140630-39-3

Basic information

• Product Name: 2-Propanol, 1-bromo-3-phenoxy-, (S)-
• CAS NO: 140630-39-3
• Molecular Formula: C9H11BrO2
• Molecular Weight: 231.089
• Mol File: 140630-39-3.mol
• Article Data: 47

Chemical Properties

• CAS DataBase Reference: 2-Propanol, 1-bromo-3-phenoxy-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanol, 1-bromo-3-phenoxy-, (S)-(140630-39-3)
• EPA Substance Registry System: 2-Propanol, 1-bromo-3-phenoxy-, (S)-(140630-39-3)

Safety Data

• Hazardous Substances Data: 140630-39-3(Hazardous Substances Data)

Upstream product

• 3132-64-7 1,2-Epoxy-3-bromopropane 
• 108-95-2 phenol 
• 142072-04-6 Benzoic acid 1-bromomethyl-2-phenoxy-ethyl ester 
• 122-60-1 Phenyl glycidyl ether 
• 925-90-6 ethylmagnesium bromide 
• 95-56-7 2-hydroxybromobenzene 
• 868-26-8 dimethyl 2-bromomalonate 
• 140428-47-3 Acetic acid 1-bromomethyl-2-phenoxy-ethyl ester 
• 82430-38-4 (S)-1-phenyl glycerol 
• 123-20-6 vinyl n-butyrate 
• 140428-44-0 1-bromo-3-phenoxy-propan-2-ol 
• 2930-05-4 Benzyloxymethyl-oxiran 
• 1746-13-0 allyl phenyl ether 
• 538-43-2 3-phenoxy-1,2-propanediol 

Downstream Products

• 140630-35-9 (R)-3-bromo-1-phenoxy-2-propanol 
• 71031-03-3 (2R)-1,2-epoxy-3-phenoxypropane 
• 133522-40-4 (R)-(-)-1-amino-3-phenyloxy-2-propanol 
• 140630-43-9 (2R)-1-Isopropylamino-3-phenoxy-2-propanol 
• 4437-83-6 4-(phenoxy)methyl-1,3-dioxolane-2-one 
• 96-21-9 1,3-dibromo-2-hydroxypropane 
• 635320-91-1 1-benzyl-2-imino-3-(2-hydroxy-3-phenoxypropyl)benzimidazole hydrobromide 
• 84137-77-9 1-phenoxy-3-(phenylthio)propan-2-ol 
• 140630-40-6 Acetic acid (R)-1-bromomethyl-2-phenoxy-ethyl ester 
• 140630-36-0 Acetic acid (S)-1-bromomethyl-2-phenoxy-ethyl ester 

Relevant articles and documents

A facile conversion of epoxides to β-halohydrins with silica gel-supported lithium halides

A variety of epoxides are efficiently converted to the corresponding β-halohydrins with lithium halides supported on silica gel in dry media.

Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts

Preparation of vicinal halohydrins, in which copper or iron chlorides catalyze the ring-opening reaction of epoxides with visible light effectively, is described. The use of trichloroacetonitrile as a halogen source enables catalytic HCl generation under the mild conditions. This method can also be applied to the aziridine ring-opening reaction.

Trihaloisocyanuric Acid/Triphenylphosphine: An Efficient System for Regioselective Conversion of Epoxides into Vicinal Halohydrins and Vicinal Dihalides under Mild Conditions

A new synthetic method has been developed for the regioselective conversion of epoxides to vicinal chloro-/bromohydrins and vicinal dihalides by reaction with the system trihaloisocyanuric acid/tri?phenylphosphine in acetonitrile under mild and neutral conditions. The reactions proceed smoothly in high yield at room temperature and at reflux, respectively, over a short time.