1504-54-7

Basic information

• Product Name: (E)-3-PHENYL-BUT-2-EN-1-OL
• Synonyms: (E)-3-PHENYL-BUT-2-EN-1-OL;(E)-3-Phenyl-but-2-en-ol;3-Phenyl-2-buten-1-ol
• CAS NO: 1504-54-7
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.20168
• Mol File: 1504-54-7.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 228.81°C (rough estimate)
• Flash Point: 118.7°C
• Appearance: /
• Density: 1.0350
• Refractive Index: 1.5678
• PKA: 14.63±0.10(Predicted)
• CAS DataBase Reference: (E)-3-PHENYL-BUT-2-EN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-PHENYL-BUT-2-EN-1-OL(1504-54-7)
• EPA Substance Registry System: (E)-3-PHENYL-BUT-2-EN-1-OL(1504-54-7)

Safety Data

• Hazardous Substances Data: 1504-54-7(Hazardous Substances Data)

Usage

General Description

(E)-3-Phenyl-but-2-en-1-ol is a chemical compound with the molecular formula C10H12O. It is a colorless liquid with a sweet, floral odor. (E)-3-PHENYL-BUT-2-EN-1-OL is commonly used in the fragrance and flavor industry, as well as in the production of various chemicals. It is also utilized in the synthesis of pharmaceuticals and as a starting material for the preparation of other organic compounds. Additionally, (E)-3-Phenyl-but-2-en-1-ol has been studied for its potential biological activities, including its antimicrobial and antioxidant properties. Overall, this chemical compound has a wide range of applications and has been the subject of scientific research for its various properties and potential uses.

InChI:InChI=1/C10H12O/c1-9(7-8-11)10-5-3-2-4-6-10/h2-7,11H,8H2,1H3/b9-7+

Upstream product

• 20883-16-3 1-acetoxy-3-phenylbut-2-ene 
• 945-93-7 ethyl (E)-3-phenylbut-2-enoate 
• 1504-72-9 ethyl 3-phenylbut-2-enoate 
• 1196-67-4 3-phenyl-2-butenal 
• 6051-52-1 2-phenylbut-3-en-2-ol 
• 7664-93-9 sulfuric acid 
• 50-00-0 formaldehyd 
• 98-83-9 isopropenylbenzene 
• 98-86-2 acetophenone 
• 2293-60-9 ethyl 3-hydroxy-3-phenylbutyrate 
• 19352-10-4 2-methyl-2-phenyloxetane 
• 704-79-0 3-phenylbut-2-enoic acid 
• 20718-17-6 2-(dimethyl(oxo)-λ⁶-sulfaneylidene)-1-phenylethan-1-one 
• 3174-83-2 3-phenylbut-3-en-1-ol 

Downstream Products

• 1196-67-4 3-phenyl-2-butenal 
• 41314-25-4 4-chloro-1-phenyl-2-butene 
• 2722-36-3 3-phenyl-1-butanol 
• 1794-51-0 1-chloro-3-phenyl-2-butene 
• 39171-59-0 (4-bromobut-2-en-2-yl)benzene 
• 138313-57-2 2,2,2-Trichlorethanimidsaeure-O-(3-phenyl-2-butenyl)ester 
• 103988-22-3 3-Phenyl-buten-⁽²⁾-yl-formiat 
• 107475-99-0 ethyl-(3-phenyl-but-2-enyl)-ether 
• 102553-04-8 Bis-<3-phenyl-buten-(2)-yl-(1)>-ether 
• 171083-61-7 4-methyl-4-phenylhex-5-en-2-one 
• 663919-81-1 ethyl 3-methyl-3-phenylpent-4-enoate 
• 663919-50-4 4-methyl-4-phenyl-hex-5-enoic acid methyl ester 
• 36920-29-3 4-methyl-4-phenylcyclopent-2-en-1-one 
• 144632-53-1 2-methyl-4-oxo-2-phenylpentanal 

Relevant articles and documents

Stereoselective reductions of N-Boc-hexahydro-1H-indolin-5(6H)-ones

We report the divergent effects of a 3a-methyl and 3a-phenyl substituent on the chemoselectivity and stereoselectivity of reduction of the enamide moiety of N-Boc-hexahydro-1H-indolin-5(6H)-ones. Under ionic reduction conditions (triethylsilane/trifluoroacetic acid) the enamide group of 3a-methyl-N-Boc-hexahydro-1H-indolin-5(6H)-one was reduced to afford exclusively a cis ring-fused product. For the 3a-phenyl substituted analogue more forcing conditions (sodium cyanoborohydride at pH 2-2.5) were required and resulted in the selective reduction of the enamide group to give a trans ring-fused product as well as reduction of the ketone group.

A Mechanistically Inspired Halenium Ion Initiated Spiroketalization: Entry to Mono- and Dibromospiroketals

Employing halenium affinity (HalA) as a guiding tool, the weak nucleophilic character of alkyl ketones was modulated by the templating effect of a tethered 2-tetrahydropyranyl(THP)-protected alcohol towards realizing a bromenium ion initiated spiroketaliz

Catalytic Asymmetric Allylic Substitution with Copper(I) Homoenolates Generated from Cyclopropanols

By using copper(I) homoenolates as nucleophiles, which are generated through the ring-opening of 1-substituted cyclopropane-1-ols, a catalytic asymmetric allylic substitution with allyl phosphates is achieved in high to excellent yields with high enantioselectivity. Both 1-substituted cyclopropane-1-ols and allylic phosphates enjoy broad substrate scopes. Remarkably, various functional groups, such as ether, ester, tosylate, imide, alcohol, nitro, and carbamate are well tolerated. Moreover, the present method is nicely extended to the asymmetric construction of quaternary carbon centers. Some control experiments argue against a radical-based reaction mechanism and a catalytic cycle based on a two-electron process is proposed. Finally, the synthetic utilities of the product are showcased by means of the transformations of the terminal olefin group and the ketone group.