40358-51-8

Basic information

• Product Name: 1-(1-cyclohexen-1-yl)naphthalene
• Synonyms: 1-(1-cyclohexen-1-yl)naphthalene;1-(1-Cyclohexenyl)naphthalene;1-(1-Naphtyl)-1-cyclohexene
• CAS NO: 40358-51-8
• Molecular Formula: C₁₆H₁₆
• Molecular Weight: 208.29824
• EINECS: 254-888-1
• Mol File: 40358-51-8.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 351.3°Cat760mmHg
• Flash Point: 177.7°C
• Appearance: /
• Density: 1.062g/cm³
• Vapor Pressure: 8.42E-05mmHg at 25°C
• Refractive Index: 1.627
• CAS DataBase Reference: 1-(1-cyclohexen-1-yl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-cyclohexen-1-yl)naphthalene(40358-51-8)
• EPA Substance Registry System: 1-(1-cyclohexen-1-yl)naphthalene(40358-51-8)

Safety Data

• Hazardous Substances Data: 40358-51-8(Hazardous Substances Data)

Usage

Chemical structure

A polycyclic aromatic hydrocarbon (PAH) with a naphthalene ring linked to a cyclohexene ring

Usage

a. Production of fragrances and aromas due to its pleasant smell
b. Manufacturing of various chemical products

Environmental impact

Identified as a potential environmental pollutant

Health hazards

a. Classified as a possible carcinogen by the International Agency for Research on Cancer (IARC)
b. Can cause skin irritation and sensitization in humans

Precaution

Caution should be exercised in handling and using this compound due to its potential health and environmental risks

InChI:InChI=1/C16H16/c1-2-7-13(8-3-1)16-12-6-10-14-9-4-5-11-15(14)16/h4-7,9-12H,1-3,8H2

Upstream product

• 116400-75-0 2-(1'-Naphthyl)-cyclohexanol 
• 108-94-1 cyclohexanone 
• 703-55-9 1-naphthylmagnesiumbromide 
• 74685-85-1 1-(naphthalen-1-yl)cyclohexanol 
• 90-11-9 1-Bromonaphthalene 
• 18428-06-3 tetrahydro(8,9,10,11)benzo(b)naphto<1,2-d>thiophene 
• 13922-41-3 1-Naphthylboronic acid 
• 109467-74-5 phosphoric acid cyclohex-1-enyl ester diphenyl ester 
• 56-23-5 tetrachloromethane 
• 40358-58-5 rac-(-)-(1R,2S)-2-(naphthalen-1-yl)cyclohexan-1-ol 
• 7789-60-8 phosphorus tribromide 
• 14474-59-0 naphthalen-1-yl-lithium 
• 110-83-8 cyclohexene 
• 2044-08-8 1-bromocyclohex-1-ene 

Downstream Products

• 6709-40-6 benzo[c]phenanthrene-5,6-dicarboxylic acid-anhydride 
• 108842-56-4 2-(1-naphthyl)-2-cyclohexenone 
• 3042-69-1 1-cyclohexylnaphthalene 
• 605-02-7 1-phenylnaphthalene 
• 206-44-0 fluoranthene 
• 40358-58-5 rac-(-)-(1R,2S)-2-(naphthalen-1-yl)cyclohexan-1-ol 
• 7583-83-7 1-(naphthalen-1-yl)-7-oxabicyclo[4.1.0]heptane 
• 22591-15-7 2-(naphthalen-1-yl)cyclohexanone 
• 93321-11-0 1-(2-methoxyphenyl)naphthalene 
• 109394-97-0 (+/-)-(2t-[1]naphthyl-3-oxo-cyclohex-r-yl)-acetic acid 
• 121968-91-0 (+/-)-trans-3,4,4a,5,6,12c-hexahydro-2H-benzo[c]phenanthren-1-one-(2,4-dinitro-phenylhydrazone) 

Relevant articles and documents

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Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides

A bimetallic catalyst system generated from readily available palladium(II) and copper(I) salts, 1,10-phenanthroline and tri-1-naphthylphosphine was found to efficiently mediate the decarboxylative cross-coupling of alkenyl bromides and chlorides with aromatic carboxylates. It allows the regiospecific synthesis of a broad range of aryl- and heteroarylalkenes in high yields.

FeCl3/Nal-catalyzed allylic C-H oxidation of arylalkenes with a catalytic amount of disulfide under air

This paper describes a FeCl3/NaI-catalyzed formal allylic C-H oxidation of arylalkenes using a catalytic amount of disulfide with BnOH and 4-nitroaniline as nucleophiles and air as oxidant to form the corresponding allyl ethers and amines. A possible reaction mechanism has been proposed.