5855-65-2

Basic information

• Product Name: Quinoline, 6-methoxy-2,4-diphenyl-
• CAS NO: 5855-65-2
• Molecular Formula: C22H17NO
• Molecular Weight: 311.383
• Mol File: 5855-65-2.mol
• Article Data: 56

Chemical Properties

• CAS DataBase Reference: Quinoline, 6-methoxy-2,4-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 6-methoxy-2,4-diphenyl-(5855-65-2)
• EPA Substance Registry System: Quinoline, 6-methoxy-2,4-diphenyl-(5855-65-2)

Safety Data

• Hazardous Substances Data: 5855-65-2(Hazardous Substances Data)

Upstream product

• 5877-59-8 (E)-3-methoxy-N-(phenylmethylene)benzenamine 
• 536-74-3 phenylacetylene 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 100-52-7 benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 94-41-7 benzalacetophenone 
• 7338-94-5 1,3-diphenyl-2-propynone 
• 100-42-5 styrene 
• 17377-95-6 benzyl(4-methoxyphenyl)amine 
• 57957-24-1 N-(1-phenylvinyl)acetamide 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 120-46-7 1,3-diphenylpropanedione 

Downstream Products

• 5855-62-9 6-hydroxy-2,4-diphenylquinoline 

Relevant articles and documents

Phenanthrenequinone-Sensitized Photocatalytic Synthesis of Polysubstituted Quinolines from 2-Vinylarylimines

Visible-light-excited 9,10-phenanthrenequinone (PQ*) was used as a photocatalyst for the synthesis of polysubstituted quinolines via the electrocyclization of 2-vinylarylimines. Up to quantitative yields of 2,4-disubstituted quinolines were received after 1 h of excitation with blue LEDs at room temperature when MgCO3 was used as an additive in DCM. On the basis of experimental and DFT studies, we propose that PQ? induces one-electron oxidation of the imine substrate that triggers the electrocyclization mechanism.

Synthesis of new quinolizinium-based fluorescent compounds and studies on their applications in photocatalysis

Quinoliziniums, cationic aromatic heterocycles bearing a quaternary bridgehead nitrogen, have been widely used as fluorescent dyes, DNA intercalators, ionic liquidsetc. A library of new quinolizinium compounds was synthesized from quinolines and internal alkyne substrates in up to 65% isolated yields. Systematic studies of their photophysical properties were conducted. The quinoliziniums have been used in three visible-light-induced photocatalysis reactions with good yields.

Palladium-Catalyzed/Copper-Mediated Desulfurization and Aryl- ation of Quinoline-2-(1 H)-thione for Rapid Access to Quinoline Derivatives

An efficient method for carbon-carbon bond formation is described. The process employs the palladium-catalyzed and copper-mediated cross-coupling of quinoline-2-(1 H)-thiones with arylboronic acids or alkynes through C-S bond cleavage without an inert atm