203442-83-5

Basic information

• Product Name: methyl 4-(N-methoxy-N-methylcarbamoyl)benzoate
• Synonyms: methyl 4-(N-methoxy-N-methylcarbamoyl)benzoate
• CAS NO: 203442-83-5
• Molecular Weight: 223.229
• Mol File: 203442-83-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: methyl 4-(N-methoxy-N-methylcarbamoyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-(N-methoxy-N-methylcarbamoyl)benzoate(203442-83-5)
• EPA Substance Registry System: methyl 4-(N-methoxy-N-methylcarbamoyl)benzoate(203442-83-5)

Safety Data

• Hazardous Substances Data: 203442-83-5(Hazardous Substances Data)

Upstream product

• 30289-28-2 N-methoxy-N-methylcarbamoyl chloride 
• 91734-76-8 methyl 4-tri-n-butylstannylbenzoate 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 7377-26-6 4-Methoxycarbonylbenzoyl chloride 
• 1679-64-7 Monomethyl terephthalate 
• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 1204742-78-8 C₁₄H₂₀BNO₄ 
• 1257841-78-3 2-(4-methoxycarbonylbenzoyloxy)-1-methylpyridinium triflate 
• 1117-97-1 N,0-dimethylhydroxylamine 
• 98-88-4 benzoyl chloride 
• 1380243-02-6 methyl 4-(2-oxooxazolidine-3-carbonyl)benzoate 

Downstream Products

• 550366-66-0 methyl-4-(2′,2′-dibromoacetyl)benzoate 
• 1401298-93-8 C₁₄H₁₈O₃ 
• 3609-53-8 methyl 4-acetylbenzoate 
• 54549-72-3 1-(4-(2-hydroxypropan-2-yl)phenyl)ethan-1-one 
• 1059549-45-9 methyl 4-(2-fluoroacetyl)benzoate 
• 887627-93-2 methyl 4-(thiophene-2-carbonyl)benzoate 
• 872254-79-0 4-(1-hydroxybutyl)benzoic acid methyl ester 
• 6908-41-4 4-(methoxycarbonyl)benzyl alcohol 
• 1571-08-0 methyl 4-formylbenzoate 
• 71616-83-6 4-butyrylbenzoic acid methyl ester 

Relevant articles and documents

Rhoda-Electrocatalyzed Bimetallic C?H Oxygenation by Weak O-Coordination

Rhodium-electrocatalyzed arene C?H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C?H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C?H activation by a bimetallic rhodium catalysis manifold.

Fluoro-Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors

The external quenching method based on flow microreactors allows the generation and use of short-lived fluoro-substituted methyllithium reagents, such as fluoromethyllithium, fluoroiodomethyllithium, and fluoroiodostannylmethyllithium. Highly chemoselective reactions have been developed, opening new opportunities in the synthesis of fluorinated molecules using fluorinated organometallics.

Broadly Applicable Ytterbium-Catalyzed Esterification, Hydrolysis, and Amidation of Imides

An efficient, broadly applicable, operationally simple, and divergent process for the transformation of imides into a range of carboxylic acid derivatives under mild conditions is reported. By simply using catalytic amounts of ytterbium(III) triflate as a Lewis acid promoter in the presence of alcohols, water, amines, or N,O-dimethylhydroxylamine, a broad range of imides is smoothly and readily converted to the corresponding esters, carboxylic acids, amides, and Weinreb amides in good yields. This method notably enables an easy cleavage of oxazolidinone-based auxiliaries.