24524-97-8

Basic information

• Product Name: Benzene, 1-(diethoxymethyl)-4-fluoro-
• Synonyms: 4-Fluorobenzaldehyde diethyl acetal;p-Fluorbenzaldehyd-diethylacetal;4-FC6H4CH(OEt)2;Benzene,1-(diethoxymethyl)-4-fluoro
• CAS NO: 24524-97-8
• Molecular Formula: C11H15FO2
• Molecular Weight: 198.237
• Mol File: 24524-97-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(diethoxymethyl)-4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(diethoxymethyl)-4-fluoro-(24524-97-8)
• EPA Substance Registry System: Benzene, 1-(diethoxymethyl)-4-fluoro-(24524-97-8)

Safety Data

• Hazardous Substances Data: 24524-97-8(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 459-57-4 4-fluorobenzaldehyde 
• 122-51-0 orthoformic acid triethyl ester 
• 104-15-4 toluene-4-sulfonic acid 

Downstream Products

• 64002-52-4 (4-fluorophenyl)methylene diacetate 
• 83521-64-6 2-(4-fluorophenyl)-1,3-dithiolane 
• 1188448-07-8 3-(4-fluorophenyl)-8,8-dimethyl-2,2-diphenyl-2,8-dihydrocyclopenta[a]indene 
• 86657-76-3 1-Fluoro-4-(1,3,3-triethoxy-propyl)-benzene 

Relevant articles and documents

Practical acetalization and transacetalization of carbonyl compounds catalyzed by recyclable PVP-I

A novel PVP-I catalyzed acetalizations/transacetalizations of carbonyl compounds has been developed processing with a mild and easy handling fashion. Different types of Acyclic and cyclic acetals were prepared from carbonyl compounds or their acetals successfully. Further applications of newly developed catalytic combination were testified. This protocol featured with simplicity of operation, mild reaction condition, short reaction time, recyclable of catalyst and broad substrates scope with excellent yields.

Development of a novel Br?nsted acid UiO-66 metal-organic framework catalyst by postsynthetic modification and its application in catalysis

A novel Br?nsted acid derived metal-organic framework (MOF) has been developed to serve as an efficient heterogeneous catalyst for the acetalization and Morita-Baylis-Hillman reaction. Aromatic sulfonic acid groups were successfully incorporated to the framework of UiO-66 by post-synthetic modifications using commercially available anhydridic reagents. The UiO-66-RArSO3H Br?nsted acid catalyst was fully characterized using SEM, PXRD, FTIR, TGA and N2 adsorption/desorption isotherms. Furthermore, efficient acetalization and Morita-Baylis-Hillman reactions were evaluated to demonstrate the high catalytic performance of the UiO-66-RArSO3H catalyst. The UiO-66-RArSO3H catalyst is compatible with a variety of substituted substrates and can be recycled five times without a compromise in the yield or selectivity.

Development of a SO3H-functionalized UIO-66 metal-organic framework by postsynthetic modification and studies of its catalytic activities

A novel metal-organic framework UiO-66-NH2-derived Br?nsted acid catalyst was synthesized on a gram scale by employing a postsynthetic modification strategy under mild conditions. The nanomorphology of the catalyst was designed and developed to enhance its catalytic performance. Acetalization and benzimidazole formation were evaluated to demonstrate the high reactivity and selectivity of the nanoscaled UiO-66-NH-RSO3H catalyst, which were found to be comparable to the reactivity and selectivity of the strong homogeneous Br?nsted acid catalyst. Furthermore, the UiO-66-NH-RSO3H catalyst was recycled several times without compromising the yield and selectivity. A novel metal-organic framework UiO-66-NH2-derived Br?nsted acid catalyst is synthesized by employing a postsynthetic modification strategy under mild conditions. Acetalization and benzimidazole formation are evaluated to demonstrate the high reactivity and selectivity of the nanoscaled UiO-66-NH-RSO3H catalyst.