1613-90-7Relevant articles and documents
Direct synthesis of imines from gem-dibromomethylaryl derivatives: Application to unsymmetrically substituted bipyridine frameworks
Weibel, Nicolas,Charbonniere, Loic J.,Ziessel, Raymond F.
, p. 7876 - 7879 (2002)
An efficient methodology for the one-pot synthesis of imines is described starting from gem-dibromomethylaryl compounds and primary amines. The synthesis was applied to various aliphatic mono- and polyamines as well as to electron-rich anilines. The proto
Sulfur-stabilised copper nanoparticles for the aerobic oxidation of amines to imines under ambient conditions
Martín-García, Iris,Díaz-Reyes, Gloria,Sloan, George,Moglie, Yanina,Alonso, Francisco
supporting information, p. 11312 - 11322 (2021/05/19)
The stabilisation of metal nanoparticles and control of their oxidation state are crucial factors in nanocatalysis. Elemental sulfur has been found to be a cheap and effective stabilising agent for copper nanoparticles in the form of copper(i) oxide. The
Photoredox-Catalyzed Four-Component Reaction for the Synthesis of Complex Secondary Amines
Kammer, Lisa Marie,Krumb, Matthias,Spitzbarth, Benjamin,Lipp, Benjamin,Kühlborn, Jonas,Busold, Jonas,Mulina, Olga M.,Terentev, Alexander O.,Opatz, Till
supporting information, p. 3318 - 3322 (2020/03/24)
The one-pot sulfonylation/aminoalkylation of styrene derivatives furnishing substituted ?3-sulfonylamines was accomplished through a photoredox-catalyzed four-component reaction. Besides one molecule of water and the sodium counterion of the sulfinate, all atoms of the starting materials are transferred to the final product, rendering this process highly atom-efficient. The operationally simple protocol allows for the simultaneous formation of three new single bonds (C-S, C-N, and C-C) and therefore grants rapid access to structurally diverse products.