114971-52-7 Usage
Description
Benzyltrimethylammonium dichloroiodate is a chemical compound with the formula (C6H5CH2N(CH3)3)ICl2. It is a slightly brown solid that is hygroscopic, meaning it has the ability to absorb moisture from the environment. Benzyltrimethylammonium dichloroiodate is known for its role in the mechanism of oxidation.
Uses
Used in Chemical Synthesis:
Benzyltrimethylammonium dichloroiodate is used as an oxidizing agent in various chemical reactions. Its application is primarily due to its ability to facilitate the transfer of electrons, which is a key process in oxidation reactions.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Benzyltrimethylammonium dichloroiodate is used as a catalyst for specific chemical transformations. Its role is to increase the rate of reactions, making the synthesis of certain pharmaceutical compounds more efficient and cost-effective.
Used in Research and Development:
Benzyltrimethylammonium dichloroiodate is also utilized in research and development settings, where it is employed to study the mechanisms of oxidation and to develop new oxidation processes for various applications.
Used in Analytical Chemistry:
In analytical chemistry, Benzyltrimethylammonium dichloroiodate is used as a reagent for the detection and quantification of certain substances. Its unique chemical properties make it a valuable tool for identifying and measuring specific compounds in complex mixtures.
Overall, Benzyltrimethylammonium dichloroiodate is a versatile compound with a range of applications across different industries, primarily due to its role in oxidation processes and its ability to act as a catalyst or reagent in various chemical reactions.
Health Hazard
Exposures to benzyltrimethylammonium dichloroiodate cause irritation to the eyes, skin,
and respiratory tract. Accidental ingestion causes gastrointestinal irritation with nausea,
vomiting, and diarrhea. Sparse information on chronic toxicity is available in literature
Check Digit Verification of cas no
The CAS Registry Mumber 114971-52-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,9,7 and 1 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 114971-52:
(8*1)+(7*1)+(6*4)+(5*9)+(4*7)+(3*1)+(2*5)+(1*2)=127
127 % 10 = 7
So 114971-52-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H16N.Cl2I/c1-11(2,3)9-10-7-5-4-6-8-10;1-3-2/h4-8H,9H2,1-3H3;/q+1;-1
114971-52-7Relevant articles and documents
Light-induced stereospecific intramolecular [2+2]-cycloaddition of atropisomeric 3,4-dihydro-2-pyridones
Kumarasamy, Elango,Sivaguru
supporting information, p. 4346 - 4348 (2013/06/27)
Atropisomeric 3,4-dihydro-2-pyridones undergo stereospecific [2+2]-photocycloaddition in solution with high stereoselectivity (ee > 98% and de > 96%) in the product. The chiral transfer during phototransformation was rationalized based on the stability/reactivity of the biradical.
Facile Synthesis of Chloro-substituted Aromatic Ethers by Use of Benzyltrimethylammonium Tetrachloroiodate
Kajigaeshi, Shoji,Shinmasu, Youichi,Fujisaki, Shizuo,Kakinami, Takaaki
, p. 415 - 418 (2007/10/02)
The reaction of aromatic ethers with a calculated amount of benzyltrimethylammonium tetrachloroiodate in acetic acid (or dichloromethane) under mild conditions gave, selectively, the objective chloro-substituted aromatic ethers in good yields.
α-Chlorination of Aromatic Acetyl Derivatives with Benzyltrimethylammonium Dichloroiodate
Kajigaeshi, Shoji,Kakinami, Takaaki,Moriwaki, Masayuki,Fujisaki, Shizuo,Maeno, Kimihiro,Okamoto, Tsuyoshi
, p. 545 - 546 (2007/10/02)
Reaction of aromatic acetyl derivatives with benzyltrimethylammonium dichloroiodate in refluxing dichloroethane/methanol for several hours gave α-chloroacetyl derivatives in good yields.