium catalysis

A palladium-catalyzed, temporary P(O) directing group assisted C-H bond arylation of carbazoles was achieved. The release of the directing group occurs spontaneously in the reaction and the mechanistic studies indicate that acid is essential for N-P bond cleavage.

A PLURALITY OF HOST MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME

The present disclosure relates to a plurality of host materials comprising a first host material comprising a compound represented by formula 1, and a second host material comprising a compound represented by formula 2, and an organic electroluminescent device comprising the same. By comprising a specific combination of compounds as host materials, it is possible to provide an organic electroluminescent device having lower driving voltage, higher luminous efficiency, higher power efficiency, and/or superior lifespan characteristics compared to conventional organic electroluminescent devices.

PLURALITY OF HOST MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME

The present disclosure relates to a plurality of host materials comprising a first host material comprising a compound represented by formula 1, and a second host material comprising a compound represented by formula 2, and an organic electroluminescent device comprising the same. By comprising a specific combination of compounds as host materials, it is possible to provide an organic electroluminescent device having higher luminous efficiency, higher power efficiency, and/or better lifetime properties, compared to conventional organic electroluminescent devices.