19351-91-8

Basic information

• Product Name: N-(naphthalen-1-ylmethyl)acetamide
• Synonyms: N-(naphthalen-1-ylmethyl)acetamide;N-(1-Naphthalenylmethyl)acetamide
• CAS NO: 19351-91-8
• Molecular Formula: C13H13NO
• Molecular Weight: 199.25
• Mol File: 19351-91-8.mol
• Article Data: 11

Chemical Properties

• Melting Point: 127-128.5 °C(Solv: ethyl acetate (141-78-6); ligroine (8032-32-4))
• Boiling Point: 437.9°Cat760mmHg
• Flash Point: 261.3°C
• Appearance: /
• Density: 1.114g/cm³
• Vapor Pressure: 7.2E-08mmHg at 25°C
• Refractive Index: 1.608
• PKA: 15.68±0.46(Predicted)
• CAS DataBase Reference: N-(naphthalen-1-ylmethyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(naphthalen-1-ylmethyl)acetamide(19351-91-8)
• EPA Substance Registry System: N-(naphthalen-1-ylmethyl)acetamide(19351-91-8)

Safety Data

• Hazardous Substances Data: 19351-91-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H13NO/c1-10(15)14-9-12-7-4-6-11-5-2-3-8-13(11)12/h2-8H,9H2,1H3,(H,14,15)

Upstream product

• 66-77-3 1-naphthaldehyde 
• 75-05-8 acetonitrile 
• 13504-46-6 1-naphtylaldehyde oxime 
• 64-19-7 acetic acid 
• 118-31-0 (naphth-1-yl)methylamine 
• 75-36-5 acetyl chloride 
• 64050-53-9 diethyl α-naphthylmethyl phosphate 
• 19534-16-8 anti(α-Naphthyl)-1-α-naphthyl-propan-2-on-oxim-tosylat 
• 108-24-7 acetic anhydride 
• 5027-32-7 1,1,2,2-Tetraacetylethan 
• 19534-15-7 syn-1-<α-Naphthyl-propanon-(2)>-oxim 
• 3163-27-7 2-(bromomethyl)naphthalene 
• 4780-79-4 1-naphthalene methanol 
• 79-16-3 N-methyl-acetamide 

Downstream Products

• 14489-76-0 ethyl(naphthalen-1-ylmethyl)amine 

Relevant articles and documents

Synthesis of functionalized pyrroles by reaction of 3,4-diacetylhexane-2,5- dione with primary amines in water

3,4-Diacetylhexane-2,5-dione (tetra-acetylethane) undergoes a complex reaction with primary amines in boiling water to produce N-alkyl-3-acetyl-2,5- dimethylpyrroles, together with small quantities of N-alkyl-3,4-diacetyl-2,5- dimethylpyrroles and 2,5-dim

Base-promoted dehydrogenative coupling of benzene derivatives with amides or ethers

Benzene derivatives are introduced into the dehydrogenative coupling via homolytic aromatic substitution (HAS) as arenes that couple with amides/ethers. NaOt-Bu is used as a critical promoter of HAS in combination with t-BuOOt-Bu as an oxidant.

Photo-ritter reaction of arylmethyl bromides in acetonitrile

The photo-Ritter reaction of five arylmethyl bromides can occur in acetonitrile to give acetamides. The intermediates, carbocations, which are formed from subsequent electron transfer between the radical pairs generated from initial homolytic cleavage of the C-Br bond, are trapped by acetonitrile, and subsequent hydrolysis generates the corresponding acetamides. Taylor & Francis Group, LLC.