1530-11-6

Basic information

• Product Name: Benzene, 1,1'-(1-pentenylidene)bis-
• CAS NO: 1530-11-6
• Molecular Formula: C17H18
• Molecular Weight: 222.33
• Mol File: 1530-11-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-pentenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-pentenylidene)bis-(1530-11-6)
• EPA Substance Registry System: Benzene, 1,1'-(1-pentenylidene)bis-(1530-11-6)

Safety Data

• Hazardous Substances Data: 1530-11-6(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 60-29-7 diethyl ether 
• 4733-41-9 benzhydrylphenyl ether 
• 693-03-8 n-butyl magnesium bromide 
• 6317-10-8 2,2-diphenyl-1,3-dithiolane 
• 7498-88-6 4,4-diphenylbut-3-enoic acid 
• 1009-14-9 phenyl butyl ketone 
• 100-58-3 phenylmagnesium bromide 
• 79654-37-8 diphenyl(2-thienyl)methanol 
• 14799-59-8 (2-cyclopropylethene-1,1-diyl)dibenzene 
• 119-61-9 benzophenone 
• 78870-77-6 di-O-methyl butylphosphonothioate 
• 5384-63-4 1,1-diphenylpentanol 
• 539-82-2 ethyl n-valerate 

Downstream Products

• 58607-49-1 1-(3-hydroxy-3,3-diphenylpropyl)cyclohexanol 
• 91-01-0 1,1-Diphenylmethanol 
• 1454679-91-4 1,1,4-triphenylbutane-1,4-diol 
• 5449-47-8 4-methyl-1,1-diphenylpentan-1-ol 
• 55766-18-2 3-cyclohexyl-1,1-diphenylpropan-1-ol 
• 31067-15-9 1,1,4-triphenyl-1-butanol 
• 119-61-9 benzophenone 
• 5194-35-4 1,1-diphenylpentane-1,4-diol 
• 1454679-77-6 1,1,4-triphenylbutyl-1-hydroperoxide 
• 1454679-89-0 4-methyl-1,1-diphenylpentylhydroperoxide 
• 1454679-87-8 3-cyclohexyl-1,1-diphenylpropylhydroperoxide 
• 5194-36-5 4-methyl-1,1-diphenylpentane-1,4-diol 
• 1418731-60-8 (R)-α-propyl deoxybenzoin 
• 21383-02-8 α-propyl deoxybenzoin 

Relevant articles and documents

Novel Coupling of Dithioacetals with Grignard Reagents

Dithioacetals react with Grignard reagents in the presence of a catalytic amount of to give the corresponding olefinic coupling products in good yields: a mechanism for the reaction is suggested.

Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.

Ruthenium(II)-catalyzed olefination: Via carbonyl reductive cross-coupling

Natural availability of carbonyl groups offers reductive carbonyl coupling tremendous synthetic potential for efficient olefin synthesis, yet the catalytic carbonyl cross-coupling remains largely elusive. We report herein such a reaction, mediated by hydrazine under ruthenium(ii) catalysis. This method enables facile and selective cross-couplings of two unsymmetrical carbonyl compounds in either an intermolecular or intramolecular fashion. Moreover, this chemistry accommodates a variety of substrates, proceeds under mild reaction conditions with good functional group tolerance, and generates stoichiometric benign byproducts. Importantly, the coexistence of KOtBu and bidentate phosphine dmpe is vital to this transformation.