114234-09-2 Usage
Description
2,4-BIS(P-TOLYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE is a complex organic compound with the chemical formula C16H14O2PS4. It is characterized by its unique structure, which includes two p-tolylthio groups, a 1,3-dithia-2,4-diphosphetane core, and a disulfide bridge. 2,4-BIS(P-TOLYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE is known for its potential applications in various industries due to its chemical properties.
Uses
Used in Agricultural Industry:
2,4-BIS(P-TOLYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE is used as an intermediate compound in the preparation of (Cyclohexyl)pyridine Carboxamides. These carboxamides are known for their herbicidal properties, making them valuable in the development of effective herbicides for controlling weed growth in agricultural settings. The compound's role in the synthesis process contributes to the overall effectiveness of the final herbicide product, helping to improve crop yields and reduce the need for manual weed control methods.
Purification Methods
Recrystallise it from toluene (light yellow solid), wash it with Et2O and dry in vacuo. [Jennt & Heimgarter Helv Chim Acta 70 1001 1987.]
Check Digit Verification of cas no
The CAS Registry Mumber 114234-09-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,2,3 and 4 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 114234-09:
(8*1)+(7*1)+(6*4)+(5*2)+(4*3)+(3*4)+(2*0)+(1*9)=82
82 % 10 = 2
So 114234-09-2 is a valid CAS Registry Number.
InChI:InChI=1/C14H14P2S6/c1-11-3-7-13(8-4-11)19-15(17)21-16(18,22-15)20-14-9-5-12(2)6-10-14/h3-10H,1-2H3
114234-09-2Relevant articles and documents
2,4-Bis(4-methylphenylthio)-1,3,2λ5,4λ5-dithiadiphosphetane-2,4-dithione: A New Reagent for Thiation of N,N-Disubstituted Amides
Wipf, Peter,Jenny, Christjohannes,Heimgartner, Heinz
, p. 1001 - 1011 (2007/10/02)
As a new reagent for the thiation of amides, the easily accessible 2,4-bis(4-methylphenylthio)-1,3,2λ5,4λ5-dithiadiphosphetane-2,4-dithione (9) shows a remarkable selectivity.This selectivity - the preferred thiation of N,N-disubstituted amides - is complementary to the one of the well known Lawesson reagent.Thiation of diamides of type 2 with 9 leads via cyclization of the corresponding dithiodiamides directly to 1,3-thiazole-5(4H)-thiones 1.