23746-59-0

Basic information

• Product Name: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-, dimethyl ester, (E,E)-
• Synonyms: E,E-dimethyl 3,3'-(1,3-phenylene)bis-2-propanoate;(2E,2E’)-dimethyl 3,3’-(1,3-phenylene)diacrylate;1.3-bis-(trans-2-methoxycarbonyl-vinyl)-benzene;1.3-Bis-(trans-2-methoxycarbonyl-vinyl)-benzol
• CAS NO: 23746-59-0
• Molecular Formula: C14H14O4
• Molecular Weight: 246.263
• Mol File: 23746-59-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-, dimethyl ester, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-, dimethyl ester, (E,E)-(23746-59-0)
• EPA Substance Registry System: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-, dimethyl ester, (E,E)-(23746-59-0)

Safety Data

• Hazardous Substances Data: 23746-59-0(Hazardous Substances Data)

Upstream product

• 626-19-7 Isophthalaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 591-18-4 1-Bromo-3-iodobenzene 
• 292638-85-8 acrylic acid methyl ester 
• 115974-96-4 (E)-3-(methoxy-3-oxoprop-1-en-1-yl)benzoic acid 
• 581799-33-9 3-[(1E)-3-methoxy-3-oxoprop-1-en-1-yl]benzoic acid chloride 
• 114862-12-3 (1R,2S,3R,4S)-3,4-Bis-[3-((E)-2-methoxycarbonyl-vinyl)-phenyl]-cyclobutane-1,2-dicarboxylic acid dimethyl ester 
• 67-56-1 methanol 
• 23713-86-2 1,3-phenylene-3,3'-bis(2-propenoic) acid 

Downstream Products

• 156808-21-8 (2E,2'E)-3,3'-(1,3-phenylene)-bis(prop-2-en-1-ol) 
• 681462-62-4 3,3'-(4,6-dinitro-m-phenylene)-di-propionic acid dimethyl ester 
• 75160-05-3 3,3'-dioxo-3,3'-m-phenylene-di-propionic acid dimethyl ester 
• 159279-96-6 m-phenylenedi-propiolic acid dimethyl ester 
• 4481-99-6 3,3'-dioxo-3,3'-m-phenylene-di-propionic acid 
• 4843-46-3 3,3′-(1,3-phenylene)dipropiolic acid 
• 60521-72-4 1,3-bis(ethoxycarbonylethynyl)benzene 
• 18910-23-1 3-acetyl-cinnamic acid 
• 6781-42-6 1,3-diacetylbenzene 
• 114862-11-2 (E,Z)-1,3-Phenylendiacrylsaeure-dimethylester 
• 114862-12-3 (1R,2S,3R,4S)-3,4-Bis-[3-((E)-2-methoxycarbonyl-vinyl)-phenyl]-cyclobutane-1,2-dicarboxylic acid dimethyl ester 
• 860517-17-5 2',3',2'',3''-tetrabromo-m-phenylene-di-propionate dimethyl ester 
• 897397-74-9 (2E,2E')-dimethyl 3,3'-(4-nitro-1,3-phenylene)diacrylate 

Relevant articles and documents

METHOD FOR PRODUCING POLYGUANIDINES

A method for preparing polycondensation products of guanidine, aminoguanidine or diaminoguanidine G with one or more benzyl or allyl derivatives BA according to the following reaction scheme is provided: wherein X, R1, Gua, Y and Z are as defined in the specification. In the disclosed method, at least one benzyl or allyl derivative BA is subjected to a polycondensation reaction with excessive guanidine, aminoguanidine or diaminoguanidine G upon elimination of HX.

Synthesis of unsymmetrical divinylbenzenes by palladium catalyzed sequential heck reactions starting from carboxybenzenediazonium salts

Six p-, m- and o-unsymmetrical divinylbenzenes 5a, 5b, 6a, 6b, 6c and 7a are synthesized from p-, m- and o- carboxybenzenediazonium tetrafluoroborates via sequential Heck reactions in good overall yield.

Palladium-catalyzed reactions of bisarenediazoniutn salts: Two-fold Heck reaction, carbonylation and cross-coupling regimen

Two-fold Heck reaction, carbonylation and cross-coupling reactions of bisarenediazonium salts have been carried out in high yields under mild, aqueous alcoholic conditions to provide a new synthetic repertoire for tetraaryls and other aromatic derivatives having extended conjugation.