24131-01-9

Basic information

• Product Name: 1,3-Dioxane-4,6-dione, 2,2,5-trimethyl-5-phenyl-
• CAS NO: 24131-01-9
• Molecular Formula: C13H14O4
• Molecular Weight: 234.252
• Mol File: 24131-01-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxane-4,6-dione, 2,2,5-trimethyl-5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxane-4,6-dione, 2,2,5-trimethyl-5-phenyl-(24131-01-9)
• EPA Substance Registry System: 1,3-Dioxane-4,6-dione, 2,2,5-trimethyl-5-phenyl-(24131-01-9)

Safety Data

• Hazardous Substances Data: 24131-01-9(Hazardous Substances Data)

Upstream product

• 2613-89-0 phenylmalonic acid 
• 110-91-8 morpholine 
• 15231-78-4 2.2-dimethyl-5-phenyl-1,3-dioxane-4,6-dione 
• 74-88-4 methyl iodide 
• 3709-18-0 2,2,5-trimethyl-1,3-dioxane-4,6-dione 
• 98-80-6 phenylboronic acid 
• 4371-02-2 2-methyl-2-phenylmalonic acid 

Downstream Products

• 1018452-00-0 1-(1-(4-nitrophenylsulfonyl)-1H-indol-3-yl)-2-phenylpropan-1-one 
• 117638-51-4 phenyl (S)-2-phenylpropionic acid 
• 97479-89-5 α-methylbenzeneacetic acid phenyl ester 
• 91668-63-2 4-methoxyphenyl 2-phenylpropanoate 
• 1308679-17-5 4-methoxyphenyl (R)-2-phenylpropanoate 
• 141964-53-6 (S)-4-methoxyphenyl 2-phenylpropanoate 
• 123392-71-2 2,4-dimethoxy-α-C-methyldesoxybenzoin 
• 57780-74-2 2-phenylpropanoyl 2-phenylpropanoate 
• 67-64-1 acetone 
• 492-37-5 hydratropic acid 
• 31508-44-8 2-phenylpropionic acid methyl ester 

Relevant articles and documents

Organocatalytic Enantioselective Decarboxylative Protonation Reaction of Meldrum's Acid Derivatives under PTC Conditions

An original organocatalyzed enantioselective protonation sequence of a transient quaternary ammonium enolate species has been developed by starting from readily available disubstituted Meldrum's acid derivatives and phenols. Under phase-transfer-catalytic (PTC) conditions, chiral nonracemic 2-aryl propionic ester derivatives were obtained in good isolated yields with enantioselectivities up to 70 % ee. The usefulness of the approach was demonstrated by the synthesis of enantioenriched (S)-ibuprofen.

Arylations mediated by lead(IV) in the presence of formazan and imine ligands

The use of formazan and imine ligands in arylations of β-dicarbonyl systems by phenyl boronic acid/lead(IV) carboxylates is examined.

Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates

An investigation of catalysis and ligand exchange in the arylation of nucleophiles with phenylboronic acid and mixed ligand lead(IV) complexes is described. Although this reaction is known to be catalyzed by mercury(II) acetate, other heavy metals have be