105849-85-2

Basic information

• Product Name: 2H-1-BENZOPYRAN, 7-METHOXY-3-NITRO-2-PHENYL-
• Synonyms: 2H-1-BENZOPYRAN, 7-METHOXY-3-NITRO-2-PHENYL-
• CAS NO: 105849-85-2
• Molecular Formula: C₁₆H₁₃NO₄
• Molecular Weight: 0
• Mol File: 105849-85-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-1-BENZOPYRAN, 7-METHOXY-3-NITRO-2-PHENYL-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1-BENZOPYRAN, 7-METHOXY-3-NITRO-2-PHENYL-(105849-85-2)
• EPA Substance Registry System: 2H-1-BENZOPYRAN, 7-METHOXY-3-NITRO-2-PHENYL-(105849-85-2)

Safety Data

• Hazardous Substances Data: 105849-85-2(Hazardous Substances Data)

Upstream product

• 673-22-3 2-Hydroxy-4-methoxybenzaldehyde 
• 102-96-5 (2-nitroethenyl)benzene 
• 5153-67-3 nitrostyrene 
• 100-52-7 benzaldehyde 

Downstream Products

• 7478-60-6 7-methoxyflavonol 
• 105849-83-0 7-Methoxy-2-phenyl-chroman-3-one 
• 113495-55-9 7-methoxy-3-nitro-2-phenylchroman 
• 113495-55-9 (2R,3R)-7-Methoxy-3-nitro-2-phenyl-chroman 
• 1162662-43-2 (R)-7-methoxy-3-nitro-2-phenyl-2H-chromene 
• 1132763-87-1 (S)-7-methoxy-3-nitro-2-phenyl-2H-chromene 
• 1227402-19-8 diethyl 7-methoxy-3,4-diphenyl-3a-nitrobenzopyrano[3.4-c]pyrrolidine-1,1-dicarboxylate 
• 1248412-04-5 3-methoxy-7-amino-6,9-diphenyl-6H-dibenzo[b,d]pyran-8-carbonitirle 
• 1438276-65-3 (6S,6aR,10aR)-7-amino-3-methoxy-10-methyl-6a-nitro-6,9-diphenyl-6a,10a-dihydro-6H-benzo[c]chromene-8-carbonitrile 
• 1438276-81-3 (6S,6aR,10aR)-7-imino-3-methoxy-10-methyl-6a-nitro-6,9-diphenyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromene-8-carbonitrile 
• 1438276-93-7 (S)-7-amino-3-methoxy-6,9-diphenyl-6H-benzo[c]chromene-8-carbonitrile 

Relevant articles and documents

One pot, three component synthesis of spiroindenoquinoxaline pyrrolidine fused nitrochromene derivatives following 1,3-dipolar cycloaddition

An expedient one-pot sequential three-component synthesis of a series of diverse spiroindenoquinoxaline pyrrolidine fused nitrochromene derivatives following 1,3-dipolar cycloaddition of azomethine ylides generated in situ by the condensation of indenoqui

Bifunctional acid-base ionic liquid for the one-pot synthesis of fine chemicals: Thioethers, 2H-chromenes and 2H-quinoline derivatives

A bifunctional organocatalyst with ionic liquid properties and with an optimized distance between the acid and basic sites efficiently activates electron deficient olefins for 1,4 conjugated addition, which can be incorporated in different one-pot transformations for the preparation of cyclic and acyclic compounds of biological and synthetic interest. More specifically, the catalyst can be successfully applied for different carbon-carbon (CC) and carbon-heteroatom (C-N, C-O, C-S) bond forming reactions integrated in a cascade sequence. The activity of the organocatalyst has been compared with that of structurally related monofunctional and bifunctional catalysts. The most attractive features of this procedure are the high atom economy and the use of inexpensive starting materials as well as the use of an environmentally friendly catalyst that can be easily recovered due to its ionic liquid properties.

A NOVEL SYNTHESIS OF 6-METHOXY AND 7-METHOXY FLAVONOLS

Condensation of 4-methoxy- (1) or 5-methoxy- (2) salicylaldehyde with ω-nitrostyrene (3-6) in the presence of triethylamine yields 7-methoxy or 6-methoxy-3-nitro-2H-flavene (7-13), which on treatment with alkaline hydrogen peroxide yields the correspondin