22679-42-1

Basic information

• Product Name: Methanone, (2-ethylphenyl)phenyl-
• Synonyms: (2-ethylphenyl)(phenyl)methanone;2-ethylphenyl phenyl ketone;2-ethyl-benzophenone;(2-ethylphenyl) (phenyl)methanone;2-Aethyl-benzophenon
• CAS NO: 22679-42-1
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• Mol File: 22679-42-1.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 165 °C(Press: 18 Torr)
• Density: 1.049±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Methanone, (2-ethylphenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (2-ethylphenyl)phenyl-(22679-42-1)
• EPA Substance Registry System: Methanone, (2-ethylphenyl)phenyl-(22679-42-1)

Safety Data

• Hazardous Substances Data: 22679-42-1(Hazardous Substances Data)

Upstream product

• 255828-63-8 1,2-bis-(2-ethyl-phenyl)-1,2-diphenyl-ethane-1,2-diol 
• 103-73-1 Phenetole 
• 10533-83-2 N-benzoyl-N-methyl-4-methylbenzenesulfonamide 
• 1519010-69-5 bis(2-ethylphenyl)borinic acid 
• 2029-73-4 2-ethyl-benzhydrol 
• 1973-22-4 1-bromo-2-ethylbenzene 
• 100-52-7 benzaldehyde 
• 98-88-4 benzoyl chloride 
• 93-98-1 N-phenyl benzoyl amide 
• 65-85-0 benzoic acid 
• 90002-36-1 2-ethylphenyl boronic acid 
• 74542-54-4 N,N-phenyl-p-toluenesulfonylbenzamide 
• 100-41-4 ethylbenzene 
• 34136-59-9 o-ethylbenzonitrile 

Downstream Products

• 73721-00-3 2-[2-(benzoyl)phenyl] propanoic acid 
• 131-58-8 2-Methylbenzophenone 
• 35011-63-3 1-phenyl-3,5-dihydro-benzo[d][1,2]diazepin-4-one 
• 23107-96-2 (2-benzoyl-phenyl)-acetic acid 
• 19164-61-5 7-phenylbicyclo<4.2.0>octa-1,3,5-trien-7-ol 
• 97437-82-6 (+/-)-2-Aethyl-benzhydrylchlorid 
• 19772-61-3 2-bromo-3-phenyl-1H-inden-1-one 

Relevant articles and documents

Highly efficient synthesis of aryl ketones by PEPPSI-palladium catalyzed acylative Suzuki coupling of amides with diarylborinic acids

An improved acylative cross-coupling of various N-methyl-N-tosyl amides with diarylborinic acids for synthesis of aryl ketones is developed. In most cases, aryl ketones could be obtained in excellent yields by using 1 mol% 2,6-diisopropylphenylimidazolylidene and 3-chloropyridine co-supported palladium chloride as catalyst in the presence of 3 equiv. K2CO3 as base in refluxing THF. The readily prepared and cost-effective substrates, N-methyl-N-tosylamides and diarylborinic acids, and the commercially available catalyst system promise a practical and efficient access to aryl ketones.

Cobalt-Catalyzed Asymmetric Hydrogenation of 1,1-Diarylethenes

Highly enantioselective cobalt-catalyzed hydrogenation of 1,1-diarylethenes was developed by using bench-stable chiral oxazoline iminopyridine-cobalt complexes as precatalysts. A unique o-chloride effect was observed to achieve high enantioselectivity. Easy removal as well as further transformations of the chloro group make this protocol a potentially useful alternative to synthesize various chiral 1,1-diarylethanes. This process can be successfully performed under 1 atm of hydrogen at room temperature on gram scale.

Acylative Suzuki coupling of amides: Acyl-nitrogen activation via synergy of independently modifiable activating groups

A highly efficient palladium-catalyzed acylative cross-coupling of carboxylic amides with arylboronic acids has been achieved via synergistic activation of the Cacyl-N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also modifiable reactivities to overcome steric hindrance. This journal is