122920-70-1

Basic information

• Product Name: (E)-1,1,1-trifluoro-4-phenylbut-3-en-2-yl acetate
• Synonyms: (E)-1,1,1-trifluoro-4-phenylbut-3-en-2-yl acetate
• CAS NO: 122920-70-1
• Molecular Weight: 244.213
• Mol File: 122920-70-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1,1,1-trifluoro-4-phenylbut-3-en-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,1,1-trifluoro-4-phenylbut-3-en-2-yl acetate(122920-70-1)
• EPA Substance Registry System: (E)-1,1,1-trifluoro-4-phenylbut-3-en-2-yl acetate(122920-70-1)

Safety Data

• Hazardous Substances Data: 122920-70-1(Hazardous Substances Data)

Upstream product

• 5739-38-8 1-(4-methoxyphenyl)-3-phenylpropan-1-one 
• 536-74-3 phenylacetylene 
• 89524-12-9 1-phenyl-3-hydroxy-4,4,4-trifluoro-1-butyne 
• 80768-54-3 (+/-)-E-1,1,1-trifluoro-4-phenylbut-3-en-2-ol 
• 75-36-5 acetyl chloride 

Downstream Products

• 108644-85-5 (E)-(R)-1,1,1-trifluoro-4-phenyl-3-buten-2-ol 
• 111004-15-0 (E)-(S)-1,1,1-trifluoro-4-phenyl-3-buten-2-ol 
• 108644-83-3 (R)-(+)-1,1,1-trifluoro-4-phenyl-2-butanol 
• 111004-16-1 (2S)-1,1,1-trifluoro-4-phenylbutan-2-ol 
• 1023641-85-1 C₁₄H₁₆F₃NO 
• 1023641-73-7 (E)-4-(4,4,4-trifluoro-1-phenylbut-2-en-1-yl)morpholine 
• 1023641-77-1 C₁₅H₂₀F₃N 
• 1023641-89-5 C₁₅H₂₀F₃N 
• 1023641-75-9 C₁₈H₂₆F₃N 
• 1023641-87-3 C₁₈H₂₆F₃N 
• 1023641-69-1 C₁₄H₁₈F₃N 
• 1023641-71-5 C₁₄H₁₈F₃N 
• 1023641-79-3 C₁₄H₁₈F₃N 
• 1023641-91-9 C₁₄H₁₈F₃N 

Relevant articles and documents

Palladium-Catalyzed Asymmetric Trifluoromethylated Allylic Alkylation of Pyrazolones Enabled by α-(Trifluoromethyl)alkenyl Acetates

The first asymmetric trifluoromethylated allylic alkylation of pyrazolones using α-(trifluoromethyl)alkenyl acetates as a novel trifluoromethylated allylation reagent is described, affording various functionalized chiral pyrazolones containing a trifluoromethylated allyl substituent in high yields with excellent regio-/enantio-/diastereoselectivities. Mechanistically, the double-bond migration of α-(trifluoromethyl)alkenyl acetates in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene is initial and interesting step. More importantly, this study is of significance in providing a novel and widely applicable trifluoromethyl-containing allylation reagent.