175158-50-6

Basic information

• Product Name: Benzaldehyde, 2-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-
• CAS NO: 175158-50-6
• Molecular Formula: C24H26O2Si
• Molecular Weight: 374.555
• Mol File: 175158-50-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-(175158-50-6)
• EPA Substance Registry System: Benzaldehyde, 2-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-(175158-50-6)

Safety Data

• Hazardous Substances Data: 175158-50-6(Hazardous Substances Data)

Upstream product

• 612-14-6 phthalyl alcohol 
• 84-66-2 Diethyl phthalate 
• 88-99-3 benzene-1,2-dicarboxylic acid 
• 149170-33-2 (2-((tert-butyldiphenylsilyloxy)methyl)phenyl)methanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 175158-51-7 [5-(tert-Butyl-dimethyl-silanyloxymethyl)-4,6,6-trimethyl-cyclohexa-1,4-dienyl]-[2-(tert-butyl-diphenyl-silanyloxymethyl)-phenyl]-methanol 
• 874672-46-5 C₂₅H₃₀O₂Si 
• 874672-44-3 C₂₈H₃₆O₂Si 
• 1345714-62-6 C₂₈H₃₂O₃Si 
• 1345714-63-7 C₂₇H₃₀O₃Si 
• 1345714-64-8 C₂₉H₃₄O₃Si 
• 1345714-65-9 C₂₅H₂₈O₂Si 
• 1345714-66-0 C₂₈H₃₄O₂Si 
• 1345714-69-3 C₁₃H₁₆O₃ 
• 1345714-73-9 isopropyl 2-formylcinnamate 
• 52753-91-0 (E)-methyl 3-(2-formylphenyl)acrylate 
• 86867-62-1 (E)-3-(2-formylphenyl)propenoic acid ethyl ester 
• 147377-67-1 (E)-ethyl 3-(2-(hydroxymethyl)phenyl)acrylate 

Relevant articles and documents

Prins spirocyclization for the synthesis of spiro[isobenzofuran-pyran] derivatives

A Prins cascade process was developed for the synthesis of tetrahydro-3H-spiro[isobenzofuran-pyran] derivatives in good yields and selectivity by the condensation of 3-[2-(hydroxymethyl)phenyl]but-3-en-1-ols with aldehydes or ketones. The reaction proceeds smoothly in the presence of indium(III) trifluoromethanesulfonate (30 mol-%) in dichloroethane at 80 C. This is the first report on the synthesis of tetrahydro-3H-spiro[isobenzofuran- pyran] scaffolds through a Prins cascade reaction. Copyright

Efficient synthesis of polysubstituted isochromanones via a novel photochemical rearrangement

A novel and convenient approach to the synthesis of polysubstituted isochromanones is described. Irradiation of 2-formyl phenylalkeno-derivatives with UV light in benzene solution afforded the corresponding products in up to 98% yield. The possible reaction mechanism is proposed and further supported by the isotopic experiments.