1152313-78-4

Basic information

• Product Name: (S)-2-(2-bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole
• Synonyms: (S)-2-(2-bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole
• CAS NO: 1152313-78-4
• Molecular Weight: 296.207
• Mol File: 1152313-78-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-2-(2-bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(2-bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole(1152313-78-4)
• EPA Substance Registry System: (S)-2-(2-bromophenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole(1152313-78-4)

Safety Data

• Hazardous Substances Data: 1152313-78-4(Hazardous Substances Data)

Upstream product

• 7154-66-7 2-bromobenzoic acid chloride 
• 163453-95-0 (S)-3-amino-2,4-dimethylpentan-2-ol 
• 157035-77-3 tert-butyl (S)-(2-hydroxy-2,4-dimethylpentan-3-yl)carbamate 
• 6306-52-1 L-valine methylester hydrochloride 
• 58561-04-9 N-tert-butoxycarbonyl-L-valine methyl ester 
• 72-18-4 L-valine 
• 1152313-77-3 (S)-2-bromo-N-(2-hydroxy-2,4-dimethylpentan-3-yl)benzamide 

Downstream Products

• 1152313-76-2 (4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole 

Relevant articles and documents

Synthesis of Bis(oxazoline) Ligands Possessing C-5 gem-Disubstitution and Their Application in Asymmetric Friedel-Crafts Alkylations

A series of eight novel bis(oxazoline) ligands incorporating gem-disubstitution on one of the oxazoline rings were prepared from (S)-valine. These ligands are designed as a cost-effective alternative to similar ligands possessing an oxazolinyl C(5)-tert-b

Use of 5,5-(dimethyl)-i-Pr-PHOX as a practical equivalent to t-Bu-PHOX in asymmetric catalysis

The use of 5,5-(dimethyl)-i-Pr-PHOX as a practical equivalent of t-Bu-PHOX in asymmetric catalysis is reported. This new member of the phosphinooxazoline (PHOX) ligand family behaves similarly in terms of stereoinduction to t-Bu-PHOX with the key advantage of being readily accessible as both enantiomers starting from either(S)- or (R)-valine.