132515-10-7Relevant articles and documents
BVMO-catalysed dynamic kinetic resolution of racemic benzyl ketones in the presence of anion exchange resins
Rodriguez, Cristina,De Gonzalo, Gonzalo,Rioz-Martinez, Ana,Torres Pazmino, Daniel E.,Fraaije, Marco W.,Gotor, Vicente
experimental part, p. 1121 - 1125 (2010/06/20)
4-Hydroxyacetophenone monooxygenase from Pseudomonas fluorescens ACB was employed in the presence of a weak anion exchange resin to perform dynamic kinetic resolutions of racemic benzyl ketones with high conversions and good optical purities. Different parameters that affect to the efficiency of the enzymatic Baeyer-Villiger oxidation and racemisation were analyzed in order to optimize the activity and selectivity of the biocatalytic system. The Royal Society of Chemistry.
Electroreductive Acylation of Benzyl Chlorides with Acid Anhydrides. Stereoselective Formation of (E)-Enol Esters from Benzyl Alkyl Ketones
Nishiguchi, Ikuzo,Oki, Tsuneo,Hirashima, Tsuneaki,Shiokawa, Jiro
, p. 2005 - 2008 (2007/10/02)
Electroreduction of benzyl chlorides in the presence of acid anhydrides brought about stereoselective formation of (E)-enol esters of the corresponding benzyl alkyl ketones, the initial acylated products, in good to moderate yields.