18893-62-4

Basic information

• Product Name: Benzene, 1,1'-[1,2-ethenediylbis(thio)]bis-, (Z)-
• CAS NO: 18893-62-4
• Molecular Formula: C14H12S2
• Molecular Weight: 244.381
• Mol File: 18893-62-4.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[1,2-ethenediylbis(thio)]bis-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[1,2-ethenediylbis(thio)]bis-, (Z)-(18893-62-4)
• EPA Substance Registry System: Benzene, 1,1'-[1,2-ethenediylbis(thio)]bis-, (Z)-(18893-62-4)

Safety Data

• Hazardous Substances Data: 18893-62-4(Hazardous Substances Data)

Upstream product

• 26620-11-1 (E)-2-chlorovinylthiobenzene 
• 156-59-2 cis-1,2-Dichloroethylene 
• 108-98-5 thiophenol 
• 35572-08-8 bromomethyl phenyl thioether 
• 14173-25-2 methyl phenyl disulfide 
• 74-86-2 acetylene 
• 882-33-7 diphenyldisulfane 
• 75-20-7 calcium carbide 
• 930-69-8 sodium thiophenolate 
• 706-02-5 (2E)-3-(phenylthio)acrylic acid 
• 706-01-4 (2Z)-3-(phenylthio)acrylic acid 
• 848412-25-9 (Z)-1-phenylsulfinyl-2-phenylsulfanylethylene 
• 865-48-5 sodium t-butanolate 
• 865-47-4 potassium tert-butylate 

Downstream Products

• 6228-98-4 phenylthioacetylene 
• 963-15-5 (Z)-1,2-bis(phenylsulfonyl)ethene 
• 80571-24-0 racem.-cis-1,2-bis-benzenesulfinyl-ethylene 
• 963-16-6 (E)-1,2-bis(phenylsulfonyl)ethylene 
• 94867-26-2 all-cis-1,2,3-Tris--cyclopropan 
• 66823-42-5 (cis-2-deuterio-vinylsulfanyl)-benzene 
• 5535-48-8 PVS 
• 599-70-2 ethyl phenyl sulfone 

Relevant articles and documents

Reactivity of 1-phenylsulfinyl-2-phenylsulfanylethylene (SOSE) with O-nucleophiles generated by potassium tert-butoxide

E-1-Phenylsulfinyl-2-phenylsulfanylethylene (E-SOSE) reacts with O-nucleophiles generated by means of t-BuOK via an addition-elimination mechanism, thus affording the product of substitution of the phenylsulfanyl group in a stereo-conservative process. When used alone, the strongly basic and hindered tert-butoxide brings about elimination of either the phenylthiolate or phenylsulfinate groups. Z-SOSE is much more prone to elimination: either with t-BuOK alone or with other O-nucleophiles generated by t-BuOK, it always leads to products derived from elimination. Other alkaline tert-butoxides or other bases appear not as effective in generating species nucleophilic enough to react with E-SOSE.

USUAL CONVERSION OF PHENYLTHIOACETYLENE INTO 1,2-DI(PHENYLTHIO)ETHENE IN THE KOH-DMSO-CYCLOHEXANONE OXIME SYSTEM

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Switchable Ni-catalyzed bis-thiolation of acetylene with aryl disulfides as an access to functionalized alkenes and 1,3-dienes

The article provides the first example of metal-catalyzed aryl disulfide addition to unsubstituted acetylene. The use of inexpensive Ni(acac)2 precatalyst with phosphine ligands results in competitive formation of (Z)-1,2-bis(arylthio)ethenes a

An efficient metal-free pathway to vinyl thioesters with calcium carbide as the acetylene source

Chemical reactions involving high-pressure acetylene are not easily performed in a standard laboratory setup. The risk of explosion and technical difficulties drastically complicate the equipment and greatly increase the cost. In this study, we propose th