22591-15-7

Basic information

• Product Name: 2-(naphthalen-1-yl)cyclohexanone
• Synonyms: cyclohexanone, 2-(1-naphthalenyl)-
• CAS NO: 22591-15-7
• Molecular Formula: C₁₆H₁₆O
• Molecular Weight: 224.2976
• Mol File: 22591-15-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 396°C at 760 mmHg
• Flash Point: 174.9°C
• Density: 1.114g/cm³
• Vapor Pressure: 1.76E-06mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: 2-(naphthalen-1-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(naphthalen-1-yl)cyclohexanone(22591-15-7)
• EPA Substance Registry System: 2-(naphthalen-1-yl)cyclohexanone(22591-15-7)

Safety Data

• Hazardous Substances Data: 22591-15-7(Hazardous Substances Data)

Upstream product

• 703-55-9 1-naphthylmagnesiumbromide 
• 822-87-7 2-Chlorocyclohexanone 
• 40358-58-5 rac-(-)-(1R,2S)-2-(naphthalen-1-yl)cyclohexan-1-ol 
• 90-11-9 1-Bromonaphthalene 
• 586961-58-2 1-(2-oxo-5-hexenyl)naphthalene 
• 40358-51-8 1-cyclohex-1-enyl-naphthalene 
• 586961-79-7 1-naphthalen-1-yl-5-hexen-2-ol 
• 74685-85-1 1-(naphthalen-1-yl)cyclohexanol 
• 108-94-1 cyclohexanone 
• 2562-37-0 1-nitrocyclohexene 
• 14474-59-0 naphthalen-1-yl-lithium 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 116400-75-0 2-(1'-Naphthyl)-cyclohexanol 

Downstream Products

• 109157-45-1 1-(2-methyl-cyclohex-1-enyl)-naphthalene 
• 60955-64-8 1-(1-Naphthyl)-2-phenethinylcyclohexen 
• 200-23-7 benzo[b]naphtho[1,8-de]pyran 
• 40358-58-5 cis-2-(naphthalen-1-yl)cyclohexan-1-ol 
• 1253693-60-5 1-naphthyl-1-(trimethylsiloxy)cyclohex-1-ene 
• 1402080-90-3 7-(naphthalen-1-yl)oxepan-2-one 
• 643760-73-0 (-)-2-(naphthalen-1-yl)cyclohexanone 
• 40358-51-8 1-cyclohex-1-enyl-naphthalene 
• 146744-37-8 (1R,2S)-trans-2-(α-naphthalenyl)cyclohexan-1-ol 
• 190256-76-9 (R)-2-(1-naphthyl)cyclohexanone 

Relevant articles and documents

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Enantioselective Protonation of Silyl Enol Ethers Catalyzed by a Chiral Pentacarboxycyclopentadiene-Based Bronsted Acid

The enantioselective protonation of silyl enol ethers was realized in the presence of a pentacarboxycyclopenta-1,3-diene-based chiral Bronsted acid catalyst with water as an achiral proton source to give the corresponding α-aryl ketones in good yields and up to 75percent ee.

Development of a new Lewis base-tolerant chiral LBA and its application to catalytic asymmetric protonation reaction

A new Lewis base-tolerant LBA (Lewis Acid Assisted Bronsted Acid) derived from La(OTf)3 and (S)-HOP has been developed as a new chiral Bronsted acid. This acid has been successfully applied as a catalyst to asymmetric protonation reactions of silyl enol ethers of 2-substituted cyclic ketones.