17983-61-8

Basic information

• Product Name: Ethanone, 1-[4-(trimethylsilyl)phenyl]-
• CAS NO: 17983-61-8
• Molecular Formula: C11H16OSi
• Molecular Weight: 192.333
• Mol File: 17983-61-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-(trimethylsilyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(trimethylsilyl)phenyl]-(17983-61-8)
• EPA Substance Registry System: Ethanone, 1-[4-(trimethylsilyl)phenyl]-(17983-61-8)

Safety Data

• Hazardous Substances Data: 17983-61-8(Hazardous Substances Data)

Upstream product

• 4360-68-3 2-(4-bromophenyl)-2-methyl-1,3-dioxolane 
• 18192-28-4 2-methyl-2-<4'-(trimethylsilyl)phenyl>-1,3-dioxolane 
• 99-90-1 para-bromoacetophenone 
• 17993-99-6 (RS)-1-(4-trimethylsilylphenyl)ethanol 
• 5391-88-8 1-(4-bromophenyl)ethanol 
• 1585-07-5 1-bromo-4-ethylbenzene 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 99-91-2 para-chloroacetophenone 
• 75-77-4 chloro-trimethyl-silane 
• 13183-70-5 1,4-bis-(trimethylsilyl)benzene 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 17878-43-2 [4-(trimethylsilyl)phenyl]magnesium bromide 
• 17988-52-2 2-ethylphenyltrimethylsilane 

Downstream Products

• 87956-06-7 4‐[¹⁸F]fluoroacetophenone 
• 125973-59-3 (E)-4-<3-oxo-3-<4-(trimethylsilyl)phenyl>-1-propenyl>benzoic acid 
• 1415605-84-3 1-[4-(benzo[b]thiophen-3-yl)phenyl]ethan-1-one 
• 132932-62-8 2-(p-acetylphenyl)benzothiophene 
• 5002-07-3 4'-(4-chlorophenyl)acetophenone 
• 1009-43-4 4-(trimethylsilyl)styrene 

Relevant articles and documents

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Sodium silylsilanolate enables nickel-catalysed silylation of aryl chlorides

Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient ones. The mild reaction conditions allowed the silylation of various aryl chlorides including functionalised drug molecules.

Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes

N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.