138490-37-6

Basic information

• Product Name: (±)-1-cyclohexyl-2-methylprop-2-en-1-ol
• Synonyms: (±)-1-cyclohexyl-2-methylprop-2-en-1-ol
• CAS NO: 138490-37-6
• Molecular Weight: 154.252
• Mol File: 138490-37-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (±)-1-cyclohexyl-2-methylprop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-1-cyclohexyl-2-methylprop-2-en-1-ol(138490-37-6)
• EPA Substance Registry System: (±)-1-cyclohexyl-2-methylprop-2-en-1-ol(138490-37-6)

Safety Data

• Hazardous Substances Data: 138490-37-6(Hazardous Substances Data)

Upstream product

• 78-85-3 2-methylpropenal 
• 931-50-0 cyclohexylmagnesium bromide 
• 13291-18-4 isopropenylmagnesium bromide 
• 2043-61-0 cyclohexanecarbaldehyde 
• 557-93-7 2-bromoprop-1-ene 
• 97563-45-6 1-cyclohexylprop-2-yn-1-ol 
• 75-16-1 methylmagnesium bromide 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 138490-38-7 (+/-)-3-(tert-butyldimethylsilyloxy)-3-cyclohexyl-2-methyl-1-propene 
• 852235-24-6 [1-cyclohexyl-2-methyl-2-propenyl] acrylate 
• 191169-56-9 (1R,2S)-1-Cyclohexyl-3-diphenylphosphinoyl-2-methylpropane-1,2-diol 
• 197244-60-3 (E)-1-Cyclohexyl-3-diphenylphosphinoyl-2-methylprop-1-ene 
• 105401-07-8 (1R,2S)-1-cyclohexyl-2-methyl-1,3-propanediol 
• 135067-18-4 (1R*,2S*)-1-cyclohexyl-2-methyl-1,3-bis(trimethylsiloxy)propane 
• 78604-73-6 (-)-methyl (2R,3R)-3-cyclohexyl-3-hydroxy-2-methylpropionate 
• 138490-51-4 (2R,3R)-3-cyclohexyl-3-hydroxy-2-methylpropanal 
• 138490-39-8 (2S*,3R*)-3-(tert-butyldimethylsilyloxy)-3-cyclohexyl-2-methylpropanol 
• 138603-03-9 (2R,3R)-3-Cyclohexyl-3-hydroxy-2-methyl-propionic acid 
• 138602-95-6 (1R*,2S*)-1-cyclohexyl-2-methyl-1,3-propanediol 
• 138604-11-2 (2R,3S,6S,7S,10R)-2-Cyclohexyl-7-isopropyl-3,10-dimethyl-1,5-dioxa-spiro[5.5]undecane 
• 138490-36-5 (2S,3R,6R,7S,10R)-2-Cyclohexyl-7-isopropyl-3,10-dimethyl-1,5-dioxa-spiro[5.5]undecane 
• 1071068-26-2 (E)-5-Cyclohexyl-4-methyl-pent-4-enoic acid ethyl ester 

Relevant articles and documents

Electrochemical Nozaki-Hiyama-Kishi Coupling: Scope, Applications, and Mechanism

One of the most oft-employed methods for C-C bond formation involving the coupling of vinyl-halides with aldehydes catalyzed by Ni and Cr (Nozaki-Hiyama-Kishi, NHK) has been rendered more practical using an electroreductive manifold. Although early studies pointed to the feasibility of such a process, those precedents were never applied by others due to cumbersome setups and limited scope. Here we show that a carefully optimized electroreductive procedure can enable a more sustainable approach to NHK, even in an asymmetric fashion on highly complex medicinally relevant systems. The e-NHK can even enable non-canonical substrate classes, such as redox-active esters, to participate with low loadings of Cr when conventional chemical techniques fail. A combination of detailed kinetics, cyclic voltammetry, and in situ UV-vis spectroelectrochemistry of these processes illuminates the subtle features of this mechanistically intricate process.

ALDEHYDES AS PERFUMING INGREDIENTS

The present invention relates to an aldehyde of formula (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein each dotted line, independently from each other, represents a single or double bond; n is 0 or 1; R1 repre

Stereoselective synthesis of cis-β-methyl- and phenyl-substituted alkenylboronates by platinum-catalyzed dehydrogenative borylation

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