16274-87-6Relevant articles and documents
Asymmetric microbial conversion of (E)-2-benzylideneindan-1-one by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata
Pinedo-Rivilla, Cristina,Aleu, Josefina,Collado, Isidro G.
experimental part, p. 1653 - 1657 (2012/01/30)
The transformation of (E)-2-benzylideneindan-1-one 1 by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata as biocatalysts was studied. The results showed the catalytic potential of these fungi in affording several hydroxylation a
On the baker's yeast mediated transformation of α-bromoenones. Synthesis of (1S,2R)-2-bromoindan-1-ol and (2s,3s)-3-bromo-4-phenylbutan-2- ol
Aleu, Josephina,Fronza, Giovanni,Fuganti, Claudio,Perozzo, Valentina,Serra, Stefano
, p. 1589 - 1596 (2007/10/03)
Fermenting baker's yeast converts α-bromo substituted enones 7 and 10 into enantiomerically pure (1S,2R)2-bromoindan-1-ol 3 and (2S,3S)-3-bromo-4- phenylbutan-2-ol 11, respectively, through the intermediacy of the corresponding saturated ketones. Structurally related 16 provides the (2R)- allylic alcohol 17 prevalently.
Undirectional Triple and Double Hydrogen Rearrangement Reactions in the Radical Cations of γ-Arylalkanols
Kuck, Dietmar,Filges, Ulrich
, p. 643 - 653 (2007/10/02)
A novel fragmentation reaction accompanied by the unidirectional migration of three hydrogen atom has been found in the radical cations of γ-arylpropanols with electron-donating substituents in the para position.This triple hydrogen (3H) rearrangement rea
